{"id":7925,"date":"2018-07-09T10:00:28","date_gmt":"2018-07-09T01:00:28","guid":{"rendered":"https:\/\/academist-cf.com\/journal\/?p=7925"},"modified":"2018-07-05T11:44:17","modified_gmt":"2018-07-05T02:44:17","slug":"%e5%85%b8%e5%9e%8b%e5%85%83%e7%b4%a0%e8%a7%a6%e5%aa%92%e3%81%a8%e6%b0%b4%e7%b4%a0%e3%82%92%e6%b4%bb%e7%94%a8%e3%81%97%e3%81%9f%e3%82%af%e3%83%aa%e3%83%bc%e3%83%b3%e3%81%aa%e3%82%a2%e3%83%9f%e3%83%b3","status":"publish","type":"post","link":"https:\/\/academist-cf.com\/journal\/?p=7925","title":{"rendered":"\u5178\u578b\u5143\u7d20\u89e6\u5a92\u3068\u6c34\u7d20\u3092\u6d3b\u7528\u3057\u305f\u30af\u30ea\u30fc\u30f3\u306a\u30a2\u30df\u30f3\u5909\u63db\u6cd5\u3092\u5b9f\u73fe\uff01"},"content":{"rendered":"<h3>\u30a2\u30df\u30f3\u306e\u9084\u5143\u7684\u30a2\u30eb\u30ad\u30eb\u5316\u53cd\u5fdc\u3001\u305d\u306e\u7406\u60f3\u7684\u306a\u5f62\u5f0f\u3092\u76ee\u6307\u3057\u3066<\/h3>\n<p>\u30a2\u30df\u30f3\uff08NR<sub>3<\/sub>\u3001N\u306f\u7a92\u7d20\u3067R\u306f\u70ad\u7d20\u3084\u6c34\u7d20\u306a\u3069\uff09\u306f\u591a\u304f\u306e\u533b\u85ac\u54c1\u3001\u8fb2\u85ac\u3001\u6a5f\u80fd\u6027\u6750\u6599\u3001\u98df\u54c1\u6dfb\u52a0\u7269\u306a\u3069\u306b\u542b\u307e\u308c\u308b\u91cd\u8981\u306a\u5316\u5408\u7269\u3067\u3059\u3002\u305f\u3068\u3048\u3070\u3001\u4e0b\u56f3\u306b\u7d39\u4ecb\u3059\u308b\u30e1\u30c8\u30c8\u30ec\u30ad\u30b5\u30fc\u30c8\uff08\u6297\u764c\u5264\u3001\u6297\u30ea\u30a6\u30de\u30c1\u85ac\uff09\u3084\u30ec\u30d1\u30b0\u30ea\u30cb\u30c9\uff08\u7cd6\u5c3f\u75c5\u85ac\uff09\u3001\u30d0\u30eb\u30b5\u30eb\u30bf\u30f3\uff08\u9ad8\u8840\u5727\u75c7\u6cbb\u7642\u85ac\uff09\u306a\u3069\u3082\u30a2\u30df\u30f3\uff08\u307e\u305f\u306f\u3001\u305d\u3053\u304b\u3089\u8a98\u5c0e\u3055\u308c\u308b\uff09\u9aa8\u683c\u3092\u542b\u3093\u3067\u3044\u308b\u5316\u5408\u7269\u3067\u3059\u3002\u6ce8\u76ee\u3059\u3079\u304d\u3053\u3068\u306b\u3001\u3053\u306e\u3088\u3046\u306a\u30a2\u30df\u30f3\u306b\u306f\u8907\u6570\u306e\u30a2\u30df\u30ce\u57fa\uff08\uff0dNR<sub>2<\/sub>\uff09\u304c\u542b\u307e\u308c\u3066\u3044\u305f\u308a\u3001\u30ab\u30eb\u30dc\u30ad\u30b7\u30eb\u57fa\uff08\uff0dCOOH\uff09\u306a\u3069\u306e\u91cd\u8981\u306a\u5b98\u80fd\u57fa\u304c\u5171\u5b58\u3057\u3066\u3044\u307e\u3059\u3002<\/p>\n<figure 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id=\"attachment_7928\" aria-describedby=\"caption-attachment-7928\" style=\"width: 600px\" class=\"wp-caption aligncenter\"><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-7928\" src=\"https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2018\/07\/003.jpg\" alt=\"\" width=\"600\" height=\"295\" srcset=\"https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2018\/07\/003.jpg 600w, https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2018\/07\/003-300x148.jpg 300w\" sizes=\"auto, (max-width: 600px) 100vw, 600px\" \/><figcaption id=\"caption-attachment-7928\" 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id=\"attachment_7933\" aria-describedby=\"caption-attachment-7933\" style=\"width: 600px\" class=\"wp-caption aligncenter\"><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-7933 size-full\" src=\"https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2018\/07\/004r.jpg\" alt=\"\" width=\"600\" height=\"264\" srcset=\"https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2018\/07\/004r.jpg 