{"id":3995,"date":"2017-03-31T10:00:03","date_gmt":"2017-03-31T01:00:03","guid":{"rendered":"https:\/\/dev.academist-cf.com\/journal\/?p=3995"},"modified":"2017-03-30T10:23:15","modified_gmt":"2017-03-30T01:23:15","slug":"%e6%9c%89%e6%a9%9f%e5%90%88%e6%88%90%e5%8c%96%e5%ad%a6%e3%81%a7%e6%96%b0%e3%81%97%e3%81%84%e5%a4%89%e6%8f%9b%e3%82%92%e7%99%ba%e8%a6%8b%e3%81%99%e3%82%8b%e7%9e%ac%e9%96%93-%e7%9f%ad%e5%af%bf","status":"publish","type":"post","link":"https:\/\/academist-cf.com\/journal\/?p=3995","title":{"rendered":"\u6709\u6a5f\u5408\u6210\u5316\u5b66\u3067\u65b0\u3057\u3044\u5909\u63db\u3092\u767a\u898b\u3059\u308b\u77ac\u9593 – \u77ed\u5bff\u547d\u306e\u5408\u6210\u4e2d\u9593\u4f53\u300c\u30a2\u30e9\u30a4\u30f3\u300d\u306e\u65b0\u3057\u3044\u767a\u751f\u6cd5"},"content":{"rendered":"

\u300c\u30a2\u30e9\u30a4\u30f3\u300d\u5316\u5b66\u7a2e\u3092\u7d4c\u308b\u6709\u6a5f\u5408\u6210\u5316\u5b66<\/h3>\n

\u6709\u6a5f\u5408\u6210\u5316\u5b66\u3092\u5c02\u9580\u3068\u3059\u308b\u7814\u7a76\u8005\u306f\u3001\u30d1\u30ba\u30eb\u30b2\u30fc\u30e0\u306e\u3088\u3046\u306a\u30eb\u30fc\u30eb\u306e\u3082\u3068\u3001\u671b\u3080\u5206\u5b50\u3001\u3053\u308c\u307e\u3067\u306f\u5165\u624b\u3067\u304d\u306a\u304b\u3063\u305f\u5206\u5b50\u3092\u5408\u6210\u3059\u308b\u305f\u3081\u306e\u65b0\u624b\u6cd5\u3092\u3001\u65e5\u591c\u3001\u63a2\u7d22\u3057\u3066\u3044\u307e\u3059\u3002\u6771\u4eac\u533b\u79d1\u6b6f\u79d1\u5927\u5b66 \u751f\u4f53\u6750\u6599\u5de5\u5b66\u7814\u7a76\u6240 \u751f\u547d\u6709\u6a5f\u5316\u5b66\u5206\u91ce \u7d30\u8c37\u7814\u7a76\u5ba4\u306b\u304a\u3044\u3066\u3082\u3001\u533b\u6b6f\u85ac\u5b66\u7cfb\u306e\u30e9\u30a4\u30d5\u30b5\u30a4\u30a8\u30f3\u30b9\u7814\u7a76\u306b\u5f79\u7acb\u3064\u5316\u5408\u7269\u7fa4\u3092\u3001\u601d\u3044\u3082\u3088\u3089\u306c\u624b\u6cd5\u3067\u5408\u6210\u3067\u304d\u308b\u3088\u3046\u306a\u6709\u6a5f\u5316\u5b66\u306e\u7814\u7a76\u306b\u660e\u3051\u66ae\u308c\u3066\u3044\u307e\u3059\u3002\u3068\u304f\u306b\u3001\u30d9\u30f3\u30bc\u30f3\u74b0\u306e\u4e00\u90e8\u304c\u4e09\u91cd\u7d50\u5408\u306b\u306a\u3063\u305f\u300c\u30a2\u30e9\u30a4\u30f3\u300d\u304c\u3001\u5b89\u5b9a\u306a\u30d9\u30f3\u30bc\u30f3\u985e\u3068\u306f\u7570\u306a\u308a\u3001\u304d\u308f\u3081\u3066\u9ad8\u3044\u53cd\u5fdc\u6027\u3092\u793a\u3059\u77ed\u5bff\u547d\u5316\u5b66\u7a2e\u3067\u3042\u308b\u3053\u3068\u306b\u6ce8\u76ee\u3057\u3001\u305d\u306e\u53cd\u5fdc\u6027\u3092\u5236\u5fa1\u3057\u3001\u5229\u7528\u3059\u308b\u624b\u6cd5\u958b\u767a\u306b\u53d6\u308a\u7d44\u3093\u3067\u304d\u307e\u3057\u305f\u3002\u672c\u7a3f\u3067\u306f\u3001\u30a2\u30e9\u30a4\u30f3\u306e\u9b45\u529b\u306b\u3068\u308a\u3064\u304b\u308c\u305f\u4e00\u4eba\u3067\u3042\u308b\u535a\u58eb\u8ab2\u7a0b\u5b66\u751f\u306e\u5185\u7530\u3055\u3093\u304c\u3001\u65b0\u3057\u3044\u5909\u63db\u53cd\u5fdc\u3092\u898b\u3064\u3051\u305f\u77ac\u9593\u306b\u3064\u3044\u3066\u7d39\u4ecb\u3057\u307e\u3059\u3002<\/p>\n

