{"id":14139,"date":"2020-08-20T08:00:29","date_gmt":"2020-08-19T23:00:29","guid":{"rendered":"https:\/\/academist-cf.com\/journal\/?p=14139"},"modified":"2020-08-30T21:00:03","modified_gmt":"2020-08-30T12:00:03","slug":"%e7%be%bd%e3%81%b0%e3%81%9f%e3%81%8f%e8%9b%8d%e5%85%89%e3%83%97%e3%83%ad%e3%83%bc%e3%83%96%e3%80%8cperylene-flap%e3%80%8d-%e9%ab%98%e3%81%84%e6%84%9f%e5%ba%a6%e3%81%a7%e5%be%ae%e8%a6%96%e7%9a%84","status":"publish","type":"post","link":"https:\/\/academist-cf.com\/journal\/?p=14139","title":{"rendered":"\u7fbd\u3070\u305f\u304f\u86cd\u5149\u30d7\u30ed\u30fc\u30d6\u300cPerylene FLAP\u300d- \u9ad8\u3044\u611f\u5ea6\u3067\u5fae\u8996\u7684\u306a\u7c98\u5ea6\u5909\u5316\u3092\u691c\u51fa"},"content":{"rendered":"<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-14138 size-full\" src=\"https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2020\/08\/001-2.jpg\" alt=\"\" width=\"600\" height=\"400\" 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FLAP\u306f\u5f93\u6765\u306eFLAP\u3067\u8ab2\u984c\u3068\u306a\u3063\u3066\u3044\u305f\u53ef\u8996\u9818\u57df\u306e\u5149\u3092\u3088\u304f\u5438\u53ce\u3059\u308b\u3046\u3048\u3001\u7fbd\u3070\u305f\u304d\u904b\u52d5\u306b\u5fc5\u8981\u3068\u306a\u308b\u81ea\u7531\u4f53\u7a4d\u304c\u30a2\u30f3\u30c8\u30e9\u30bb\u30f3\u30a4\u30df\u30c9\u3088\u308a\u3082\u5927\u304d\u304f\u3001\u3088\u308a\u654f\u611f\u306a\u7c98\u5ea6\u5fdc\u7b54\u3092\u671f\u5f85\u3067\u304d\u307e\u3059\u3002\u5b9f\u969b\u306b\u3001\u958b\u767a\u3057\u305fPerylene FLAP\u306f\u5149\u306b\u5bfe\u3057\u3066\u975e\u5e38\u306b\u5b89\u5b9a\u306b\u306a\u308a\u307e\u3057\u305f\uff08\u5f8c\u8ff0\uff09\u3002<\/p>\n<p>\u305d\u306e\u4e00\u65b9\u3067\u3001\u4e88\u60f3\u306b\u53cd\u3057\u3001Perylene FLAP\u306e\u6eb6\u6db2\u306f\u5fae\u5f31\u306a\u86cd\u5149\u3057\u304b\u793a\u3057\u307e\u305b\u3093\u3067\u3057\u305f\u3002\u5177\u4f53\u7684\u306b\u306f\u3001\u30d8\u30ad\u30b5\u30f3\uff08C<sub>6<\/sub>H<sub>14<\/sub>\uff1b\u7c98\u5ea60.3 cP\uff09\u306e\u6eb6\u6db2\u4e2d\u3067\u86cd\u5149\u91cf\u5b50\u53ce\u7387\uff08\u52b1\u8d77\u3055\u308c\u305f\u5206\u5b50\u306e\u3046\u3061\u3001\u86cd\u5149\u3092\u767a\u3059\u308b\u5206\u5b50\u306e\u5272\u5408\uff09\u304c2%\u3067\u3042\u308a\u3001\u86cd\u5149\u5bff\u547d\u304c120\u30d4\u30b3\u79d2\uff08ps\uff1a1\u5146\u5206\u306e1\u79d2\uff09\u3067\u3057\u305f\u3002\u4e00\u822c\u7684\u306a\u30da\u30ea\u30ec\u30f3\u30a4\u30df\u30c9\u5316\u5408\u7269\u306e\u86cd\u5149\u91cf\u5b50\u53ce\u7387\u304c90%\u3092\u8d85\u3048\u308b\u3053\u3068\u3092\u8e0f\u307e\u3048\u308b\u3068\u3001\u304b\u306a\u308a\u5c0f\u3055\u3044\u3068\u3044\u3048\u307e\u3059\u3002<\/p>\n<p>\u3057\u304b\u3057\u3001\u540c\u3058\u76f4\u9396\u30a2\u30eb\u30ab\u30f3\u3067\u7c98\u5ea6\u304c\u5c11\u3057\u3060\u3051\u9ad8\u3044\u30d8\u30ad\u30b5\u30c7\u30ab\u30f3\uff08C<sub>16<\/sub>H<sub>34<\/sub>\uff1b\u7c98\u5ea63 