600w, https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2018\/07\/004r-300x132.jpg 300w\" sizes=\"auto, (max-width: 600px) 100vw, 600px\" \/><figcaption id=\"caption-attachment-7933\" class=\"wp-caption-text\">\u6211\u3005\u306e\u53cd\u5fdc\u7cfb\u306b\u9069\u7528\u53ef\u80fd\u306a\u30a2\u30df\u30f3\u306e\u4f8b<\/figcaption><\/figure>\n<p>\u305d\u3057\u3066\u4f55\u3088\u308a\u3082\u3001\u6211\u3005\u306e\u624b\u6cd5\u3092\u5229\u7528\u3057\u305f\u969b\u306e\u53cd\u5fdc\u526f\u751f\u6210\u7269\u306f\u6c34\u306e\u307f\u3067\u3042\u308a\u3001\u540c\u6642\u306b\u3001\u6bd2\u6027\u306e\u9ad8\u3044\u5143\u7d20\u3092\u542b\u307e\u306a\u3044\u305f\u3081\u3001\u975e\u5e38\u306b\u30af\u30ea\u30fc\u30f3\u306a\u30a2\u30df\u30f3\u5909\u63db\u624b\u6cd5\u3067\u3042\u308b\u3068\u8a00\u3048\u307e\u3059\u3002<\/p>\n<h3>\u307e\u3060\u307e\u3060\u8ab2\u984c\u306f\u5c3d\u304d\u306a\u3044\u3001\u3060\u304b\u3089\u6b21\u306e\u6311\u6226\u3078\uff01<\/h3>\n<p>\u4eca\u56de\u3001\u6211\u3005\u306f\u3001\u89e6\u5a92\u306b\u6709\u6a5f\u30db\u30a6\u7d20\u5316\u5408\u7269\u3001\u9084\u5143\u5264\u306bH<sub>2<\/sub>\u3092\u7528\u3044\u305f\u30a2\u30df\u30f3\u306e\u9084\u5143\u7684\u30a2\u30eb\u30ad\u30eb\u5316\u53cd\u5fdc\u3092\u958b\u767a\u3057\u307e\u3057\u305f\u3002\u6211\u3005\u306e\u624b\u6cd5\u3092\u7528\u3044\u308b\u3053\u3068\u3067\u3001\u751f\u7406\u6d3b\u6027\u3092\u5099\u3048\u305f\u30a2\u30df\u30ce\u9178\u306a\u3069\u591a\u69d8\u306a\u30a2\u30df\u30f3\u3092\u30c0\u30a4\u30ec\u30af\u30c8\u306b\u5909\u63db\u3059\u308b\u3053\u3068\u304c\u53ef\u80fd\u3068\u306a\u308a\u307e\u3057\u305f\u3002\u3055\u3089\u306b\u3001\u53cd\u5fdc\u306e\u526f\u751f\u6210\u7269\u306f\u6c34\u306e\u307f\u3067\u3059\u3002\u307e\u305f\u3001\u6bd2\u6027\u306e\u9ad8\u3044\u8cb4\u91d1\u5c5e\u985e\u3092\u4e00\u5207\u7528\u3044\u3066\u3044\u306a\u3044\u70b9\u3082\u3001\u6211\u3005\u306e\u624b\u6cd5\u306e\u7279\u7b46\u3059\u3079\u304d\u7d50\u679c\u3067\u3042\u308b\u3068\u8a00\u3048\u307e\u3059\u3002<\/p>\n<p>\u3057\u304b\u3057\u3001\u307e\u3060\u307e\u3060\u6539\u5584\u3059\u3079\u304d\u70b9\u304c\u6b8b\u3063\u3066\u3044\u308b\u3053\u3068\u3082\u4e8b\u5b9f\u3067\u3059\u3002\u305f\u3068\u3048\u3070\u3001\u53cd\u5fdc\u306e\u6761\u4ef6\u3092\u3088\u308a\u7a4f\u3084\u304b\u306b\u3059\u308b\uff08\u53cd\u5fdc\u6e29\u5ea6\u3092\u4e0b\u3052\u308b\u3001H<sub>2<\/sub>\u306e\u5727\u529b\u3092\u4e0b\u3052\u308b\uff09\u3053\u3068\u3067\u3001\u30a8\u30cd\u30eb\u30ae\u30fc\u306e\u7121\u99c4\u3092\u6e1b\u3089\u3059\u3053\u3068\u304c\u3067\u304d\u307e\u3059\u3002\u307e\u305f\u3001\u6709\u6a5f\u30db\u30a6\u7d20\u89e6\u5a92\u306e\u30d1\u30d5\u30a9\u30fc\u30de\u30f3\u30b9\u3092\u5411\u4e0a\u3055\u305b\u308b\u3053\u3068\u3067\u3001\u30b3\u30b9\u30c8\u9762\u3067\u306e\u5229\u70b9\u3092\u3088\u308a\u969b\u7acb\u305f\u305b\u308b\u3053\u3068\u304c\u3067\u304d\u307e\u3059\u3002\u53cd\u5fdc\u751f\u6210\u7269\u306e\u4e09\u6b21\u5143\u7684\u306a\u7acb\u4f53\u5236\u5fa1\u306b\u3082\u6311\u6226\u3057\u306a\u304f\u3066\u306f\u3044\u3051\u307e\u305b\u3093\u3002<\/p>\n<p>\u3053\u308c\u3089\u306f\u3001\u6211\u3005\u304c\u53d6\u308a\u7d44\u3080\u3079\u304d\u6b21\u306e\u8ab2\u984c\u3067\u3042\u308a\u3001\u3088\u308a\u7406\u60f3\u7684\u304b\u3064\u7a76\u6975\u7684\u306a\u30a2\u30df\u30f3\u5909\u63db\u6cd5\u306e\u958b\u767a\u3092\u76ee\u6307\u3057\u3066\u3001\u7814\u7a76\u3092\u7d9a\u3051\u3066\u3044\u304d\u305f\u3044\u3068\u601d\u3063\u3066\u3044\u307e\u3059\u3002<\/p>\n<p>\u672c\u7814\u7a76\u306f<a