{"id":16134,"date":"2021-06-28T08:00:56","date_gmt":"2021-06-27T23:00:56","guid":{"rendered":"https:\/\/academist-cf.com\/journal\/?p=16134"},"modified":"2021-10-22T17:43:04","modified_gmt":"2021-10-22T08:43:04","slug":"%e7%94%9f%e7%89%a9%e3%81%ae%e5%a4%9a%e6%a7%98%e3%81%aa%e5%bd%a2%e7%8a%b6%e3%81%ae%e8%b5%b7%e6%ba%90%e3%81%a8%e3%81%af%ef%bc%9f-%e9%9b%86%e5%90%88%e4%bd%93%e3%81%ae%e5%bd%a2%e3%81%af%e5%88%86","status":"publish","type":"post","link":"https:\/\/academist-cf.com\/journal\/?p=16134","title":{"rendered":"\u751f\u7269\u306e\u591a\u69d8\u306a\u5f62\u72b6\u306e\u8d77\u6e90\u3068\u306f\uff1f &#8211; \u96c6\u5408\u4f53\u306e\u5f62\u306f\u5206\u5b50\u8a8d\u8b58\u76f8\u4e92\u4f5c\u7528\u306e\u5f37\u3055\u3067\u6c7a\u307e\u308b"},"content":{"rendered":"<h3>\u5206\u5b50\u8a8d\u8b58\u306b\u3088\u3063\u3066\u5f62\u6210\u3055\u308c\u308b\u96c6\u5408\u4f53\u306e\u5f62\u306f\u3069\u306e\u3088\u3046\u306b\u6c7a\u307e\u308b\u304b\uff1f<\/h3>\n<p>\u751f\u7269\u306e\u3055\u307e\u3056\u307e\u306a\u5f62\u306f\u3001\u7d30\u80de\u540c\u58eb\u304c\u305d\u306e\u8868\u9762\u306b\u5b58\u5728\u3059\u308b\u5206\u5b50\u306e\u5206\u5b50\u8a8d\u8b58\u3092\u4ecb\u3057\u3066\u3001\u7279\u5b9a\u306e\u4f4d\u7f6e\u3084\u914d\u5217\u3067\u96c6\u5408\uff08\u81ea\u5df1\u7d44\u7e54\u5316\uff09\u3059\u308b\u3053\u3068\u306b\u3088\u308a\u5f62\u6210\u3055\u308c\u307e\u3059\u3002\u751f\u4f53\u306f\u3001\u3053\u306e\u5206\u5b50\u8a8d\u8b58\u306b\u57fa\u3065\u3044\u305f\u81ea\u5df1\u7d44\u7e54\u5316\u306b\u3088\u3063\u3066\u5f62\u6210\u3055\u308c\u308b\u5de8\u8996\u7684\u96c6\u5408\u4f53\u3067\u3059\u3002\u751f\u4f53\u7cfb\u306e\u5de8\u8996\u7684\u96c6\u5408\u4f53\u306b\u89e6\u767a\u3055\u308c\u3001\u591a\u304f\u306e\u7814\u7a76\u30b0\u30eb\u30fc\u30d7\u304c\u5206\u5b50\u8a8d\u8b58\u3092\u57fa\u76e4\u3068\u3059\u308b\u30b9\u30de\u30fc\u30c8\u6750\u6599\u3092\u958b\u767a\u3057\u3066\u3044\u307e\u3059\u3002<\/p>\n<p>\u4ee5\u524d\u3001\u79c1\u305f\u3061\u306f\u5206\u5b50\u8a8d\u8b58\u90e8\u4f4d\u3068\u3057\u3066\u74b0\u72b6\u30aa\u30ea\u30b4\u7cd6\u3067\u3042\u308b\u30b7\u30af\u30ed\u30c7\u30ad\u30b9\u30c8\u30ea\u30f3 (CD) \u6b8b\u57fa\u3068\u3001CD\u306e\u7a7a\u6d1e\u306b\u53d6\u308a\u8fbc\u307e\u308c\u308b\u30b2\u30b9\u30c8\u90e8\u4f4d\u3092\u5c0e\u5165\u3057\u305f\u30df\u30ea\u30e1\u30fc\u30c8\u30eb\u30b9\u30b1\u30fc\u30eb\u306e\u30dd\u30ea\u30a2\u30af\u30ea\u30eb\u30a2\u30df\u30c9\u30d2\u30c9\u30ed\u30b2\u30eb\u3092\u7528\u3044\u308b\u3053\u3068\u306b\u3088\u3063\u3066\u3001\u5206\u5b50\u8a8d\u8b58\u3092\u8089\u773c\u3067\u89b3\u5bdf\u3059\u308b\u3053\u3068\u306b\u4e16\u754c\u3067\u521d\u3081\u3066\u6210\u529f\u3057\u307e\u3057\u305f\u3002\u305d\u306e\u7814\u7a76\u306e\u904e\u7a0b\u3067\u3001\u5206\u5b50\u8a8d\u8b58\u90e8\u4f4d\u306e\u76f8\u4e92\u4f5c\u7528\u304c\u5f37\u3044\u5834\u5408\u306b\u306f\u30b2\u30eb\u306f\u4ea4\u4e92\u306e\u7dda\u72b6\u96c6\u5408\u4f53\u3092\u5f62\u6210\u3059\u308b\u306e\u306b\u5bfe\u3057\u3001\u5206\u5b50\u8a8d\u8b58\u90e8\u4f4d\u306e\u76f8\u4e92\u4f5c\u7528\u304c\u5f31\u3044\u5834\u5408\u306b\u306f\u30c1\u30a7\u30c3\u30af\u6a21\u69d8\u306e\u9762\u72b6\u96c6\u5408\u4f53\u304c\u5f62\u6210\u3059\u308b\u50be\u5411\u3092\u793a\u3059\u3053\u3068\u306b\u6c17\u3065\u304d\u307e\u3057\u305f\u3002<\/p>\n<p>\u305d\u3053\u3067\u79c1\u305f\u3061\u306f\u96c6\u5408\u4f53\u306e\u5f62\u72b6\u3068\u76f8\u4e92\u4f5c\u7528\u306e\u5f37\u3055\u306e\u76f8\u95a2\u95a2\u4fc2\u3092\u8abf\u3079\u308b\u305f\u3081\u306b\u3001\u5316\u5b66\u7684\u306b\u4fee\u98fe\u3059\u308b\u3053\u3068\u304c\u5bb9\u6613\u3067\u5165\u624b\u3057\u3084\u3059\u3044\u7c92\u5f84200 \u03bcm\u7a0b\u5ea6\u306e\u9ad8\u5438\u6c34\u6027\u30dd\u30ea\u30de\u30fc (SAP) \u306e\u7403\u72b6\u30de\u30a4\u30af\u30ed\u7c92\u5b50\u306b\u7740\u76ee\u3057\u307e\u3057\u305f\u3002\u3053\u306e\u8a18\u4e8b\u3067\u306f\u3001SAP\u30de\u30a4\u30af\u30ed\u7c92\u5b50\u306b\u03b2-\u30b7\u30af\u30ed\u30c7\u30ad\u30b9\u30c8\u30ea\u30f3 (\u03b2CD) \u6b8b\u57fa\u3068\u30a2\u30c0\u30de\u30f3\u30bf\u30f3 (Ad) \u6b8b\u57fa\u3092\u5c0e\u5165\u3057\u3001\u305d\u306eSAP\u30de\u30a4\u30af\u30ed\u7c92\u5b50\u306e\u76f8\u4e92\u4f5c\u7528\u3068\u5f97\u3089\u308c\u305f\u96c6\u5408\u4f53\u306e\u5f62\u72b6\u3092\u8abf\u67fb\u3057\u305f\u7814\u7a76\u306b\u3064\u3044\u3066\u7d39\u4ecb\u3057\u307e\u3059\u3002<\/p>\n<h3>\u5206\u5b50\u8a8d\u8b58\u306b\u57fa\u3065\u3044\u305f\u30de\u30a4\u30af\u30ed\u7c92\u5b50\u306e\u96c6\u5408\u4f53\u5f62\u6210<\/h3>\n<p>\u03b2CD\u6b8b\u57fa\u3068Ad\u6b8b\u57fa\u3092\u5c0e\u5165\u3057\u305f\u03b2CD(<em>x<\/em>)-SAP\u30de\u30a4\u30af\u30ed\u7c92\u5b50\u3001Ad(<em>y<\/em>)-SAP\u30de\u30a4\u30af\u30ed\u7c92\u5b50\u3092\u6e96\u5099\u3057\u3001\u4e21\u8005\u3092\u8b58\u5225\u3059\u308b\u305f\u3081\u306bAd(<em>y<\/em>)-SAP\u30de\u30a4\u30af\u30ed\u7c92\u5b50\u3092\u30d1\u30e9\u30ed\u30fc\u30ba\u30a2\u30cb\u30ea\u30f3\u3068\u3044\u3046\u8d64\u8272\u8272\u7d20\u3067\u67d3\u8272\u3057\u307e\u3057\u305f\u3002<\/p>\n<p>\u3053\u3053\u3067\u3001<em>x<\/em>\u3068<em>y<\/em>\u306f\u03b2CD\u6b8b\u57fa\u3068Ad\u6b8b\u57fa\u306eSAP\u30de\u30a4\u30af\u30ed\u7c92\u5b50\u3078\u306e\u5c0e\u5165\u7387\u3092\u793a\u3057\u307e\u3059\u3002<em>x<\/em> = 16.2, 22.3, 26.7 mol%\u306e3\u7a2e\u985e\u306e\u03b2CD(<em>x<\/em>)-SAP\u30de\u30a4\u30af\u30ed\u7c92\u5b50\u3068\u3001<em>y<\/em> = 5.2, 7.1, 10.7, 15.1 mol% \u306e4\u7a2e\u985e\u306eAd(<em>y<\/em>)-SAP\u30de\u30a4\u30af\u30ed\u7c92\u5b50\u3092\u8abf\u88fd\u3057\u3066\u7528\u3044\u307e\u3057\u305f\u3002<\/p>\n<figure id=\"attachment_16138\" aria-describedby=\"caption-attachment-16138\" style=\"width: 600px\" class=\"wp-caption aligncenter\"><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-16138\" src=\"https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2021\/06\/001-2.jpg\" alt=\"\" width=\"600\" height=\"415\" srcset=\"https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2021\/06\/001-2.jpg 600w, https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2021\/06\/001-2-300x208.jpg 300w\" sizes=\"auto, (max-width: 600px) 100vw, 600px\" \/><figcaption id=\"caption-attachment-16138\" class=\"wp-caption-text\">\u03b2-\u30b7\u30af\u30ed\u30c7\u30ad\u30b9\u30c8\u30ea\u30f3 (\u03b2CD) \u6b8b\u57fa\u3068\u30a2\u30c0\u30de\u30f3\u30bf\u30f3 (Ad) \u6b8b\u57fa\u3092\u5c0e\u5165\u3057\u305f\u9ad8\u5438\u6c34\u6027\u30dd\u30ea\u30de\u30fc\u30de\u30a4\u30af\u30ed\u7c92\u5b50 (\u03b2CD(<em>x<\/em>)-SAP, Ad(<em>y<\/em>)-SAP) \u306e\u5316\u5b66\u69cb\u9020\u3068\u5149\u5b66\u9855\u5fae\u93e1\u5199\u771f\u3002<em>x<\/em>\u3068<em>y<\/em>\u306f\u03b2CD\u6b8b\u57fa\u3068Ad\u6b8b\u57fa\u306e\u5c0e\u5165\u7387\u3002Ad(<em>y<\/em>)-SAP\u30de\u30a4\u30af\u30ed\u7c92\u5b50\u306f\u30d1\u30e9\u30ed\u30fc\u30ba\u30a2\u30cb\u30ea\u30f3\u3067\u67d3\u8272\u3002<\/figcaption><\/figure>\n<p>\u03b2CD(<em>x<\/em>)-SAP\u30de\u30a4\u30af\u30ed\u7c92\u5b50\u3068Ad(<em>y<\/em>)-SAP\u30de\u30a4\u30af\u30ed\u7c92\u5b50\u306e\u76f8\u4e92\u4f5c\u7528\u3092\u8abf\u67fb\u3059\u308b\u305f\u3081\u3001\u305d\u308c\u305e\u308c\u306e\u61f8\u6fc1\u6db2\u3092\u6df7\u5408\u3057\u307e\u3057\u305f\u3002\u4eca\u56de\u4f7f\u7528\u3057\u305fSAP\u30de\u30a4\u30af\u30ed\u7c92\u5b50\u306f\u6bd4\u8f03\u7684\u5927\u304d\u304f\u3001\u307b\u3068\u3093\u3069\u30d6\u30e9\u30a6\u30f3\u904b\u52d5\u3057\u306a\u3044\u305f\u3081\u3001\u30d4\u30f3\u30bb\u30c3\u30c8\u3092\u7528\u3044\u3066\u6df7\u305c\u305f\u308a\u3001\u64b9\u62cc\u5668\u3067\u6df7\u5408\u3057\u305f\u308a\u3059\u308b\u3053\u3068\u3067\u96c6\u5408\u4f53\u304c\u5f62\u6210\u3055\u308c\u308b\u304b\u3069\u3046\u304b\u3092\u8abf\u67fb\u3057\u307e\u3057\u305f\u3002<\/p>\n<p>\u03b2CD(16.2)-SAP\u30de\u30a4\u30af\u30ed\u7c92\u5b50\u3068\u03b2CD(22.3)-SAP\u30de\u30a4\u30af\u30ed\u7c92\u5b50\u306f\u3001\u4eca\u56de\u7528\u3044\u305f\u5168\u3066\u306eAd(<em>y<\/em>)-SAP\u30de\u30a4\u30af\u30ed\u7c92\u5b50\u3068\u306f\u96c6\u5408\u4f53\u3092\u5f62\u6210\u3057\u307e\u305b\u3093\u3067\u3057\u305f\u304c\u3001\u03b2CD(26.7)-SAP\u30de\u30a4\u30af\u30ed\u7c92\u5b50\u306f\u3059\u3079\u3066\u306eAd(<em>y<\/em>)-SAP\u30de\u30a4\u30af\u30ed\u7c92\u5b50\u3068\u96c6\u5408\u4f53\u3092\u5f62\u6210\u3057\u307e\u3057\u305f\u3002\u3053\u306e\u7d50\u679c\u306f\u3001\u96c6\u5408\u4f53\u5f62\u6210\u306e\u305f\u3081\u306e\u03b2CD\u6b8b\u57fa\u306e\u5c0e\u5165\u91cf\u306e\u95be\u5024\u304c22.3\u306826.7 mol%\u306e\u3042\u3044\u3060\u306b\u3042\u308b\u3053\u3068\u3092\u793a\u3057\u3066\u3044\u307e\u3059\u3002<\/p>\n<h3>\u30de\u30a4\u30af\u30ed\u7c92\u5b50\u306e\u5206\u5b50\u8a8d\u8b58\u76f8\u4e92\u4f5c\u7528\u306e\u5f37\u3055<\/h3>\n<p>\u4ee5\u524d\u306e\u79c1\u305f\u3061\u306e\u30d2\u30c9\u30ed\u30b2\u30eb\u306b\u3088\u308b\u5de8\u8996\u7684\u96c6\u5408\u4f53\u306e\u7814\u7a76\u3067\u306f\u3001\u5f15\u3063\u5f35\u308a\u8a66\u9a13\u6a5f\u3067\u5f97\u3089\u308c\u305f\u96c6\u5408\u4f53\u306e\u7834\u65ad\u5f37\u5ea6\u3092\u6e2c\u5b9a\u3059\u308b\u3053\u3068\u304c\u53ef\u80fd\u3067\u3001\u305d\u306e\u7d50\u679c\u304b\u3089\u76f8\u4e92\u4f5c\u7528\u306e\u5f37\u3055\u3092\u8a55\u4fa1\u3059\u308b\u3053\u3068\u304c\u3067\u304d\u307e\u3057\u305f\u3002\u3057\u304b\u3057\u3001\u4eca\u56de\u306f\u5f15\u3063\u5f35\u308a\u8a66\u9a13\u6a5f\u3092\u7528\u3044\u308b\u3053\u3068\u304c\u3067\u304d\u306a\u3044\u305f\u3081\u306bSAP\u30de\u30a4\u30af\u30ed\u7c92\u5b50\u540c\u58eb\u306e\u76f8\u4e92\u4f5c\u7528\u306e\u5f37\u3055\u3092\u6bd4\u8f03\u3059\u308b\u3053\u3068\u306f\u56f0\u96e3\u3067\u3057\u305f\u3002\u305f\u3068\u3048\u3070\u3001\u96c6\u5408\u4f53\u5f62\u6210\u306e\u6240\u8981\u6642\u9593\u3092\u8a08\u6e2c\u3057\u305f\u308a\u3001\u96c6\u5408\u