\"\"<\/p>\n

\u65b0\u3057\u3044\u5909\u63db\u3092\u767a\u898b\u3059\u308b\u77ac\u9593<\/h3>\n

\u79c1\u305f\u3061\u306f\u4ee5\u524d\u306b\u3001\u4e09\u91cd\u7d50\u5408\u306b\u96a3\u63a5\u3059\u308b\u4f4d\u7f6e\u3067\u3042\u308b3\u4f4d\u306b\u30c8\u30ea\u30d5\u30ea\u30eb\u30aa\u30ad\u30b7\uff08OTf = OSO2<\/sub>CF3<\/sub>\uff09\u57fa\u3092\u6709\u3059\u308b\u30a2\u30e9\u30a4\u30f3\u306e\u767a\u751f\u30fb\u5909\u63db\u306b\u6210\u529f\u3057\u307e\u3057\u305f\u3002\u3053\u306e\u751f\u6210\u7269\u4e2d\u306eOTf\u57fa\u306f\u30d1\u30e9\u30b8\u30a6\u30e0\u89e6\u5a92\u306a\u3069\u3092\u7528\u3044\u308b\u30af\u30ed\u30b9\u30ab\u30c3\u30d7\u30ea\u30f3\u30b0\u306b\u5229\u7528\u3067\u304d\u308b\u3053\u3068\u306b\u52a0\u3048\u3001\u305d\u306e\u96fb\u5b50\u6c42\u5f15\u6027\u306e\u305f\u3081\u306b\u767a\u751f\u3057\u305f\u30a2\u30e9\u30a4\u30f3\u304c\u8208\u5473\u6df1\u3044\u53cd\u5fdc\u6027\u3092\u793a\u3059\u3053\u3068\u3082\u5831\u544a\u3057\u307e\u3057\u305f\u3002\u3053\u3046\u3044\u3063\u305f\u80cc\u666f\u306e\u3082\u3068\u3001\u5f53\u521d\u79c1\u305f\u3061\u306f\u3001\u30a2\u30eb\u30b3\u30fc\u30eb2\u3092\u7528\u3044\u308b\u5909\u63db\u53cd\u5fdc\u306b\u3064\u3044\u3066\u691c\u8a0e\u3057\u3066\u3044\u307e\u3057\u305f\u3002<\/p>\n