cP\uff09\u306e\u6eb6\u6db2\u4e2d\u3067\u306f\u86cd\u5149\u91cf\u5b50\u53ce\u7387\u304c8%\u306b\u5411\u4e0a\u3057\u3001\u86cd\u5149\u5bff\u547d\u306f560ps\u307e\u3067\u9577\u304f\u306a\u308b\u3053\u3068\u304c\u308f\u304b\u308a\u307e\u3057\u305f\u3002\u3055\u3089\u306b\u3001\u9ad8\u5206\u5b50\u3067\u3042\u308bPMMA\uff08\u30dd\u30ea\u30e1\u30bf\u30af\u30ea\u30eb\u9178\u30e1\u30c1\u30eb\uff09\u306e\u8584\u819c\u306b\u5206\u6563\u3055\u305b\u3066\u6e2c\u5b9a\u3092\u884c\u3063\u305f\u3068\u3053\u308d\u3001\u86cd\u5149\u91cf\u5b50\u53ce\u7387\u306f18%\u307e\u3067\u4e0a\u6607\u3057\u3001\u86cd\u5149\u5bff\u547d\u306f1.6\u30ca\u30ce\u79d2\uff08=1600 ps\uff09\u307e\u3067\u9577\u304f\u306a\u308b\u3053\u3068\u304c\u5224\u660e\u3057\u307e\u3057\u305f\u3002<\/p>\n<p>\u3053\u306e\u3088\u3046\u306b\u5468\u56f2\u74b0\u5883\u306e\u5909\u5316\u306b\u3088\u3063\u3066\u7121\u86cd\u5149\u3084\u305d\u308c\u306b\u8fd1\u3044\u7269\u8cea\u304c\u86cd\u5149\u3092\u5897\u5927\u3055\u305b\u308b\u6027\u8cea\u306f\u30d5\u30eb\u30aa\u30ed\u30b8\u30a7\u30cb\u30c3\u30af\u3068\u547c\u3070\u308c\u3001\u30da\u30ea\u30ec\u30f3\u30a4\u30df\u30c9\u306e\u7cfb\u3067\u767a\u73fe\u3057\u305f\u4f8b\u306f\u307b\u3068\u3093\u3069\u5831\u544a\u3055\u308c\u3066\u3044\u307e\u305b\u3093\u3067\u3057\u305f\u3002\u307e\u305f\u30013 cP\u4ee5\u4e0b\u306e\u7c98\u5ea6\u306e\u9055\u3044\u3092\u86cd\u5149\u5bff\u547d\u306e\u9055\u3044\u306b\u3088\u3063\u3066\u533a\u5225\u3067\u304d\u308b\u3053\u3068\u304b\u3089\u3001\u30ec\u30fc\u30b6\u30fc\u9855\u5fae\u93e1\u6280\u8853\u3068\u7d44\u307f\u5408\u308f\u305b\u308b\u3053\u3068\u3067\u3001\u5f93\u6765\u306e\u86cd\u5149\u7c98\u5ea6\u30d7\u30ed\u30fc\u30d6\u3067\u306f\u96e3\u3057\u304b\u3063\u305f\u300c\u8d85\u4f4e\u7c98\u5ea6\u9818\u57df\u306b\u304a\u3051\u308b\u5b9a\u91cf\u7684\u306a\u7c98\u5ea6\u5206\u5e03\u306e\u30a4\u30e1\u30fc\u30b8\u30f3\u30b0\u300d\u306e\u5b9f\u73fe\u304c\u671f\u5f85\u3055\u308c\u307e\u3059\u3002<\/p>\n<p>Perylene FLAP\u304c\u30d5\u30eb\u30aa\u30ed\u30b8\u30a7\u30cb\u30c3\u30af\u7279\u6027\u3092\u793a\u3059\u30e1\u30ab\u30cb\u30ba\u30e0\u306f\u3001\u52b1\u8d77\u72b6\u614b\u306b\u304a\u3051\u308b\u5206\u5b50\u306e\u6319\u52d5\u3092\u8003\u3048\u308b\u3053\u3068\u3067\u7406\u89e3\u3067\u304d\u307e\u3059\u3002\u4f4e\u7c98\u5ea6\u5a92\u4f53\u4e2d\u3067\u52b1\u8d77\u3055\u308c\u305f\u5f8c\u3001\u307b\u3068\u3093\u3069\u306e\u5206\u5b50\u306f\u901f\u3084\u304b\u306bV\u5b57\u578b\u69cb\u9020\u304b\u3089\u5e73\u9762\u69cb\u9020\u3078\u3068\u5f62\u3092\u5909\u3048\u3001\u5e73\u9762\u69cb\u9020\u304b\u3089\u57fa\u5e95\u72b6\u614b\u3078\u3068\u5931\u6d3b\u3057\u307e\u3059\u3002\u5e73\u9762\u69cb\u9020\u304b\u3089\u306e\u5931\u6d3b\u904e\u7a0b\u3067\u306fFLAP1\u3068\u306f\u7570\u306a\u308a\u86cd\u5149\u3092\u767a\u3055\u306a\u3044\u3053\u3068\u304c\u308f\u304b\u3063\u3066\u3044\u307e\u3059\u3002<\/p>\n<p>\u4e00\u65b9\u3067\u3001\u52b1\u8d77\u72b6\u614b\u306b\u304a\u3051\u308b\u5b89\u5b9a\u69cb\u9020\u3068\u3057\u3066\u3001\u5e73\u9762\u69cb\u9020\u3060\u3051\u3067\u306f\u306a\u304fV\u5b57\u578b\u69cb\u9020\u3082\u5b58\u5728\u3059\u308b\u3053\u3068\u304c\u308f\u304b\u3063\u3066\u304a\u308a\u3001V\u5b57\u578b\u69cb\u9020\u304b\u3089\u57fa\u5e95\u72b6\u614b\u3078\u5931\u6d3b\u3059\u308b\u969b\u306b\u306f\u86cd\u5149\u3092\u767a\u3057\u307e\u3059\u3002\u3064\u307e\u308a\u3001Perylene