4f53\u306e\u5f62\u6210\u904e\u7a0b\u306e\u89b3\u5bdf\u3092\u8a66\u307f\u305f\u308a\u3057\u307e\u3057\u305f\u304c\u3001\u76f8\u4e92\u4f5c\u7528\u306e\u5f37\u3055\u3092\u8a55\u4fa1\u3059\u308b\u3053\u3068\u306f\u3067\u304d\u307e\u305b\u3093\u3067\u3057\u305f\u3002<\/p>\n<p>\u6700\u7d42\u7684\u306b\u306f\u3001SAP\u30de\u30a4\u30af\u30ed\u7c92\u5b50\u540c\u58eb\u306e\u76f8\u4e92\u4f5c\u7528\u3092\u963b\u5bb3\u3059\u308b\u7af6\u4e89\u5206\u5b50\u3001\u3059\u306a\u308f\u3061\u03b2CD\u3068\u30a2\u30c0\u30de\u30f3\u30bf\u30f3\u30ab\u30eb\u30dc\u30f3\u9178\u30ca\u30c8\u30ea\u30a6\u30e0\u3092\u6dfb\u52a0\u3057\u305f\u969b\u306b\u3001\u96c6\u5408\u4f53\u3092\u69cb\u6210\u3059\u308bSAP\u30de\u30a4\u30af\u30ed\u7c92\u5b50\u306e\u6570\u3092\u8a08\u6e2c\u3057\u3001\u5358\u7d14\u5316\u3057\u305f\u30e2\u30c7\u30eb\u3092\u7528\u3044\u3066\u89e3\u6790\u3059\u308b\u3053\u3068\u3067\u3001SAP\u30de\u30a4\u30af\u30ed\u7c92\u5b50\u540c\u58eb\u306e\u76f8\u4e92\u4f5c\u7528\u306e\u5f37\u3055\u3092\u6bd4\u8f03\u3059\u308b\u3053\u3068\u304c\u3067\u304d\u307e\u3057\u305f\u3002<\/p>\n<p>\u4e88\u60f3\u901a\u308a\u3001\u30a2\u30c0\u30de\u30f3\u30bf\u30f3\u6b8b\u57fa\u5c0e\u5165\u7387<em>y<\/em>\u306e\u9ad8\u3044Ad(<em>y<\/em>)-SAP\u30de\u30a4\u30af\u30ed\u7c92\u5b50\u307b\u3069\u03b2CD(26.7)-SAP\u30de\u30a4\u30af\u30ed\u7c92\u5b50\u3068\u5f37\u304f\u76f8\u4e92\u4f5c\u7528\u3059\u308b\u3053\u3068\u304c\u308f\u304b\u308a\u307e\u3057\u305f\u3002<\/p>\n<figure id=\"attachment_16139\" aria-describedby=\"caption-attachment-16139\" style=\"width: 600px\" class=\"wp-caption aligncenter\"><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-16139\" src=\"https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2021\/06\/002-2.jpg\" alt=\"\" width=\"600\" height=\"322\" srcset=\"https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2021\/06\/002-2.jpg 600w, https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2021\/06\/002-2-300x161.jpg 300w\" sizes=\"auto, (max-width: 600px) 100vw, 600px\" \/><figcaption id=\"caption-attachment-16139\" class=\"wp-caption-text\">\u03b2CD(<em>x<\/em>)-SAP\u30de\u30a4\u30af\u30ed\u7c92\u5b50\u3068Ad(<em>y<\/em>)-SAP\u30de\u30a4\u30af\u30ed\u7c92\u5b50\u304b\u3089\u5f62\u6210\u3055\u308c\u305f\u96c6\u5408\u4f53\u306e\u5149\u5b66\u9855\u5fae\u93e1\u5199\u771f\u3002\u03b2CD\u6b8b\u57fa\u306e\u5c0e\u5165\u7387<em>x<\/em>\u306f26.7 mol%\u3001Ad\u6b8b\u57fa\u306e\u5c0e\u5165\u7387<em>y<\/em>\u306f5.2 mol%\u306815.1 mol%\u3002<\/figcaption><\/figure>\n<h3>\u30de\u30a4\u30af\u30ed\u7c92\u5b50\u96c6\u5408\u4f53\u306e\u5f62\u72b6\u3068\u5206\u5b50\u8a8d\u8b58\u76f8\u4e92\u4f5c\u7528\u306e\u5f37\u3055\u306e\u95a2\u4fc2<\/h3>\n<p>\u6b21\u306b\u79c1\u305f\u3061\u306f\u3001\u03b2CD(26.7)-SAP\u30de\u30a4\u30af\u30ed\u7c92\u5b50\u3068Ad(<em>y<\/em>)-SAP\u30de\u30a4\u30af\u30ed\u7c92\u5b50\u304c\u5f62\u6210\u3059\u308b\u96c6\u5408\u4f53\u306e\u5f62\u72b6\u3092\u6bd4\u8f03\u3059\u308b\u65b9\u6cd5\u3092\u691c\u8a0e\u3057\u307e\u3057\u305f\u3002<\/p>\n<p>\u306f\u3058\u3081\u306b\u3001\u3072\u3068\u3064\u306e\u30de\u30a4\u30af\u30ed\u7c92\u5b50\u304c\u63a5\u89e6\u3059\u308b\u30de\u30a4\u30af\u30ed\u7c92\u5b50\u306e\u6570\u3067\u3042\u308b\u914