\"\"<\/p>\n

\u3053\u306e\u3068\u304d\u3001\u985e\u4f3c\u306e\u5316\u5408\u7269\u306e\u5408\u6210\u6cd5\u3092\u53c2\u8003\u306b\u3001\u30b1\u30c8\u30f31\u3068\u30d5\u30a7\u30cb\u30eb\u30ea\u30c1\u30a6\u30e0\u3068\u306e\u53cd\u5fdc\u3092\u884c\u3044\u3001\u30a2\u30eb\u30b3\u30fc\u30eb2\u306e\u5408\u6210\u3092\u8a66\u307f\u307e\u3057\u305f\u3002\u305d\u3046\u3057\u307e\u3059\u3068\u3001\u306a\u305c\u304b\u3001\u76ee\u7684\u3068\u3059\u308b\u30a2\u30eb\u30b3\u30fc\u30eb2\u3092\u5f97\u308b\u3053\u3068\u306f\u3067\u304d\u305a\u3001\u8907\u96d1\u306a\u6df7\u5408\u7269\u3068\u306a\u3063\u3066\u3057\u307e\u3057\u307e\u3057\u305f\u3002\u30a2\u30eb\u30b3\u30fc\u30eb2\u81ea\u4f53\u306f\u3001\u7528\u3044\u308b\u6709\u6a5f\u91d1\u5c5e\u53cd\u5fdc\u5264\u3092\u30d5\u30a7\u30cb\u30ebGrignard\u53cd\u5fdc\u5264\u3068\u3059\u308b\u3053\u3068\u3067\u5408\u6210\u3067\u304d\u305f\u306e\u3067\u3059\u304c\u3001\u3053\u3053\u3067\u3075\u3068\u8db3\u3092\u6b62\u3081\u3001\u300c\u306a\u305c\u3001\u30d5\u30a7\u30cb\u30eb\u30ea\u30c1\u30a6\u30e0\u3092\u7528\u3044\u305f\u5834\u5408\u306b\u306f\u30a2\u30eb\u30b3\u30fc\u30eb2\u304c\u5f97\u3089\u308c\u306a\u304b\u3063\u305f\u306e\u304b\u300d\u3092\u5185\u7530\u3055\u3093\u304c\u8003\u3048\u305f\u3053\u3068\u304c\u3001\u4eca\u56de\u306e\u767a\u898b\u306e\u304d\u3063\u304b\u3051\u3067\u3057\u305f\u3002<\/p>\n

\u77e2\u5370\u3092\u4f7f\u3063\u305f\u6709\u6a5f\u5316\u5b66\u306b\u304a\u3051\u308b\u5909\u63db\u306e\u8003\u3048\u65b9\u3092\u99c6\u4f7f\u3057\u3001\u3042\u3042\u3067\u3082\u306a\u3044\u3001\u3053\u3046\u3067\u3082\u306a\u3044\u3001\u3068\u601d\u6848\u3057\u3066\u3044\u308b\u3046\u3061\u306b\u3001\u5185\u7530\u3055\u3093\u304c\u601d\u3044\u3064\u3044\u305f\u306e\u306f\u3001\u300c\u70ad\u7d20\uff0d\u70ad\u7d20\u7d50\u5408\u306e\u5207\u65ad\u3092\u4f34\u3063\u3066\u3001\u30a2\u30e9\u30a4\u30f3\u304c\u751f\u3058\u3001\u3053\u308c\u304c\u8907\u96d1\u306a\u6df7\u5408\u7269\u3092\u4e0e\u3048\u305f\u539f\u56e0\u3067\u306f\u306a\u3044\u304b\u300d\u3068\u3044\u3046\u30a2\u30a4\u30c7\u30a3\u30a2\u3067\u3059\u3002\u3082\u3061\u308d\u3093\u3001\u70ad\u7d20\uff0d\u70ad\u7d20\u7d50\u5408\u306f\u4e00\u822c\u7684\u306b\u306f\u5f37\u3044\u7d50\u5408\u3067\u3059\u3057\u3001\u985e\u4f3c\u306e\u30a2\u30eb\u30b3\u30fc\u30eb\u306e\u5408\u6210\u4f8b\u3082\u77e5\u3089\u308c\u3066\u3044\u308b\u3053\u3068\u3082\u3042\u308a\u3001\u306f\u3058\u3081\u306f\u534a\u4fe1\u534a\u7591\u3002\u305f\u3060\u3001\u4eca\u56de\u306fOTf\u57fa\u3092\u6709\u3057\u3066\u3044\u308b\u3053\u3068\u3082\u3042\u308a\u3001\u65e2\u5831\u306e\u4f8b\u304b\u3089\u3060\u3051\u3067\u306f\u63a8\u3057\u91cf\u308c\u306a\u3044\u3068\u8003\u3048\u3066\u3001\u5185\u7530\u3055\u3093\u306f\u3001\u30a2\u30e9\u30a4\u30f3\u3092\u6355\u6349\u3067\u304d\u308b\u30d5\u30e9\u30f3\u5b58\u5728\u4e0b\u3067\u306e\u30b1\u30c8\u30f3\u3068\u30d5\u30a7\u30cb\u30eb\u30ea\u30c1\u30a6\u30e0\u3068\u306e\u53cd\u5fdc\u3092\u8a08\u753b\u3057\u3001\u65e9\u901f\u305d\u306e\u5b9f\u9a13\u3092\u5b9f\u884c\u3001\u3068\u30d5\u30c3\u30c8\u30ef\u30fc\u30af\u8efd\u304f\u52d5\u304d\u307e\u3057\u305f\u3002<\/p>\n