FLAP\u306e\u5468\u56f2\u306e\u7c98\u5ea6\u304c\u4e0a\u6607\u3059\u308b\u3053\u3068\u306b\u3088\u3063\u3066V\u5b57\u578b\u304b\u3089\u5e73\u9762\u578b\u3078\u306e\u69cb\u9020\u5909\u5316\u304c\u6291\u5236\u3055\u308c\u3001\u86cd\u5149\u3092\u767a\u3059\u308bV\u5b57\u578b\u69cb\u9020\u304b\u3089\u306e\u5931\u6d3b\u306e\u5272\u5408\u304c\u5897\u52a0\u3057\u305f\u7d50\u679c\u3001\u86cd\u5149\u91cf\u5b50\u53ce\u7387\u306e\u5897\u52a0\u306b\u3064\u306a\u304c\u308b\u3053\u3068\u304c\u660e\u3089\u304b\u3068\u306a\u308a\u307e\u3057\u305f\u3002<\/p>\n<figure id=\"attachment_14134\" aria-describedby=\"caption-attachment-14134\" style=\"width: 600px\" class=\"wp-caption aligncenter\"><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-14134 size-full\" src=\"https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2020\/08\/003-2.jpg\" alt=\"\" width=\"600\" height=\"400\" srcset=\"https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2020\/08\/003-2.jpg 600w, https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2020\/08\/003-2-300x200.jpg 300w, https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2020\/08\/003-2-480x320.jpg 480w\" sizes=\"auto, (max-width: 600px) 100vw, 600px\" \/><figcaption id=\"caption-attachment-14134\" class=\"wp-caption-text\">\uff08a\uff09\u30da\u30ea\u30ec\u30f3\u30a4\u30df\u30c9\u3092\u9aa8\u683c\u3068\u3059\u308bFLAP\uff08Perylene FLAP\uff09\u306e\u69cb\u9020<br \/>\uff08b\uff09\u5468\u56f2\u306e\u7c98\u5ea6\u4e0a\u6607\u306b\u4f34\u3063\u3066\u86cd\u5149\u5f37\u5ea6\u304c\u5897\u5927\u3057\u3001\u86cd\u5149\u5bff\u547d\u304c\u9577\u304f\u306a\u308b\u69d8\u5b50<br \/>\uff08c\uff09\u57fa\u5e95\u72b6\u614b\uff08S<sub>0<\/sub>\uff09\u3068\u52b1\u8d77\u72b6\u614b\uff08S<sub>1<\/sub>\uff09\u306b\u304a\u3051\u308b\u30a8\u30cd\u30eb\u30ae\u30fc\u56f3\u3068\u3001\u9ad8\u7c98\u5ea6\u74b0\u5883\u3067\u86cd\u5149\u304c\u5897\u5927\u3059\u308b\u30e1\u30ab\u30cb\u30ba\u30e0<\/figcaption><\/figure>\n<h3>\u7fbd\u3070\u305f\u304d\u904b\u52d5\u306b\u3088\u308a\u3001\u56de\u8ee2\u3059\u308b\u86cd\u5149\u7c98\u5ea6\u30d7\u30ed\u30fc\u30d6\u4ee5\u4e0a\u306e\u6a5f\u80fd\u3092\u5b9f\u73fe<\/h3>\n<p>\u3055\u3089\u306b\u79c1\u305f\u3061\u306f\u3001\u70ad\u7d20\u6570\u304c\u7570\u306a\u308a\u7c98\u5ea6\u306e\u7570\u306a\u308b\u4e00\u9023\u306e\u76f4\u9396\u30a2\u30eb\u30ab\u30f3\u6eb6\u5a92\u306bPerylene FLAP\u3092\u6eb6\u89e3\u3055\u305b\u3001\u540c\u69d8\u306b\u86cd\u5149\u91cf\u5b50\u53ce\u7387\u3068\u86cd\u5149\u5bff\u547d\u3092\u6e2c\u5b9a\u3057\u307e\u3057\u305f\u3002\u7d50\u679c\u3001Perylene FLAP\u306f\u30013 