href=\"http:\/\/www.chem.eng.osaka-u.ac.jp\/~ogoshi-lab\/\">\u5927\u962a\u5927\u5b66\u5927\u5b66\u9662\u5de5\u5b66\u7814\u7a76\u79d1\u306e\u751f\u8d8a\u5c08\u4ecb\u6559\u6388\u304c\u4e3b\u50ac\u3059\u308b\u7814\u7a76\u5ba4<\/a>\u306e\u6210\u679c\u3067\u3059\u3002\u7814\u7a76\u30c1\u30fc\u30e0\u306e\u30e1\u30f3\u30d0\u30fc\u3067\u3042\u308b\u6728\u4e0b \u62d3\u4e5f\u541b\uff08\u535a\u58eb\u5f8c\u671f\u8ab2\u7a0b\uff09\u3001\u30cf\u30ba\u30e9 \u30b9\u30cb\u30c3\u30c8\u535a\u58eb\uff08\u7814\u7a76\u54e1\uff09\u3001\u5927\u6a4b \u7406\u4eba\u51c6\u6559\u6388\u3001\u751f\u8d8a\u6559\u6388\u3089\u306e\u4ee3\u8868\u3068\u3057\u3066\u3001\u79c1\u304c\u672c\u7a3f\u3092\u5bc4\u7a3f\u3055\u305b\u3066\u6234\u304d\u307e\u3057\u305f\u3002\u307e\u305f\u3001\u7814\u7a76\u8cbb\u306f\u65e5\u672c\u5b66\u8853\u632f\u8208\u4f1a\u304b\u3089\u652f\u63f4\u3055\u308c\u307e\u3057\u305f\u3002<\/p>\n<p><b>\u53c2\u8003\u6587\u732e<\/b><\/p>\n<ul>\n<li>P. J. Dunn et al., Green Chem., 2007, 9, 411.<\/li>\n<li>T. So\u00f3s et al., ACS Catal., 2015, 5, 5366.<\/li>\n<li>Y. Hoshimoto et al., J. Am. Chem. Soc., 2018, 140, 7292.<\/li>\n<\/ul>\n","protected":false},"excerpt":{"rendered":"<p>\u30a2\u30df\u30f3\u306e\u9084\u5143\u7684\u30a2\u30eb\u30ad\u30eb\u5316\u53cd\u5fdc\u3001\u305d\u306e\u7406\u60f3\u7684\u306a\u5f62\u5f0f\u3092\u76ee\u6307\u3057\u3066 \u30a2\u30df\u30f3\uff08NR3\u3001N\u306f\u7a92\u7d20\u3067R\u306f\u70ad\u7d20\u3084\u6c34\u7d20\u306a\u3069\uff09\u306f\u591a\u304f\u306e\u533b\u85ac\u54c1\u3001\u8fb2\u85ac\u3001\u6a5f\u80fd\u6027\u6750\u6599\u3001\u98df\u54c1\u6dfb\u52a0\u7269\u306a\u3069\u306b\u542b\u307e\u308c\u308b\u91cd\u8981\u306a\u5316\u5408\u7269\u3067\u3059\u3002\u305f\u3068\u3048\u3070\u3001\u4e0b\u56f3\u306b\u7d39\u4ecb [&hellip;]<\/p>\n","protected":false},"author":310,"featured_media":7928,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_acf_changed":false,"_monsterinsights_skip_tracking":false,"_monsterinsights_sitenote_active":false,"_monsterinsights_sitenote_note":"","_monsterinsights_sitenote_category":0,"footnotes":""},"categories":[3],"tags":[20],"class_list":["post-7925","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-outcome","tag-20","has_thumb"],"acf":[],"aioseo_notices":[],"_links":{"self":[{"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=\/wp\/v2\/posts\/7925","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=\/wp\/v2\/users\/310"}],"replies":[{"embeddable":true,"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=7925"}],"version-history":[{"count":4,"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=\/wp\/v2\/posts\/7925\/revisions"}],"predecessor-version":[{"id":7931,"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=\/wp\/v2\/posts\/7925\/revisions\/7931"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=\/wp\/v2\/media\/7928"}],"wp:attachment":[{"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=7925"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=7925"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=7925"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}