\u53cd\u5fdc\u306e\u9014\u4e2d\u7d4c\u904e\u3092\u3001\u65e9\u901f\u3001\u8584\u5c64\u30af\u30ed\u30de\u30c8\u30b0\u30e9\u30d5\u30a3\u30fc\uff08TLC\uff09\u3067\u8abf\u3079\u3066\u307f\u308b\u3068\u3001\u65b0\u3057\u3044\u30b9\u30dd\u30c3\u30c8\u304c\u30ad\u30ec\u30a4\u306b\u73fe\u308c\u3001\u03b1-\u30a2\u30ea\u30fc\u30eb\u30b1\u30c8\u30f33\u304c\u751f\u6210\u3057\u3066\u3044\u308b\u3053\u3068\u304c\u308f\u304b\u308a\u307e\u3057\u305f\u3002\u4e88\u60f3\u304c\u898b\u4e8b\u306b\u5f53\u305f\u3063\u305f\u308f\u3051\u3067\u3059\u3002\u5b9f\u9a13\u3092\u4ed5\u8fbc\u3093\u3067\u9593\u3082\u306a\u3044\u5185\u7530\u3055\u3093\u304c\u3001\u8208\u596e\u3057\u3066\u5831\u544a\u3057\u306b\u99c6\u3051\u8fbc\u3093\u3067\u304d\u3066\u304f\u308c\u305f\u3068\u304d\u306e\u69d8\u5b50\u3092\u9bae\u660e\u306b\u899a\u3048\u3066\u3044\u307e\u3059\u3002\u3053\u3046\u3044\u3063\u305f\u767a\u898b\u306e\u77ac\u9593\u304c\u3001\u79c1\u305f\u3061\u3092\u7814\u7a76\u306b\u75c5\u307f\u3064\u304d\u306b\u3055\u305b\u308b\u308f\u3051\u3067\u3059\u3002\u305d\u306e\u5f8c\u3001\u8a73\u7d30\u306b\u53cd\u5fdc\u6761\u4ef6\u3084\u57fa\u8cea\u9069\u7528\u7bc4\u56f2\u3092\u691c\u8a0e\u3057\u3001\u591a\u5f69\u306a\u03b1-\u30a2\u30ea\u30fc\u30eb\u30b1\u30c8\u30f3\u985e\u3092\u9ad8\u53ce\u7387\u3067\u5408\u6210\u3067\u304d\u308b\u3088\u3046\u306b\u306a\u308a\u307e\u3057\u305f\u3002<\/p>\n

\u5de7\u307f\u306e\u6280\u3067\u305d\u306e\u6a5f\u69cb\u3092\u660e\u3089\u304b\u306b<\/h3>\n

