{"id":13963,"date":"2020-08-12T08:00:37","date_gmt":"2020-08-11T23:00:37","guid":{"rendered":"https:\/\/academist-cf.com\/journal\/?p=13963"},"modified":"2020-08-30T21:07:36","modified_gmt":"2020-08-30T12:07:36","slug":"%e3%83%8a%e3%83%8e%e3%82%b7%e3%83%bc%e3%83%88%e3%81%a8%e8%89%b2%e7%b4%a0%e3%81%ab%e3%82%88%e3%82%8b%e3%80%8c%e8%89%b2%e7%b4%a0%e5%a2%97%e6%84%9f%e5%9e%8b%e5%85%89%e8%a7%a6%e5%aa%92%e3%80%8d%e3%81%a7","status":"publish","type":"post","link":"https:\/\/academist-cf.com\/journal\/?p=13963","title":{"rendered":"\u30ca\u30ce\u30b7\u30fc\u30c8\u3068\u8272\u7d20\u306b\u3088\u308b\u300c\u8272\u7d20\u5897\u611f\u578b\u5149\u89e6\u5a92\u300d\u3067\u3001\u592a\u967d\u5149\u3068\u6c34\u304b\u3089\u6c34\u7d20\u3092\u9ad8\u52b9\u7387\u306b\u751f\u307f\u51fa\u3059"},"content":{"rendered":"<style type=\"text\/css\">\n<!--\nol.list_parentheses{\n  margin-left: 3em;\n}\nol.list_parentheses li{\n  list-style-type:none;\n  list-style-position:inside;\n  counter-increment:cnt;\n  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id=\"attachment_13987\" aria-describedby=\"caption-attachment-13987\" style=\"width: 600px\" class=\"wp-caption aligncenter\"><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2020\/07\/002-11.jpg\" alt=\"\" width=\"600\" height=\"301\" class=\"size-full wp-image-13987\" srcset=\"https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2020\/07\/002-11.jpg 600w, https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2020\/07\/002-11-300x151.jpg 300w\" sizes=\"auto, (max-width: 600px) 100vw, 600px\" \/><figcaption id=\"caption-attachment-13987\" class=\"wp-caption-text\">\u5c64\u72b6HCa<sub>2<\/sub>Nb<sub>3<\/sub>O<sub>10<\/sub>\u3068\u5c64\u5265\u96e2\u306b\u3088\u308a\u751f\u6210\u3057\u305f\u30ca\u30ce\u30b7\u30fc\u30c8<\/figcaption><\/figure>\n<p>\u5b9f\u969b\u306bPt\u30ca\u30ce\u7c92\u5b50\u306b\u3088\u308a\u4fee\u98fe\u3057\u305fHCa<sub>2<\/sub>Nb<sub>3<\/sub>O<sub>10<\/sub>\u30ca\u30ce\u30b7\u30fc\u30c8\u306b\u5bfe\u3057\u3066\u3001\u8272\u7d20\u5206\u5b50\u3068\u3057\u3066Ru\u932f\u4f53\u3092\u5438\u7740\u3055\u305b\u305f\u8907\u5408\u4f53\u3092\u6c34\u7d20\u767a\u751f\u5149\u89e6\u5a92\u306b\u7528\u3044\u3001WO<sub>3<\/sub>\u7cfb\u306e\u9178\u7d20\u751f\u6210\u5149\u89e6\u5a92\u3068\u30e8\u30a6\u7d20\u7cfb\u96fb\u5b50\u4f1d\u9054\u5264\uff08I<sub>3<\/sub><sup>&#8211;<\/sup>\/I<sup>&#8211;<\/sup>\uff09\u3092\u7d44\u307f\u5408\u308f\u305b\u308b\u3053\u3068\u3067\u3001\u53ef\u8996\u5149\u306b\u3088\u308