cP\u4ee5\u4e0b\u3068\u3044\u3046\u6975\u3081\u3066\u4f4e\u3044\u7c98\u5ea6\u9818\u57df\u3067\u3042\u3063\u3066\u3082\u86cd\u5149\u5bff\u547d\u306e\u5024\u304b\u3089\u5c40\u6240\u7c98\u5ea6\u304c\u5b9a\u91cf\u3067\u304d\u308b\u86cd\u5149\u7c98\u5ea6\u30d7\u30ed\u30fc\u30d6\u3068\u3057\u3066\u6a5f\u80fd\u3059\u308b\u3053\u3068\u304c\u660e\u3089\u304b\u3068\u306a\u308a\u307e\u3057\u305f\u3002<\/p>\n<p>\u86cd\u5149\u7c98\u5ea6\u30d7\u30ed\u30fc\u30d6\u3068\u3057\u3066\u3088\u304f\u7528\u3044\u3089\u308c\u308b\u3001\u56de\u8ee2\u904b\u52d5\u306b\u3088\u3063\u3066\u7c98\u5ea6\u3092\u611f\u77e5\u3059\u308bBODIPY-C<sub>12<\/sub>\u3068\u6bd4\u8f03\u3057\u3066\u3082\u3001\u6975\u4f4e\u7c98\u5ea6\u9818\u57df\u3067\u306f\u3088\u308a\u92ed\u654f\u306a\u5fdc\u7b54\u3092\u793a\u3059\u3053\u3068\u304c\u308f\u304b\u308a\u307e\u3057\u305f\u3002Perylene FLAP\u304a\u3088\u3073BODIPY-C<sub>12<\/sub>\u3092\u70ad\u7d20\u65706\uff08\u30d8\u30ad\u30b5\u30f3\uff09\u304b\u308916\uff08\u30d8\u30ad\u30b5\u30c7\u30ab\u30f3\uff09\u307e\u3067\u306e\u7570\u306a\u308b\u7c98\u5ea6\u306e\u76f4\u9396\u30a2\u30eb\u30ab\u30f3\u6eb6\u5a92\u306b\u6eb6\u304b\u3057\u3066\u86cd\u5149\u3092\u6e2c\u5b9a\u3057\u305f\u3068\u3053\u308d\u3001\u3068\u3082\u306b\u30b9\u30da\u30af\u30c8\u30eb\u5f62\u72b6\u306e\u5909\u5316\u306f\u307b\u3068\u3093\u3069\u898b\u3089\u308c\u307e\u305b\u3093\u3067\u3057\u305f\u304c\u3001\u30a2\u30eb\u30ab\u30f3\u306e\u7c98\u5ea6\u4e0a\u6607\u306b\u4f34\u3063\u3066\u86cd\u5149\u91cf\u5b50\u53ce\u7387\u306f\u5897\u52a0\u3057\u3001\u86cd\u5149\u5bff\u547d\u306f\u9577\u304f\u306a\u308a\u307e\u3057\u305f\u3002\u305d\u308c\u305e\u308c\u306e\u86cd\u5149\u7c98\u5ea6\u30d7\u30ed\u30fc\u30d6\u3092\u5404\u6eb6\u5a92\u306b\u540c\u3058\u6fc3\u5ea6\u3067\u6eb6\u304b\u3057\u305f\u3068\u304d\u306e\u86cd\u5149\u30b9\u30da\u30af\u30c8\u30eb\u3092\u793a\u3057\u307e\u3059\u3002<\/p>\n<figure id=\"attachment_14135\" aria-describedby=\"caption-attachment-14135\" style=\"width: 600px\" class=\"wp-caption aligncenter\"><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-14135 size-full\" src=\"https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2020\/08\/004-1.jpg\" alt=\"\" width=\"600\" height=\"400\" srcset=\"https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2020\/08\/004-1.jpg 600w, https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2020\/08\/004-1-300x200.jpg 300w, https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2020\/08\/004-1-480x320.jpg 480w\" sizes=\"auto, (max-width: 600px) 100vw, 600px\" \/><figcaption id=\"caption-attachment-14135\" class=\"wp-caption-text\">\u5404\u6eb6\u5a92\u306b\u304a\u3051\u308b\u86cd\u5149\u30b9\u30da\u30af\u30c8\u30eb<br \/>\uff08a\uff09\u306f\u7fbd\u3070\u305f\u304f\u86cd\u5149\u7c98\u5ea6\u30d7\u30ed\u30fc\u30d6Perylene