\u6b21\u306e\u8ab2\u984c\u306f\u3001\u4eca\u56de\u898b\u3064\u3051\u305f\u53cd\u5fdc\u306e\u8a73\u7d30\u306a\u53cd\u5fdc\u6a5f\u69cb\u3067\u3059\u3002\u3068\u304f\u306b\u3001\u4e00\u822c\u7684\u306b\u306f\u3001\u751f\u6210\u3057\u305f\u03b1-\u30a2\u30ea\u30fc\u30eb\u30b1\u30c8\u30f3\u985e\u306e\u53cd\u5fdc\u6027\u306f\u9ad8\u304f\u3001\u30a2\u30eb\u30ad\u30eb\u30ea\u30c1\u30a6\u30e0\u985e\u3068\u5bb9\u6613\u306b\u53cd\u5fdc\u3057\u3066\u3057\u307e\u3046\u3053\u3068\u304b\u3089\u3001\u300c\u306a\u305c\u9ad8\u53ce\u7387\u3067\u03b1-\u30a2\u30ea\u30fc\u30eb\u30b1\u30c8\u30f3\u985e\u3092\u5f97\u308b\u3053\u3068\u304c\u3067\u304d\u305f\u306e\u304b\uff1f\u300d\u304c\u8208\u5473\u6df1\u3044\u70b9\u3067\u3059\u3002\u3053\u306e\u554f\u3044\u306b\u5bfe\u3059\u308b\u7b54\u3048\u3092\u3001\u5185\u7530\u3055\u3093\u306e\u5de7\u307f\u306a\u5b9f\u9a13\u64cd\u4f5c\u306b\u3088\u3063\u3066\u5f97\u3089\u308c\u305f\u7d50\u679c\u304c\u6559\u3048\u3066\u304f\u308c\u307e\u3057\u305f\u3002\u3059\u306a\u308f\u3061\u3001\u30b1\u30c8\u30f31\u3068\u30d5\u30e9\u30f3\u306e\u6df7\u5408\u7269\u306b\u201378\u2103\u3067\u30d5\u30a7\u30cb\u30eb\u30ea\u30c1\u30a6\u30e0\u3092\u6ce8\u610f\u6df1\u304f\u52a0\u3048\u30011\u5206\u9593\u652a\u62cc\u5f8c\u3001\u3042\u3089\u304b\u3058\u3081\u201378\u2103\u306b\u51b7\u3084\u3057\u3066\u304a\u3044\u305f\u542b\u6c34THF\u3092\u52a0\u3048\u308b\u3001\u3068\u3044\u3046\u5b9f\u9a13\u64cd\u4f5c\u3067\u53cd\u5fdc\u958b\u59cb\u76f4\u5f8c\u306b\u53cd\u5fdc\u3092\u505c\u6b62\u3057\u3066\u307f\u307e\u3057\u305f\u3002<\/p>\n

\"\"<\/p>\n

\u3053\u306e\u3068\u304d\u3001\u53cd\u5fdc\u505c\u6b62\u6642\u306e\u6c34\u3067\u7cfb\u5185\u306e\u6e29\u5ea6\u304c\u4e0a\u304c\u3089\u306a\u3044\u3088\u3046\u306b\u5de5\u592b\u3059\u308b\u5fc5\u8981\u304c\u3042\u308a\u307e\u3057\u305f\u3002\u305d\u3046\u3059\u308b\u3068\u3001\u30b1\u30c8\u30f31\u3078\u306e\u30d5\u30a7\u30cb\u30eb\u30ea\u30c1\u30a6\u30e0\u306e\u4ed8\u52a0\u53cd\u5fdc\u306f\u3053\u306e\u6642\u70b9\u3067\u307b\u3068\u3093\u3069\u5b8c\u7d50\u3057\u3066\u304a\u308a\u3001\u4e3b\u306b\u30a2\u30eb\u30b3\u30fc\u30eb2\u304c\u5f97\u3089\u308c\u3066\u304d\u307e\u3057\u305f\u3002\u3057\u304b\u3082\u3001\u3054\u304f\u308f\u305a\u304b\u306a\u91cf\uff081%\uff09\u306e\u30a2\u30e9\u30a4\u30f3\u3068\u30d5\u30e9\u30f3\u3068\u306e\u74b0\u5316\u4ed8\u52a0\u4f533\u306b\u52a0\u3048\u3001\u70ad\u7d20\uff0d\u70ad\u7d20\u7d50\u5408\u304c\u5207\u308c\u3066\u304b\u3089\u30d7\u30ed\u30c8\u30f3\u5316\u3055\u308c\u305f\u751f\u6210\u72694\u304c\u5f97\u3089\u308c\u305f\u306e\u3067\u3059\u3002<\/p>\n