d\u4f4d\u6570\u306b\u7740\u76ee\u3057\u307e\u3057\u305f\u3002\u4e00\u6b21\u5143\u306b\u4f38\u3073\u305f\u96c6\u5408\u4f53\u306e\u5834\u5408\u3001\u914d\u4f4d\u6570\u306f2\u3068\u306a\u308a\u3001\u5e73\u9762\u72b6\u96c6\u5408\u4f53\u306a\u3089\u30704\u30846\u3068\u306a\u308b\u306f\u305a\u3067\u3059\u3002\u3057\u304b\u3057\u3001\u7c92\u5b50\u6570\u304c\u591a\u304f\u624b\u9593\u304c\u304b\u304b\u308b\u305f\u3081\u3001\u914d\u4f4d\u6570\u306e\u6c7a\u5b9a\u306f\u73fe\u5b9f\u7684\u3067\u306f\u3042\u308a\u307e\u305b\u3093\u3067\u3057\u305f\u3002\u3057\u305f\u304c\u3063\u3066\u3001\u6bd4\u8f03\u7684\u826f\u304f\u5229\u7528\u3055\u308c\u3066\u3044\u308b\u753b\u50cf\u306e\u6955\u5186\u8fd1\u4f3c\u306b\u3088\u308a\u9577\u8ef8 (<em>a<\/em>) \u3068\u77ed\u8ef8 (<em>b<\/em>) \u306e\u6bd4\u3001\u3064\u307e\u308a\u30a2\u30b9\u30da\u30af\u30c8\u6bd4 (<em>a\/b<\/em>) \u3092\u7528\u3044\u3066\u96c6\u5408\u4f53\u306e\u5f62\u72b6\u3092\u8a55\u4fa1\u3059\u308b\u3053\u3068\u306b\u3057\u307e\u3057\u305f\u3002<\/p>\n<p>\u540c\u3058\u5b9f\u9a13\u30923\u56de\u7e70\u308a\u8fd4\u3057\u3066<em>a\/b<\/em>\u3092\u6c7a\u5b9a\u3057\u3001\u305d\u306e\u5e73\u5747\u5024\u3092<em>y<\/em>\u306b\u5bfe\u3057\u3066\u30d7\u30ed\u30c3\u30c8\u3059\u308b\u3068\u3001<em>y<\/em>\u304c5.1 mol%\u304b\u308915.1 mol%\u307e\u3067\u5897\u52a0\u3059\u308b\u3068\u3068\u3082\u306b\u3001\u30a2\u30b9\u30da\u30af\u30c8\u6bd4<em>a\/b<\/em>\u306f1.6\u304b\u30892.8\u307e\u3067\u5897\u52a0\u3059\u308b\u50be\u5411\u3092\u793a\u3057\u307e\u3057\u305f\u3002<\/p>\n<p>\u5148\u306b\u8ff0\u3079\u305f\u3088\u3046\u306b\u3001<em>y<\/em>\u306e\u5897\u52a0\u3068\u3068\u3082\u306bSAP\u30de\u30a4\u30af\u30ed\u7c92\u5b50\u540c\u58eb\u306e\u76f8\u4e92\u4f5c\u7528\u304c\u5f37\u304f\u306a\u308b\u305f\u3081\u3001\u76f8\u4e92\u4f5c\u7528\u304c\u5f37\u3044\u5834\u5408\u306b\u306f\u4f38\u3073\u305f\u96c6\u5408\u4f53\u3092\u5f62\u6210\u3057\u3001\u76f8\u4e92\u4f5c\u7528\u304c\u5f31\u3044\u5834\u5408\u306b\u306f\u5e73\u9762\u7684\u306a\u96c6\u5408\u4f53\u3092\u5f62\u6210\u3059\u308b\u3053\u3068\u304c\u660e\u3089\u304b\u3068\u306a\u308a\u307e\u3057\u305f\u3002<\/p>\n<figure id=\"attachment_16140\" aria-describedby=\"caption-attachment-16140\" style=\"width: 600px\" class=\"wp-caption aligncenter\"><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-16140\" src=\"https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2021\/06\/003-2.jpg\" alt=\"\" width=\"600\" height=\"404\" srcset=\"https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2021\/06\/003-2.jpg 600w, https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2021\/06\/003-2-300x202.jpg 300w\" sizes=\"auto, (max-width: 600px) 100vw, 600px\" \/><figcaption id=\"caption-attachment-16140\" class=\"wp-caption-text\">\u30de\u30a4\u30af\u30ed\u7c92\u5b50\u96c6\u5408\u4f53\u306e\u30a2\u30b9\u30da\u30af\u30c8\u6bd4 (<em>a\/b<\/em>) \u3068Ad\u6b8b\u57fa\u306e\u5c0e\u5165\u7387<em>y<\/em>\u3068\u306e\u95a2\u4fc2\u3002<em>y<\/em>\u304c\u5927\u304d\u304f\u76f8\u4e92\u4f5c\u7528\u304c\u5f37\u3044\u307b\u3069\u9577\u7d30\u3044\u96c6\u5408\u4f53\u304c\u5f62\u6210\u3055\u308c\u308b\u3002<\/figcaption><\/figure>\n<h3>\u76f8\u4e92\u4f5c\u7528\u306e\u5f37\u3055\u306b\u3088\u3063\u3066\u30de\u30a4\u30af\u30ed\u7c92\u5b50\u96c6\u5408\u4f53\u306e\u5f62\u72b6\u304c\u5909\u5316\u3059\u308b\u7406\u7531<\/h3>\n<p>\u3053\u308c\u3089\u306e\u7d50\u679c\u306f\u3001\u4ee5\u4e0b\u306e\u3088\u3046\u306b\u5b9a\u6027\u7684\u306b\u8aac\u660e\u3067\u304d\u307e\u3059\u3002\u652a\u62cc\u5f8c\u521d\u671f\u306b\u5f62\u6210\u3057\u305f\u5c11\u6570\u306eSAP\u30de\u30a4\u30af\u30ed\u7c92\u5b50\u304b\u3089\u306a\u308b\u5c0f\u3055\u306a\u96c6\u5408\u4f53\u306f\u3001\u3055\u3089\u306b\u885d\u7a81\u3057\u3066\u5927\u304d\u306a\u96c6\u5408\u4f53\u3078\u3068\u6210\u9577\u3057\u3066\u3044\u304d\u307e\u3059\u3002\u305d\u306e\u969b\u3001SAP\u30de\u30a4\u30af\u30ed\u7c92\u5b50\u306e\u76f8\u4e92\u4f5c\u7528\u304c\u5f37\u3044\u5834\u5408\u306f\u30011\u70b9\u3067\u63a5\u89e6\u3057\u3066\u3082\u63a5\u7740\u3057\u307e\u3059\u304c\u3001\u5f31\u3044\u76f8\u4e92\u4f5c\u7528\u306e\u5834\u5408\u3001\u8907\u6570\u306e\u70b9\u3067\u63a5\u89e6\u3057\u305f\u5834\u5408\u306b\u306e\u307f\u96c6\u5408\u4f53\u304c\u6210\u9577\u3059\u308b\u3068\u8003\u3048\u3089\u308c\u3001\u30a2\u30b9\u30da\u30af\u30c8\u6bd4\u3068\u76f8\u4e92\u4f5c\u7528\u306e\u5f37\u3055\u3068\u306e\u76f8\u95a2\u95a2\u4fc2\u304c\u8aac\u660e\u3067\u304d\u307e\u3059\u3002<\/p>\n<p>\u30d6\u30e9\u30a6\u30f3\u904b\u52d5\u3059\u308b\u5c0f\u3055\u306a\u30b3\u30ed\u30a4\u30c9\u7c92\u5b50\u306e\u51dd\u96c6\u306b\u3064\u3044\u3066\u306f\u53e4\u304f\u304b\u3089\u7814\u7a76\u304c\u884c\u308f\u308c\u3066\u3044\u307e\u3059\u3002\u305d\u3053\u3067\u4eca\u56de\u306eSAP\u30de\u30a4\u30af\u30ed\u7c92\u5b50\u306e\u7d50\u679c\u3092\u30b3\u30ed\u30a4\u30c9\u51dd\u96c6\u7406\u8ad6\u3068\u6bd4\u8f03\u3059\u308b\u3053\u3068\u306b\u3057\u307e\u3057\u305f\u3002\u30b3\u30ed\u30a4\u30c9\u51dd\u96c6\u304c\u8d77\u3053\u308b\u969b\u3001\u30b3\u30ed\u30a4\u30c9\u7c92\u5b50\u9593\u306e\u76f8\u4e92\u4f5c\u7528\u304c\u5f37\u304f\u3001\u885d\u7a81\u3059\u308b\u3068\u5fc5\u305a\u51dd\u96c6\u304c\u8d77\u3053\u308b\u62e1\u6563\u5f8b\u901f\u6a5f\u69cb\u3068\u3001\u885d\u7a81\u3057\u305f\u969b\u306b\u306a\u3093\u3089\u304b\u306e\u53cd\u5fdc\u304c\u8d77\u3053\u3089\u306a\u3044\u3068\u51dd\u96c6\u3057\u306a\u3044\u53cd\u5fdc\u5f8b\u901f\u6a5f\u69cb\u304c\u77e5\u3089\u308c\u3066\u3044\u307e\u3059\u3002\u307e\u305f\u3001\u305d\u308c\u305e\u308c\u306e\u6a5f\u69cb\u3067\u5f62\u6210\u3055\u308c\u308b\u51dd\u96c6\u4f53\u306f\u3001\u30d5\u30e9\u30af\u30bf\u30eb\u69cb\u9020\u3068\u306a\u308b\u3053\u3068\u304c\u77e5\u3089\u308c\u3066\u3044\u307e\u3059\u3002<\/p>\n<p>\u30b3\u30ed\u30a4\u30c9\u51dd\u96c6\u4f53\u306e\u8cea\u91cf\u3068\u534a\u5f84\u3092\u305d\u308c\u305e\u308c<em>M<\/em>\u3001<em>R<\/em>\u3068\u3059\u308b\u3068\u3001<em>M<\/em> \u221d <em>R<\/em><sup><em>D<\/em><sub>f<\/sub><\/sup>\u3067\u8868\u3055\u308c\u308b\u30d5\u30e9\u30af\u30bf\u30eb\u6b21\u5143<em>D<\/em><sub>f<\/sub>\u306f\u3001\u62e1\u6563\u5f8b\u901f\u6a5f\u69cb\u3067\u306f1.75\u3001\u53cd\u5fdc\u5f8b\u901f\u6a5f\u69cb\u3067\u306f2.05\u3067\u3042\u308b\u3053\u3068\u304c\u77e5\u3089\u308c\u3066\u3044\u307e\u3059\u3002<\/p>\n<p>Tunable Limited Aggregation\u30bd\u30d5\u30c8\u30a6\u30a7\u30a2\u3092\u7528\u3044\u3066\u30b3\u30ed\u30a4\u30c9\u7c92\u5b50\u6570<em>N<\/em> = 