FLAP\u3001\uff08b\uff09\u306f\u56de\u8ee2\u3059\u308b\u86cd\u5149\u7c98\u5ea6\u30d7\u30ed\u30fc\u30d6BODIPY-C<sub>12<\/sub>\u3067\u3042\u308b\u3002\u86cd\u5149\u5f37\u5ea6\u306e\u8868\u793a\u306b\u3042\u305f\u3063\u3066\u306f\u3001\u5404\u6eb6\u5a92\u306b\u304a\u3051\u308b\u86cd\u5149\u91cf\u5b50\u53ce\u7387\u3092\u8003\u616e\u3057\u3066\u3044\u308b\u3002<\/figcaption><\/figure>\n<p>Perylene FLAP\u306b\u3064\u3044\u3066\u3001\u7c98\u5ea6\u3092\u5b9a\u91cf\u3067\u304d\u308b\u4e0a\u9650\u306e\u5024\u3092\u78ba\u8a8d\u3059\u308b\u305f\u3081\u3001\u3055\u3089\u306b\u7c98\u5ea6\u3092\u5897\u52a0\u3055\u305b\u305f30 cP\u7a0b\u5ea6\u306e\u30df\u30cd\u30e9\u30eb\u30aa\u30a4\u30eb\u306b\u6eb6\u89e3\u3055\u305b\u305f\u3068\u3053\u308d\u3001\u86cd\u5149\u91cf\u5b50\u53ce\u7387\u306f17%\u3001\u86cd\u5149\u5bff\u547d\u306f1.3 ns\uff08=1300 ps\uff09\u307e\u3067\u5411\u4e0a\u3057\u307e\u3057\u305f\u3002\u3053\u306e\u7d50\u679c\u306f\u4e0a\u8a18PMMA\u819c\u3067\u6e2c\u5b9a\u3057\u305f\u5834\u5408\u3068\u307b\u307c\u540c\u69d8\u306e\u7d50\u679c\u3067\u3042\u3063\u305f\u3053\u3068\u304b\u3089\u3001\u7c98\u5ea6\u306b\u3088\u308b\u5fdc\u7b54\u306f\u98fd\u548c\u3057\u3066\u304a\u308a\u3001\u5b9a\u91cf\u3067\u304d\u308b\u7c98\u5ea6\u306e\u4e0a\u9650\u306f30cP\u7a0b\u5ea6\u3067\u3042\u308b\u3068\u308f\u304b\u308a\u307e\u3057\u305f\u3002<\/p>\n<p>\u3055\u3089\u306b\u3001\u86cd\u5149\u5bff\u547d\uff08\u03c4<sub>F<\/sub>\uff09\u306e\u5bfe\u6570\u3092\u7c98\u5ea6\u306e\u5bfe\u6570\u306b\u5bfe\u3057\u3066\u30d7\u30ed\u30c3\u30c8\u3057\u305f\u691c\u91cf\u7dda\uff08F\u00f6rster-Hoffmann\u30d7\u30ed\u30c3\u30c8\uff09\u306e\u50be\u304d\u3092\u6bd4\u8f03\u3057\u307e\u3057\u305f\u3002F\u00f6rster-Hoffmann\u30d7\u30ed\u30c3\u30c8\u306f\u4ee5\u4e0b\u306e\u5f0f\u3067\u8868\u3055\u308c\u307e\u3059\u3002<\/p>\n<p style=\"text-align: center;\">\u00a0\u00a0\u00a0 log \u03c4<sub>F<\/sub> =\u03b1 log \u03b7 + log z\/<em>k<sub>r<\/sub><\/em><\/p>\n<p>\u3053\u3053\u3067\u3001\u03b7\u306f\u7c98\u5ea6\u3001<em>k<\/em><sub>r<\/sub>\u306f\u8f3b\u5c04\u5931\u6d3b\u901f\u5ea6\u5b9a\u6570\u3001\u03b1\u3001z\u306f\u305d\u308c\u305e\u308c\u5b9a\u6570\u3067\u3059\u3002<\/p>\n<figure id=\"attachment_14136\" aria-describedby=\"caption-attachment-14136\" style=\"width: 600px\" class=\"wp-caption aligncenter\"><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-14136 size-full\" src=\"https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2020\/08\/005.jpg\" alt=\"\" width=\"600\" height=\"211\" srcset=\"https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2020\/08\/005.jpg 600w, https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2020\/08\/005-300x106.jpg 300w\" sizes=\"auto, (max-width: 600px) 100vw, 600px\" \/><figcaption id=\"caption-attachment-14136\" class=\"wp-caption-text\">\uff08a\uff09\u86cd\u5149\u5bff\u547d\u306e\u5bfe\u6570\u3092\u7c98\u5ea6\u306e\u5bfe\u6570\u306b\u5bfe\u3057\u3066\u30d7\u30ed\u30c3\u30c8\u3057\u305f\u691c\u91cf\u7dda\uff08F\u00f6rster-Hoffmann\u30d7\u30ed\u30c3\u30c8\uff09<br \/>\uff08b\uff09\u30c8\u30eb\u30a8\u30f3\u6eb6\u6db2\u4e2d\u3067\u7d2b\u5916\u5149\u3092\u7167\u5c04\u3057\u305f\u6642\u306e\u5149\u9000\u8272\u306e\u901f\u3055\u306e\u6bd4\u8f03<\/figcaption><\/figure>\n<p>Perylene FLAP\u3068BODIPY-C<sub>12<\/sub>\u306e\u30d7\u30ed\u30c3\u30c8\u306f\u30010.3-3 cP\u3068\u3044\u3046\u6975\u3081\u3066\u4f4e\u3044\u7c98\u5ea6\u9818\u57df\u306b\u304a\u3044\u3066\u3001\u3044\u305a\u308c\u3082\u826f\u3044\u76f4\u7dda\u95a2\u4fc2\u3092\u793a\u3057\u305f\u4e00\u65b9\u3067\u3001\u691c\u91cf\u7dda\u306e\u300c\u50be\u304d\u300d\u306b\u6ce8\u76ee\u3057\u3066\u307f\u308b\u3068\u3001Perylene FLAP\u306e\u65b9\u304c\u9855\u8457\u306b\u5927\u304d\u3044\u3053\u3068\u304c\u308f\u304b\u308a\u307e\u3057\u305f\u3002\u691c\u91cf\u7dda\u306e\u50be\u304d\u304c\u5927\u304d\u3044\u307b\u3069\u3001\u308f\u305a\u304b\u306a\u7c98\u5ea6\u5909\u5316\u306b\u5bfe\u3057\u3066\u3082\u5927\u304d\u306a\u86cd\u5149\u5bff\u547d\u306e\u5909\u5316\u304c\u73fe\u308c\u308b\u3053\u3068\u3092\u610f\u5473\u3059\u308b\u305f\u3081\u3001Perylene FLAP\u306e\u86cd\u5149\u7c98\u5ea6\u30d7\u30ed\u30fc\u30d6\u3068\u3057\u3066\u306e\u5fdc\u7b54\u6027\u306f\u3088\u308a\u654f\u611f\u3067\u3042\u308b\u3068\u3044\u3048\u307e\u3059\u3002<\/p>\n<p>BODIPY\u306e\u7c98\u5ea6\u5fdc\u7b54\u4e0a\u9650\u304c1000 cP\u3092\u8d85\u3048\u308b\u3053\u3068\u3092\u8003\u3048\u308b\u3068\u3001BODIPY\u306e\u307b\u3046\u304c\u3088\u308a\u5e83\u7bc4\u56f2\u306e\u7c98\u5ea6\u306b\u5bfe\u5fdc\u3067\u304d\u307e\u3059\u304c\u3001\u4eca\u56de\u6ce8\u76ee\u3057\u305f\u300c\u6975\u4f4e\u7c98\u5ea6\u9818\u57df\u300d\u3067\u306f\u3001Perylene FLAP\u306e\u65b9\u304cBODIPY-C<sub>12<\/sub>\u3088\u308a\u92ed\u654f\u306b\u5fdc\u7b54\u3059\u308b\u3068\u3044\u3046\u308f\u3051\u3067\u3059\u3002<\/p>\n<p>\u307e\u305f\u3001\u8272\u7d20\u5206\u5b50\u3092\u5149\u6280\u8853\u3078\u5fdc\u7528\u3059\u308b\u969b\u3001\u5149\u5b89\u5b9a\u6027\u304c\u91cd\u8981\u3067\u3042\u308b\u3053\u3068\u306f\u524d\u8ff0\u306e\u3068\u304a\u308a\u3067\u3059\u304c\u3001Perylene FLAP\u3067\u306f\u9577\u6642\u9593\u30fb\u9ad8\u5f37\u5ea6\u306e\u5149\u7167\u5c04\u4e0b\u3067\u3082\u9000\u8272\u304c\u307f\u3089\u308c\u305a\u3001BODIPY-C<sub>12<\/sub>\u3088\u308a\u3082\u5149\u5b89\u5b9a\u6027\u304c\u9ad8\u3044\u3053\u3068\u304c\u308f\u304b\u308a\u307e\u3057\u305f\u3002<\/p>\n<p>\u5f37\u3044\u7d2b\u5916\u5149\uff08365 nm\uff09\u3092\u6eb6\u6db2\u306b\u9577\u6642\u9593\u5f53\u3066\u7d9a\u3051\u3001\u5438\u5149\u5ea6\u306e\u6e1b\u8870\u3092\u89b3\u5bdf\u3057\u305f\u3068\u3053\u308d\u3001BODIPY-C<sub>12<\/sub>\u306e\u6eb6\u6db2\u3067\u306f\u3001700 mW\/cm<sup>2<\/sup>\u306e\u7d2b\u5916\u5149\u30925\u6642\u9593\u7167\u5c04\u5f8c\u306b\u5438\u5149\u5ea6\u304c\u6e2c\u5b9a\u958b\u59cb\u6642\u306e63%\u307e\u3067\u6e1b\u8870\u3057\u305f\u306e\u306b\u5bfe\u3057\u3001Perylene FLAP\u306e\u6eb6\u6db2\u3067\u306f10\u6642\u9593\u307e\u3067\u307e\u3063\u305f\u304f\u6e1b\u8870\u304c\u89b3\u5bdf\u3055\u308c\u307e\u305b\u3093\u3067\u3057\u305f\u3002\u3053\u306e\u7d50\u679c\u3082Perylene