\u3055\u3089\u306b\u3001\u540c\u69d8\u306e\u5b9f\u9a13\u3092\u300110\u5206\u9593\u30011\u6642\u9593\u3068\u53cd\u5fdc\u6642\u9593\u3092\u5909\u66f4\u3057\u3001\u305d\u306e\u7d50\u679c\u3092\u4e26\u3079\u3066\u307f\u307e\u3057\u305f\u3002\u305d\u3046\u3059\u308b\u3068\u3001\u3053\u306e\u70ad\u7d20\uff0d\u70ad\u7d20\u7d50\u5408\u304c\u5207\u308c\u3066\u304b\u3089\u30d7\u30ed\u30c8\u30f3\u5316\u3055\u308c\u305f\u751f\u6210\u72694\u306e\u91cf\u304c\u6642\u9593\u7d4c\u904e\u306b\u5f93\u3063\u3066\u5897\u3048\u3066\u3044\u304f\u3053\u3068\u3082\u308f\u304b\u308a\u307e\u3057\u305f\u3002\u3053\u3046\u3044\u3063\u305f\u53cd\u5fdc\u6a5f\u69cb\u306b\u95a2\u3059\u308b\u5b9f\u9a13\u7d50\u679c\u304b\u3089\u3001\u4eca\u56de\u898b\u3064\u3051\u305f\u5909\u63db\u304c\u3001\u4f4e\u6e29\u306b\u304a\u3044\u3066\u901f\u3084\u304b\u306b\u30b1\u30c8\u30f31\u306b\u6709\u6a5f\u30ea\u30c1\u30a6\u30e0\u53cd\u5fdc\u5264\u304c\u4ed8\u52a0\u3057\u305f\u5f8c\u3001\u6607\u6e29\u3059\u308b\u306a\u304b\u3001\u70ad\u7d20\uff0d\u70ad\u7d20\u7d50\u5408\u306e\u5207\u65ad\u306b\u3088\u308b\u30ab\u30eb\u30dc\u30a2\u30cb\u30aa\u30f3\u306e\u751f\u6210\u3001\u5f15\u304d\u7d9a\u304f\u3001OTf\u57fa\u306e\u8131\u96e2\u306b\u3088\u308b\u30a2\u30e9\u30a4\u30f3\u306e\u767a\u751f\u3001\u30d5\u30e9\u30f3\u3068\u306e\u74b0\u5316\u4ed8\u52a0\u53cd\u5fdc\u3001\u3068\u3044\u3046\u6a5f\u69cb\u3067\u9032\u884c\u3059\u308b\u3053\u3068\u3092\u660e\u3089\u304b\u306b\u3067\u304d\u307e\u3057\u305f\u3002\u3053\u306e\u660e\u3089\u304b\u306b\u3067\u304d\u305f\u6a5f\u69cb\u3092\u3082\u3068\u306b\u3001\u30b7\u30ea\u30eb\u30a2\u30bb\u30bf\u30fc\u30eb\u306b\u30d5\u30c3\u5316\u7269\u30a4\u30aa\u30f3\u3092\u4f5c\u7528\u3055\u305b\u308b\u3053\u3068\u3067\u3082\u3001\u985e\u4f3c\u306e\u30a2\u30e9\u30a4\u30f3\u304c\u767a\u751f\u3059\u308b\u3053\u3068\u3082\u7a81\u304d\u6b62\u3081\u3001\u03b1-\u30a2\u30ea\u30fc\u30eb\u9162\u9178\u30a8\u30b9\u30c6\u30eb\u985e\u306e\u7c21\u4fbf\u5408\u6210\u6cd5\u306e\u958b\u767a\u306b\u3082\u6210\u529f\u3057\u307e\u3057\u305f\u3002<\/p>\n

\u3055\u3089\u306b\u3001\u3082\u3046\u4e00\u6ce2\u4e71<\/h3>\n

\u3053\u306e\u3088\u3046\u306b\u3001\u3046\u307e\u304f\u3044\u304b\u306a\u304b\u3063\u305f\u53cd\u5fdc\u304b\u3089\u30d2\u30f3\u30c8\u3092\u5f97\u3066\u3001\u65b0\u3057\u3044\u5909\u63db\u53cd\u5fdc\u3092\u898b\u3064\u3051\u308b\u3053\u3068\u304c\u3067\u304d\u307e\u3057\u305f\u3002\u3055\u3089\u306b\u3001\u4e01\u5be7\u306a\u5b9f\u9a13\u306b\u3088\u308a\u3001\u305d\u306e\u6a5f\u69cb\u89e3\u660e\u306b\u3082\u81f3\u308a\u3001\u65b0\u3057\u3044\u5909\u63db\u306e\u958b\u767a\u3078\u3068\u7814\u7a76\u3092\u5c55\u958b\u3059\u308b\u306b\u3082\u6210\u529f\u3057\u307e\u3057\u305f\u3002<\/p>\n