a\u6c34\u3092\u6c34\u7d20\u3068\u9178\u7d20\u306b\u5206\u89e3\u3059\u308b\u3053\u3068\u306b\u6210\u529f\u3057\u307e\u3057\u305f\u3002\u3055\u3089\u306bHCa<sub>2<\/sub>Nb<sub>3<\/sub>O<sub>10<\/sub>\u30ca\u30ce\u30b7\u30fc\u30c8\u306e\u8868\u9762\u3092Al<sub>2<\/sub>O<sub>3<\/sub>\u306b\u3088\u308a\u4fee\u98fe\u3059\u308b\u3053\u3068\u3067\u3001\u6c34\u5206\u89e3\u6d3b\u6027\u304c\u5927\u5e45\u306b\u5411\u4e0a\u3059\u308b\u3053\u3068\u3082\u898b\u51fa\u3057\u307e\u3057\u305f\u3002<\/p>\n<p>\u7a2e\u3005\u306e\u6700\u9069\u5316\u3092\u884c\u3063\u305f\u3068\u3053\u308d\u3001\u89e6\u5a92\u6d3b\u6027\u3092\u8868\u3059\u5024\u3067\u3042\u308b\u30bf\u30fc\u30f3\u30aa\u30fc\u30d0\u30fc\u983b\u5ea6\u306f1960\uff08\u6bce\u6642\uff09\u3068\u306a\u308a\u3001\u3053\u308c\u307e\u3067\u306b\u5831\u544a\u3055\u308c\u3066\u304d\u305f\u985e\u4f3c\u306e\u8272\u7d20\u5897\u611f\u578b\u306e\u6c34\u5206\u89e3\u5149\u89e6\u5a92\u3068\u6bd4\u8f03\u3057\u3066200\u500d\u4ee5\u4e0a\u3082\u5927\u304d\u306a\u5024\u3068\u306a\u308a\u307e\u3057\u305f\u3002\u307e\u305f\u89e6\u5a92\u8010\u4e45\u6027\u3092\u8868\u3059\u5024\u3067\u3042\u308b\u30bf\u30fc\u30f3\u30aa\u30fc\u30d0\u30fc\u30ca\u30f3\u30d0\u30fc\u3082\u904e\u53bb\u306b\u5831\u544a\u3055\u308c\u3066\u3044\u308b\u5024\u306e\u7d049\u500d\u306e4580\u3068\u306a\u308a\u3001\u8010\u4e45\u6027\u306e\u5411\u4e0a\u306b\u3082\u6210\u529f\u3057\u307e\u3057\u305f\u3002\u3053\u308c\u3089\u306e\u5024\u306f\u4e16\u754c\u6700\u9ad8\u5024\u3067\u3042\u308a\u3001\u9178\u5316\u7269\u30ca\u30ce\u30b7\u30fc\u30c8\u304c\u8272\u7d20\u5897\u611f\u578b\u5149\u89e6\u5a92\u3068\u3057\u3066\u6709\u671b\u306a\u6750\u6599\u3067\u3042\u308b\u3053\u3068\u3092\u793a\u3057\u307e\u3057\u305f\u3002<\/p>\n<figure id=\"attachment_13988\" aria-describedby=\"caption-attachment-13988\" style=\"width: 600px\" class=\"wp-caption aligncenter\"><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2020\/07\/003-8.jpg\" alt=\"\" width=\"600\" height=\"318\" class=\"size-full wp-image-13988\" srcset=\"https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2020\/07\/003-8.jpg 600w, https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2020\/07\/003-8-300x159.jpg 300w\" sizes=\"auto, (max-width: 600px) 100vw, 600px\" \/><figcaption