FLAP\u306e\u86cd\u5149\u7c98\u5ea6\u30d7\u30ed\u30fc\u30d6\u3068\u3057\u3066\u306e\u5b9f\u7528\u6027\u3092\u793a\u3057\u3066\u304a\u308a\u3001\u30ec\u30fc\u30b6\u30fc\u3092\u7528\u3044\u308b\u30a4\u30e1\u30fc\u30b8\u30f3\u30b0\u6280\u8853\u3078\u306e\u5fdc\u7528\u304c\u671f\u5f85\u3067\u304d\u307e\u3059\u3002<\/p>\n<h3>\u86cd\u5149\u7c98\u5ea6\u30d7\u30ed\u30fc\u30d6\u306e\u5149\u6280\u8853\u3078\u306e\u5fdc\u7528\u3082\u8996\u91ce\u306b<\/h3>\n<p>\u4eca\u56de\u65b0\u305f\u306b\u958b\u767a\u3057\u305f\u300c\u7fbd\u3070\u305f\u304f\u86cd\u5149\u7c98\u5ea6\u30d7\u30ed\u30fc\u30d6\u300dPerylene FLAP\u306f\u30011\uff09\u53ef\u8996\u5149\u9818\u57df\u306b\u5f37\u3044\u5438\u53ce\u3092\u3082\u3061\u30012\uff09\u9577\u6642\u9593\u30fb\u9ad8\u5f37\u5ea6\u306e\u5149\u306b\u5bfe\u3057\u3066\u5b89\u5b9a\u3067\u3042\u308a\u30013\uff093 cP\u4ee5\u4e0b\u306e\u5fae\u5c0f\u7c98\u5ea6\u5909\u5316\u306b\u3082\u5fdc\u7b54\u3057\u3066\u3001\u5f93\u6765\u306e\u56de\u8ee2\u578b\u30d7\u30ed\u30fc\u30d6\uff08BODIPY\uff09\u3088\u308a\u3082\u92ed\u654f\u306b\u86cd\u5149\u5bff\u547d\u3092\u5909\u5316\u3055\u305b\u308b\u30d5\u30eb\u30aa\u30ed\u30b8\u30a7\u30cb\u30c3\u30af\u306a\u6027\u8cea\u304c\u3042\u308b\u3053\u3068\u304c\u660e\u3089\u304b\u306b\u306a\u308a\u307e\u3057\u305f\u3002<\/p>\n<p>\u3053\u308c\u3089\u306e\u7279\u6027\u3092\u5229\u7528\u3059\u308c\u3070\u3001\u30ec\u30fc\u30b6\u30fc\u6280\u8853\u3001\u7279\u306b\u86cd\u5149\u5bff\u547d\u9855\u5fae\u93e1\u6280\u8853\uff08FLIM\uff09\u3068\u7d44\u307f\u5408\u308f\u305b\u308b\u3053\u3068\u306b\u3088\u3063\u3066\u3001\u4e0d\u5747\u4e00\u7cfb\u306b\u304a\u3051\u308b\u5c40\u6240\u7c98\u5ea6\u306e\u5b9a\u91cf\u3084\u7c98\u5ea6\u30e0\u30e9\u306e\u53ef\u8996\u5316\u6280\u8853\u306b\u5fdc\u7528\u3067\u304d\u308b\u53ef\u80fd\u6027\u304c\u3042\u308a\u307e\u3059\u3002\u5177\u4f53\u7684\u306b\u306f\u3001\u86cd\u5149\u5bff\u547d\u306e\u9055\u3044\u3088\u3063\u3066\u6709\u6a5f\u8584\u819c\u306a\u3069\u306e\u6750\u6599\u306e\u786c\u3055\u3092\u975e\u7834\u58ca\u7684\u306b\u8a55\u4fa1\u3059\u308b\u3053\u3068\u3084\u3001\u3055\u3089\u306b\u5c06\u6765\u7684\u306b\u306f\u3001\u6c34\u6eb6\u6027\u3092\u4ed8\u4e0e\u3059\u308b\u3053\u3068\u306b\u3088\u3063\u3066\u8840\u6f3f\u7c98\u5ea6\u306e\u5b9a\u91cf\u3084\u5065\u5eb7\u8a3a\u65ad\u3078\u306e\u5fdc\u7528\u3082\u53ef\u80fd\u306b\u306a\u308b\u3068\u8003\u3048\u3066\u3044\u307e\u3059\u3002<\/p>\n<p><b>\u53c2\u8003\u6587\u732e<\/b><\/p>\n<ul>\n<li>R. Kimura, H. Kuramochi, P. Liu, T. Yamakado, A. Osuka, T. Tahara, S. Saito, <em>Angew. Chem. Int. Ed. <\/em>2020, in press\uff08DOI:10.1002\/anie.202006198\uff09<a href=\"https:\/\/onlinelibrary.wiley.com\/doi\/abs\/10.1002\/anie.202006198\">https:\/\/onlinelibrary.wiley.com\/doi\/abs\/10.1002\/anie.202006198<\/a><br \/>\n\u30d7\u30ec\u30b9\u30ea\u30ea\u30fc\u30ba: \u308f\u305a\u304b\u306a\u7c98\u5ea6\u306e\u9055\u3044\u3092\u611f\u3058\u3068\u308b\u300c\u7fbd\u3070\u305f\u304f\u86cd\u5149\u5206\u5b50\u300d\u3092\u958b\u767a \uff0d\u30ca\u30ce\u30b5\u30a4\u30ba\u306e\u52d5\u304d\u3067\u6db2\u4f53\u306e\u30b5\u30e9\u30b5\u30e9\u5ea6\u3092\u6e2c\u308b\uff0d<br \/>\n<a href=\"http:\/\/www.kyoto-u.ac.jp\/ja\/research\/research_results\/2020\/200612_1.html\">http:\/\/www.kyoto-u.ac.jp\/ja\/research\/research_results\/2020\/200612_1.html<\/a><\/li>\n<li>R. Kimura, H. Kitakado, A. Osuka, S. Saito, <em>Bull. Chem. Soc. Jpn.<\/em> 2020, in press\uff08DOI: 10.1246\/bcsj.20200117\uff09<br \/>\n<a href=\"https:\/\/www.journal.csj.jp\/doi\/full\/10.1246\/bcsj.20200117\">https:\/\/www.journal.csj.jp\/doi\/full\/10.1246\/bcsj.20200117<\/a><\/li>\n<li>R. Kotani, H. Sotome, H. Okajima, S. Yokoyama, Y. Nakaike, A. Kashiwagi, C. Mori, Y. Nakada, S. Yamaguchi, A. Osuka, A. Sakamoto, H. Miyasaka, S. Saito, <em>J. Mater. Chem. C<\/em>, 2017, <em>5<\/em>, 5248.<\/li>\n<\/ul>\n","protected":false},"excerpt":{"rendered":"<p>\u4e0d\u5747\u4e00\u7cfb\u306e\u300c\u30e0\u30e9\u300d\u3092\u3069\u3046\u5b9a\u91cf\u7684\u306b\u8a55\u4fa1\u3059\u308b\u304b\uff1f \u4e0d\u5747\u4e00\u306a\u7cfb\u306b\u304a\u3044\u3066\u3001\u3055\u307e\u3056\u307e\u306a\u8981\u56e0\u3067\u767a\u751f\u3059\u308b\u300c\u30e0\u30e9\u300d\u3092\u5b9a\u91cf\u7684\u306b\u8a55\u4fa1\u3059\u308b\u3053\u3068\u306f\u3001\u57fa\u790e\u79d1\u5b66\u306e\u307f\u306a\u3089\u305a\u5de5\u696d\u7684\u306b\u3082\u91cd\u8981\u3067\u3059\u3002\u8fd1\u5e74\u3067\u306f\u3001\u4e0d\u5747\u4e00\u7cfb\u306e\u5c40\u6240\u7c98\u5ea6\u3092\u5b9a\u91cf\u3059\u308b [&hellip;]<\/p>\n","protected":false},"author":516,"featured_media":14138,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_acf_changed":false,"_monsterinsights_skip_tracking":false,"_monsterinsights_sitenote_active":false,"_monsterinsights_sitenote_note":"","_monsterinsights_sitenote_category":0,"footnotes":""},"categories":[3],"tags":[20,59],"class_list":["post-14139","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-outcome","tag-20","tag-59","has_thumb"],"acf":[],"aioseo_notices":[],"_links":{"self":[{"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=\/wp\/v2\/posts\/14139","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=\/wp\/v2\/users\/516"}],"replies":[{"embeddable":true,"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=14139"}],"version-history":[{"count":17,"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=\/wp\/v2\/posts\/14139\/revisions"}],"predecessor-version":[{"id":14363,"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=\/wp\/v2\/posts\/14139\/revisions\/14363"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=\/wp\/v2\/media\/14138"}],"wp:attachment":[{"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=14139"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=14139"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=14139"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}