\u3053\u306e\u3088\u3046\u306a\u4e00\u9023\u306e\u5b9f\u9a13\u306b\u3001\u5185\u7530\u3055\u3093\u304c1\u5e74\u4ee5\u4e0a\u304b\u3051\u3066\u53d6\u308a\u7d44\u307f\u3001\u5f97\u3089\u308c\u3066\u304d\u305f\u6210\u679c\u3092\u8ad6\u6587\u306b\u307e\u3068\u3081\u308b\u306a\u304b\u30012017\u5e74\u306e\u306f\u3058\u3081\u306b\u3082\u3046\u4e00\u6ce2\u4e71\u3042\u308a\u307e\u3057\u305f\u3002\u304a\u6b63\u6708\u306b\u8ad6\u6587\u30c1\u30a7\u30c3\u30af\u3092\u3057\u3066\u3044\u305f\u3001\u3053\u306e4\u6708\u304b\u3089\u535a\u58eb\u8ab2\u7a0b\u306b\u9032\u3080\u4e2d\u6751\u3055\u3093\u304b\u3089\u3001\u300c\u5185\u7530\u3055\u3093\u306e\u7cfb\u3068\u540c\u3058\u3088\u3046\u306a\u5909\u63db\u304c\u5831\u544a\u3055\u308c\u3066\u307e\u3059\uff01\uff01\u300d\u3068\u3044\u3046\u4e00\u5831\u304c\u5165\u3063\u305f\u306e\u3067\u3059\u3002\u30a2\u30e1\u30ea\u30ab\u5316\u5b66\u4f1a\u8a8c\uff08J.Am.Chem.Soc.\uff09\u306eJust Accepted\u3068\u3044\u3046\u65b0\u7740\u306e\u6821\u6b63\u524d\u539f\u7a3f\u306b\u3001\u5185\u7530\u3055\u3093\u304c\u898b\u3064\u3051\u305f\u5909\u63db\u3068\u985e\u4f3c\u306e\u5909\u63db\u304c\u5831\u544a\u3055\u308c\u3066\u3044\u308b\u3001\u3068\u8a00\u3046\u306e\u3067\u3059\u3002\u6025\u3044\u3067\u5185\u5bb9\u3092\u30c1\u30a7\u30c3\u30af\u3057\u3001\u985e\u4f3c\u3067\u306f\u3042\u308b\u3082\u306e\u306e\u65b0\u898f\u6027\u304c\u5931\u308f\u308c\u3066\u306f\u3044\u306a\u3044\u3053\u3068\u3092\u78ba\u8a8d\u3057\u307e\u3057\u305f\u3002\u305d\u306e\u5f8c\u3001\u304a\u6b63\u6708\u4f11\u307f\u660e\u3051\u306e\u5185\u7530\u3055\u3093\u30683\u4eba\u3067\u6253\u3061\u5408\u308f\u305b\u3092\u3057\u3001\u8d85\u7279\u6025\u3067\u8ad6\u6587\u3092\u4ed5\u4e0a\u3052\u3001\u6295\u7a3f\u3001\u3068\u30c9\u30bf\u30d0\u30bf\u3067\u9032\u3093\u3067\u3044\u304d\u307e\u3057\u305f\u3002\u3068\u3066\u3082\u9762\u767d\u3044\u6210\u679c\u306b\u6c17\u3092\u826f\u304f\u3057\u3066\u3044\u305f\u6642\u671f\u306b\u3001\u305d\u306e\u6162\u5fc3\u3092\u8acc\u3081\u3089\u308c\u305f\u3088\u3046\u306a\u3001\u305d\u3093\u306a\u5c55\u958b\u30672017\u5e74\u304c\u59cb\u307e\u3063\u305f\u308f\u3051\u3067\u3059\u3002<\/p>\n