15, 30, 100, 200\u306b\u5bfe\u3057\u3066<em>D<\/em><sub>f<\/sub> = 1.75, 2.05\u3068\u306a\u308b\u3088\u3046\u306b\u69cb\u7bc9\u3057\u305f\u51dd\u96c6\u4f53\u3092\u6bd4\u8f03\u3059\u308b\u3068\u3001\u62e1\u6563\u5f8b\u901f\u6a5f\u69cb (<em>D<\/em><sub>f<\/sub> = 1.75) \u306e\u65b9\u304c\u758e\u3067\u5e83\u304c\u3063\u305f\u51dd\u96c6\u4f53\u3068\u306a\u308b\u3053\u3068\u3092\u793a\u3057\u3066\u3044\u307e\u3059\u3002<\/p>\n<p>\u7279\u306b\u5c0f\u3055\u306a<em>N<\/em> (= 15) \u306e\u51dd\u96c6\u4f53\u306b\u7740\u76ee\u3057\u3001\u4e8c\u6b21\u5143\u5e73\u9762\u3078\u306e\u6295\u5f71\u56f3\u306b\u5bfe\u3057\u3066\u6955\u5186\u8fd1\u4f3c\u3092\u884c\u3046\u3068\u30a2\u30b9\u30da\u30af\u30c8\u6bd4\u306f\u305d\u308c\u305e\u308c<em>a\/b<\/em> = 1.75, 1.45\u3068\u8a55\u4fa1\u3059\u308b\u3053\u3068\u304c\u3067\u304d\u307e\u3057\u305f\u3002\u3059\u306a\u308f\u3061\u3001\u672c\u7814\u7a76\u3067\u5f97\u3089\u308c\u305f\u76f8\u4e92\u4f5c\u7528\u306e\u5f37\u3055\u3068\u30a2\u30b9\u30da\u30af\u30c8\u6bd4\u306e\u95a2\u4fc2\u306f\u3001\u7c92\u5b50\u6570\u306e\u5c0f\u3055\u306a\u6761\u4ef6\u306b\u304a\u3051\u308b\u30b3\u30ed\u30a4\u30c9\u51dd\u96c6\u7406\u8ad6\u3067\u8aac\u660e\u3067\u304d\u308b\u3053\u3068\u304c\u308f\u304b\u308a\u307e\u3057\u305f\u3002<\/p>\n<figure id=\"attachment_16141\" aria-describedby=\"caption-attachment-16141\" style=\"width: 497px\" class=\"wp-caption aligncenter\"><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-16141\" src=\"https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2021\/06\/004-1.jpg\" alt=\"\" width=\"497\" height=\"713\" srcset=\"https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2021\/06\/004-1.jpg 497w, https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2021\/06\/004-1-209x300.jpg 209w\" sizes=\"auto, (max-width: 497px) 100vw, 497px\" \/><figcaption id=\"caption-attachment-16141\" class=\"wp-caption-text\">Tunable Limited Aggregation\u30bd\u30d5\u30c8\u30a6\u30a7\u30a2\u3092\u7528\u3044\u3066\u69cb\u7bc9\u3057\u305f\u30b3\u30ed\u30a4\u30c9\u51dd\u96c6\u4f53\u306e\u4f8b\u3002\u30b3\u30ed\u30a4\u30c9\u7c92\u5b50\u6570<em>N<\/em> = 15, 30, 100, 200\u306b\u5bfe\u3057\u3001\u51dd\u96c6\u4f53\u62e1\u6563\u5f8b\u901f\u6a5f\u69cb (<em>D<\/em><sub>f<\/sub> = 1.75)\u3001\u304a\u3088\u3073\u3001\u53cd\u5fdc\u5f8b\u901f\u6a5f\u69cb (<em>D<\/em><sub>f<\/sub> = 2.05) \u306b\u3066\u69cb\u7bc9\u3002<\/figcaption><\/figure>\n<h3>\u751f\u7269\u304c\u4f5c\u308b\u591a\u69d8\u306a\u5f62\u72b6\u3068\u306e\u95a2\u4fc2<\/h3>\n<p>\u3053\u306e\u3088\u3046\u306b\u76f8\u4e92\u4f5c\u7528\u306e\u5f37\u3055\u3001\u3064\u307e\u308a\u5206\u5b50\u8a8d\u8b58\u90e8\u4f4d\u3067\u3042\u308bAd\u6b8b\u57fa\u306e\u5c0e\u5165\u7387<em>y<\/em>\u3092\u5909\u5316\u3055\u305b\u308b\u3053\u3068\u3067\u3001\u96c6\u5408\u4f53\u306e\u5f62\u72b6\u3092\u5236\u5fa1\u3067\u304d\u308b\u3053\u3068\u304c\u308f\u304b\u308a\u307e\u3057\u305f\u3002\u751f\u7269\u306e\u5f62\u72b6\u306e\u591a\u69d8\u6027\u304c\u3069\u306e\u3088\u3046\u306b\u3067\u304d\u305f\u304b\u306f\u3001\u307e\u3060\u307e\u3060\u7814\u7a76\u304c\u5fc5\u8981\u3067\u3059\u3002\u3057\u304b\u3057\u3001\u751f\u7269\u304c\u4f5c\u308b\u5f62\u72b6\u306e\u591a\u69d8\u6027\u306f\u3001\u751f\u7269\u304c\u3067\u304d\u3064\u3064\u3042\u308b\u904e\u7a0b\u3067\u3001\u76f8\u4e92\u4f5c\u7528\u306e\u5f37\u3055\u306b\u3088\u3063\u3066\u7570\u306a\u308b\u5f62\u72b6\u306e\u96c6\u5408\u4f53\u304c\u5f62\u6210\u3057\u305f\u3053\u3068\u306b\u7aef\u3092\u767a\u3057\u3066\u3044\u308b\u306e\u304b\u3082\u3057\u308c\u307e\u305b\u3093\u3002<\/p>\n<p><b>\u53c2\u8003\u6587\u732e<\/b><br \/>\n\u30fbMacroscopic self-assembly through molecular recognition<br \/>\nHarada, A.; Kobayashi, R.; Takashima, Y.; Hashidzume, A.; Yamaguchi, H. <em>Nat. Chem.<\/em> <b>2011<\/b>, <em>3<\/em> (1), 34-37.<br \/>\n\u30fbThe macroscopic shape of assemblies formed from microparticles based on host\u2013guest interaction dependent on the guest content<br \/>\nItami, T.; Hashidzume, A.; Kamon, Y.; Yamaguchi, H.; Harada, A. <em>Sci. Rep.<\/em> <b>2021<\/b>, <em>11<\/em> (1), 6320.<br \/>\n\u30fbA Simplified Model for Multivalent Interaction Competing with a Low Molecular Weight Competitor<br \/>\nHashidzume, A.; Itami, T.; Kamon, Y.; Harada, A. <em>Chem. Lett.<\/em> <b>2020<\/b>, <em>49<\/em> (11), 1306-1308.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u5206\u5b50\u8a8d\u8b58\u306b\u3088\u3063\u3066\u5f62\u6210\u3055\u308c\u308b\u96c6\u5408\u4f53\u306e\u5f62\u306f\u3069\u306e\u3088\u3046\u306b\u6c7a\u307e\u308b\u304b\uff1f \u751f\u7269\u306e\u3055\u307e\u3056\u307e\u306a\u5f62\u306f\u3001\u7d30\u80de\u540c\u58eb\u304c\u305d\u306e\u8868\u9762\u306b\u5b58\u5728\u3059\u308b\u5206\u5b50\u306e\u5206\u5b50\u8a8d\u8b58\u3092\u4ecb\u3057\u3066\u3001\u7279\u5b9a\u306e\u4f4d\u7f6e\u3084\u914d\u5217\u3067\u96c6\u5408\uff08\u81ea\u5df1\u7d44\u7e54\u5316\uff09\u3059\u308b\u3053\u3068\u306b\u3088\u308a\u5f62\u6210\u3055\u308c\u307e\u3059\u3002\u751f [&hellip;]<\/p>\n","protected":false},"author":577,"featured_media":16139,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_acf_changed":false,"_monsterinsights_skip_tracking":false,"_monsterinsights_sitenote_active":false,"_monsterinsights_sitenote_note":"","_monsterinsights_sitenote_category":0,"footnotes":""},"categories":[3],"tags":[20,139,59,15],"class_list":["post-16134","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-outcome","tag-20","tag-139","tag-59","tag-biology","has_thumb"],"acf":[],"aioseo_notices":[],"_links":{"self":[{"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=\/wp\/v2\/posts\/16134","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=\/wp\/v2\/users\/577"}],"replies":[{"embeddable":true,"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=16134"}],"version-history":[{"count":13,"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=\/wp\/v2\/posts\/16134\/revisions"}],"predecessor-version":[{"id":16204,"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=\/wp\/v2\/posts\/16134\/revisions\/16204"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=\/wp\/v2\/media\/16139"}],"wp:attachment":[{"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=16134"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=16134"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=16134"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}