id=\"caption-attachment-13988\" class=\"wp-caption-text\">Al<sub>2<\/sub>O<sub>3<\/sub>\u4fee\u98fePt\/HCa<sub>2<\/sub>Nb<sub>3<\/sub>O<sub>10<\/sub>\u30ca\u30ce\u30b7\u30fc\u30c8\u3068WO<sub>3<\/sub>\u5149\u89e6\u5a92\u306b\u3088\u308b\u6c34\u5206\u89e3\u53cd\u5fdc\u306e\u6a21\u5f0f\u56f3<\/figcaption><\/figure>\n<h3>\u30ec\u30fc\u30b6\u30fc\u5206\u5149\u3067Al<sub>2<\/sub>O<sub>3<\/sub>\u306e\u4fee\u98fe\u52b9\u679c\u3092\u8abf\u3079\u308b<\/h3>\n<p>HCa<sub>2<\/sub>Nb<sub>3<\/sub>O<sub>10<\/sub>\u30ca\u30ce\u30b7\u30fc\u30c8\u3092\u7528\u3044\u305f\u8272\u7d20\u5897\u611f\u578b\u5149\u89e6\u5a92\u306b\u304a\u3044\u3066\u3001\u9ad8\u3044\u6d3b\u6027\u3092\u5f97\u308b\u305f\u3081\u306b\u306fAl<sub>2<\/sub>O<sub>3<\/sub>\u306b\u3088\u308b\u4fee\u98fe\u304c\u5fc5\u8981\u4e0d\u53ef\u6b20\u3067\u3057\u305f\u3002\u6211\u3005\u306f\u305d\u306e\u7406\u7531\u306b\u975e\u5e38\u306b\u8208\u5473\u3092\u3082\u3061\u8a73\u3057\u304f\u8abf\u3079\u308b\u3053\u3068\u306b\u3057\u307e\u3057\u305f\u3002\u3053\u306e\u8272\u7d20\u5897\u611f\u578b\u5149\u89e6\u5a92\u306e\u8a73\u3057\u3044\u96fb\u5b50\u79fb\u52d5\u30e1\u30ab\u30cb\u30ba\u30e0\u3092\u4e0b\u56f3\u306b\u793a\u3057\u307e\u3059\u3002\u306f\u3058\u3081\u306b\u53ef\u8996\u5149\u3092\u5438\u53ce\u3057\u305fRu\u8272\u7d20\u304b\u3089HCa<sub>2<\/sub>Nb<sub>3<\/sub>O<sub>10<\/sub>\u30ca\u30ce\u30b7\u30fc\u30c8\u3078\u96fb\u5b50\u6ce8\u5165\u304c\u8d77\u3053\u308a\u3001Ru\u8272\u7d20\u306f\u96fb\u5b50\u304c\u3072\u3068\u3064\u4e0d\u8db3\u3057\u305f\u72b6\u614b\u306b\u306a\u308a\u307e\u3059\u3002\u30ca\u30ce\u30b7\u30fc\u30c8\u306b\u6ce8\u5165\u3055\u308c\u305f\u96fb\u5b50\u306f\u4e3b\u306b\u4ee5\u4e0b\u306e2\u3064\u306e\u65b9\u6cd5\u306b\u3088\u3063\u3066\u6d88\u8cbb\u3055\u308c\u307e\u3059\u3002<\/p>\n<ol class=\"list_parentheses\">\n<li>Pt\u30ca\u30ce\u7c92\u5b50\u3078\u79fb\u52d5\u3057\u6c34\u7d20\u3092\u767a\u751f\u3055\u305b\u308b\u3002\u96fb\u5b50\u4e0d\u8db3\u72b6\u614b\u306eRu\u8272\u7d20\u306f\u96fb\u5b50\u4f9b\u4e0e\u5264\u3067\u3042\u308b\u30e8\u30a6\u5316\u7269\u30a4\u30aa\u30f3\uff08I<sup>&#8211;<\/sup>\uff09\u304b\u3089\u96fb\u5b50\u3092\u53d7\u3051\u53d6\u308b<\/li>\n<li>\u96fb\u5b50\u4e0d\u8db3\u72b6\u614b\u306eRu\u8272\u7d20\u306b\u623b\u308b\uff08\u9006\u96fb\u5b50\u79fb\u52d5\uff09<\/li>\n<\/ol>\n<p>(2) \u306e\u9006\u96fb\u5b50\u79fb\u52d5\u306f\u6c34\u7d20\u3092\u767a\u751f\u3055\u305b\u308b\u3053\u3068\u306a\u304f\u5143\u306e\u72b6\u614b\u306b\u623b\u3063\u3066\u3057\u307e\u3046\u305f\u3081\u3001\u53cd\u5fdc\u306e\u52b9\u7387\u3092\u4f4e\u4e0b\u3055\u305b\u308b\u539f\u56e0\u3068\u306a\u308a\u307e\u3059\u3002<\/p>\n<figure id=\"attachment_13989\" aria-describedby=\"caption-attachment-13989\" style=\"width: 