\u305d\u306e\u5f8c\u3001\u5be9\u67fb\u7d50\u679c\u304c\u8fd4\u3063\u3066\u304d\u3066\u3001\u3044\u304f\u3064\u304b\u306e\u8ffd\u52a0\u5b9f\u9a13\u306e\u7d50\u679c\u3092\u52a0\u3048\u3066\u518d\u6295\u7a3f\u3068\u9032\u307f\u3001\u7121\u4e8b\u306b\u6210\u679c\u3092\u516c\u958b\u3059\u308b\u6bb5\u968e\u306b\u307e\u3067\u5230\u9054\u3057\u307e\u3057\u305f\u3002\u7d06\u4f59\u66f2\u6298\u3042\u308a\u3001\u5b9f\u969b\u306b\u8ad6\u6587\u3092\u8aad\u3093\u3067\u304f\u3060\u3055\u3063\u305f\u65b9\u3005\u306e\u76ee\u306b\u306f\u79c1\u305f\u3061\u306e\u898b\u3064\u3051\u305f\u5909\u63db\u304c\u3069\u3046\u6620\u308b\u306e\u304b\u3001\u3088\u304f\u308f\u304b\u308a\u307e\u305b\u3093\u304c\u3001\u3044\u308d\u3044\u308d\u306a\u601d\u3044\u51fa\u306e\u8a70\u307e\u3063\u305f\u8ad6\u6587\u306b\u306a\u308a\u307e\u3057\u305f\u3002\u3053\u306e\u5909\u63db\u3067\u5f97\u3089\u308c\u305f\u8cb4\u91cd\u306a\u77e5\u898b\u306f\u3001\u591a\u5f69\u306a\u5c55\u958b\u306b\u3064\u306a\u304c\u3063\u3066\u3044\u304f\u306f\u305a\u3067\u3059\u306e\u3067\u3001\u4eca\u5f8c\u306e\u79c1\u305f\u3061\u306e\u5316\u5b66\u306b\u671f\u5f85\u3057\u3066\u304f\u3060\u3055\u308b\u65b9\u304c\u304a\u308a\u307e\u3057\u305f\u3089\u5e78\u3044\u3067\u3059\u3002<\/p>\n

<\/p>\n

\u53c2\u8003\u6587\u732e<\/strong>
\nS. Yoshida, K. Uchida, K. Igawa, K. Tomooka, T. Hosoya: Chem. Commun., 50, 15059 (2014).
\nK. Uchida, S. Yoshida, T. Hosoya: Synthesis, 48, 4099 (2016).
\nK. Uchida, S. Yoshida, T. Hosoya: Org. Lett., 19, 1184 (2017).<\/p>\n","protected":false},"excerpt":{"rendered":"

\u300c\u30a2\u30e9\u30a4\u30f3\u300d\u5316\u5b66\u7a2e\u3092\u7d4c\u308b\u6709\u6a5f\u5408\u6210\u5316\u5b66 \u6709\u6a5f\u5408\u6210\u5316\u5b66\u3092\u5c02\u9580\u3068\u3059\u308b\u7814\u7a76\u8005\u306f\u3001\u30d1\u30ba\u30eb\u30b2\u30fc\u30e0\u306e\u3088\u3046\u306a\u30eb\u30fc\u30eb\u306e\u3082\u3068\u3001\u671b\u3080\u5206\u5b50\u3001\u3053\u308c\u307e\u3067\u306f\u5165\u624b\u3067\u304d\u306a\u304b\u3063\u305f\u5206\u5b50\u3092\u5408\u6210\u3059\u308b\u305f\u3081\u306e\u65b0\u624b\u6cd5\u3092\u3001\u65e5\u591c\u3001\u63a2\u7d22\u3057\u3066\u3044\u307e\u3059\u3002\u6771\u4eac\u533b […]<\/p>\n","protected":false},"author":111,"featured_media":3996,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_acf_changed":false,"_monsterinsights_skip_tracking":false,"_monsterinsights_sitenote_active":false,"_monsterinsights_sitenote_note":"","_monsterinsights_sitenote_category":0,"footnotes":""},"categories":[3],"tags":[20],"class_list":["post-3995","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-outcome","tag-20","has_thumb"],"acf":[],"aioseo_notices":[],"_links":{"self":[{"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=\/wp\/v2\/posts\/3995","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=\/wp\/v2\/users\/111"}],"replies":[{"embeddable":true,"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=3995"}],"version-history":[{"count":0,"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=\/wp\/v2\/posts\/3995\/revisions"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=\/wp\/v2\/media\/3996"}],"wp:attachment":[{"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=3995"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=3995"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=3995"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}