600px\" class=\"wp-caption aligncenter\"><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2020\/07\/004-6.jpg\" alt=\"\" width=\"600\" height=\"409\" class=\"size-full wp-image-13989\" srcset=\"https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2020\/07\/004-6.jpg 600w, https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2020\/07\/004-6-300x205.jpg 300w\" sizes=\"auto, (max-width: 600px) 100vw, 600px\" \/><figcaption id=\"caption-attachment-13989\" class=\"wp-caption-text\">Ru\u8272\u7d20\u3068HCa<sub>2<\/sub>Nb<sub>3<\/sub>O<sub>10<\/sub>\u30ca\u30ce\u30b7\u30fc\u30c8\u9593\u306b\u304a\u3051\u308b\u96fb\u5b50\u79fb\u52d5\u30e1\u30ab\u30cb\u30ba\u30e0<\/figcaption><\/figure>\n<p>Al<sub>2<\/sub>O<sub>3<\/sub>\u306fHCa<sub>2<\/sub>Nb<sub>3<\/sub>O<sub>10<\/sub>\u30ca\u30ce\u30b7\u30fc\u30c8\u304b\u3089\u306e\u9006\u96fb\u5b50\u79fb\u52d5\u904e\u7a0b\u3001\u307e\u305f\u306fI<sup>&#8211;<\/sup>\u304b\u3089\u306e\u96fb\u5b50\u4f9b\u4e0e\u904e\u7a0b\u306e\u3069\u3061\u3089\u304b\u306b\u5f71\u97ff\u3092\u4e0e\u3048\u3066\u3044\u308b\u306e\u3067\u306f\u306a\u3044\u304b\u3068\u8003\u3048\u3001\u30ec\u30fc\u30b6\u30fc\u5206\u5149\u3092\u7528\u3044\u3066\u8a73\u7d30\u306a\u691c\u8a0e\u3092\u884c\u3044\u307e\u3057\u305f\u3002\u3053\u306e\u6e2c\u5b9a\u3067\u306f\u30ec\u30fc\u30b6\u30fc\u5149\u3092\u5438\u53ce\u3057\u305f\u8272\u7d20\u5206\u5b50\u306e\u5909\u5316\u3092\u30ca\u30ce\u79d2\uff0810\u5104\u5206\u306e1\u79d2\uff09\u3068\u3044\u3046\u975e\u5e38\u306b\u77ed\u3044\u6642\u9593\u30b9\u30b1\u30fc\u30eb\u3067\u89b3\u6e2c\u3059\u308b\u3053\u3068\u304c\u3067\u304d\u307e\u3059\u3002<\/p>\n<p>\u3053\u306e\u6e2c\u5b9a\u306b\u3088\u308a\u96fb\u5b50\u4e0d\u8db3\u72b6\u614b\u306eRu\u8272\u7d20\u3092\u89b3\u6e2c\u3057\u3066\u3068\u3053\u308d\u3001\u96fb\u5b50\u4f9b\u4e0e\u5264\u3067\u3042\u308b\u30e8\u30a6\u5316\u7269\u30a4\u30aa\u30f3\u304c\u5b58\u5728\u3057\u306a\u3044\u6761\u4ef6\u3001\u3059\u306a\u308f\u3061HCa<sub>2<\/sub>Nb<sub>3<\/sub>O<sub>10<\/sub>\u30ca\u30ce\u30b7\u30fc\u30c8\u304b\u3089\u306e\u9006\u96fb\u5b50\u79fb\u52d5\u306e\u307f\u304c\u9032\u884c\u3059\u308b\u6761\u4ef6\u3067\u306f\u3001Ru\u8272\u7d20\u304c\u5143\u306e\u72b6\u614b\u306b\u623b\u308b\u901f\u5ea6\u306f\u4e00\u5b9a\u3067\u3042\u308b\u3053\u3068\u304c\u308f\u304b\u308a\u307e\u3057\u305f\u3002\u3064\u307e\u308aAl<sub>2<\/sub>O<sub>3<\/sub>\u306f (2) 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\/>\nTakayoshi Oshima, Shunta Nishioka, Yuka Kikuchi, Shota Hirai, Kei-ichi Yanagisawa, Miharu Eguchi, Yugo Miseki, Toshiyuki Yokoi, Tatsuto Yui, Koji Kimoto, Kazuhiro Sayama, Osamu Ishitani, Thomas E. Mallouk*, and Kazuhiko Maeda*\u3000&#8221;An Artificial Z-Scheme Constructed from Dye-Sensitized Metal Oxide Nanosheets for Visible Light-Driven Overall Water Splitting&#8221; <em>J. Am. Chem. Soc.<\/em> 2020, 142, 18, 8412-8420<br \/>\n<a href=\"https:\/\/doi.org\/10.1021\/jacs.0c02053\">https:\/\/doi.org\/10.1021\/jacs.0c02053<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u5149\u89e6\u5a92\u3067\u592a\u967d\u5149\u30a8\u30cd\u30eb\u30ae\u30fc\u3092\u52b9\u7387\u7684\u306b\u5909\u63db\u3059\u308b\u306b\u306f\uff1f \u73fe\u5728\u306e\u6211\u3005\u306e\u751f\u6d3b\u306f\u3001\u77f3\u6cb9\u3084\u5929\u7136\u30ac\u30b9\u306a\u3069\u306e\u5316\u77f3\u8cc7\u6e90\u3092\u4e3b\u306a\u30a8\u30cd\u30eb\u30ae\u30fc\u6e90\u3068\u3057\u3066\u5229\u7528\u3059\u308b\u3053\u3068\u3067\u652f\u3048\u3089\u308c\u3066\u3044\u307e\u3059\u3002\u3057\u304b\u3057\u3001\u5316\u77f3\u71c3\u6599\u306e\u67af\u6e07\u3084\u5927\u6c17\u4e2d\u306e\u4e8c\u9178\u5316\u70ad\u7d20\u6fc3\u5ea6 [&hellip;]<\/p>\n","protected":false},"author":509,"featured_media":13988,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_acf_changed":false,"_monsterinsights_skip_tracking":false,"_monsterinsights_sitenote_active":false,"_monsterinsights_sitenote_note":"","_monsterinsights_sitenote_category":0,"footnotes":""},"categories":[3],"tags":[20,139],"class_list":["post-13963","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-outcome","tag-20","tag-139","has_thumb"],"acf":[],"aioseo_notices":[],"_links":{"self":[{"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=\/wp\/v2\/posts\/13963","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=\/wp\/v2\/users\/509"}],"replies":[{"embeddable":true,"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=13963"}],"version-history":[{"count":19,"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=\/wp\/v2\/posts\/13963\/revisions"}],"predecessor-version":[{"id":14367,"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=\/wp\/v2\/posts\/13963\/revisions\/14367"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=\/wp\/v2\/media\/13988"}],"wp:attachment":[{"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=13963"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=13963"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=13963"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}