{"id":13392,"date":"2020-06-10T08:00:07","date_gmt":"2020-06-09T23:00:07","guid":{"rendered":"https:\/\/academist-cf.com\/journal\/?p=13392"},"modified":"2020-06-27T14:56:31","modified_gmt":"2020-06-27T05:56:31","slug":"%e4%ba%8c%e5%8e%9f%e5%ad%90%e7%82%ad%e7%b4%a0%ef%bc%88c2%ef%bc%89%e3%81%ae%e5%8c%96%e5%ad%a6%e5%90%88%e6%88%90%e3%81%ab%e6%88%90%e5%8a%9f%ef%bc%81-%e6%98%8e%e3%82%89%e3%81%8b%e3%81%ab%e3%81%aa","status":"publish","type":"post","link":"https:\/\/academist-cf.com\/journal\/?p=13392","title":{"rendered":"\u4e8c\u539f\u5b50\u70ad\u7d20\uff08C2\uff09\u306e\u5316\u5b66\u5408\u6210\u306b\u6210\u529f\uff01 &#8211; \u660e\u3089\u304b\u306b\u306a\u3063\u305f4\u3064\u306e\u7d50\u5408\u3068\u30ca\u30ce\u30ab\u30fc\u30dc\u30f3\u306e\u8d77\u6e90"},"content":{"rendered":"<h3>C<sub>2<\/sub>\u3068\u3044\u3046\u8b0e\u306e\u5206\u5b50<\/h3>\n<p>\u4e8c\u539f\u5b50\u70ad\u7d20\uff08C<sub>2<\/sub>\uff09\u306f\u70ad\u7d202\u3064\u304b\u3089\u69cb\u6210\u3055\u308c\u308b\u3001\u5730\u7403\u4e0a\u306b\u304a\u3044\u3066\u6700\u3082\u5358\u7d14\u306a\u70ad\u7d20\u5206\u5b50\u3067\u3059\u3002\u53e4\u304f\u304b\u3089\u3001\u308d\u3046\u305d\u304f\u306e\u9752\u3044\u708e\u3084\u5b87\u5b99\u7a7a\u9593\u306b\u5b58\u5728\u3059\u308b\u3053\u3068\u304c\u77e5\u3089\u308c\u3066\u304d\u307e\u3057\u305f\u304c\u3001\u767a\u898b\u304b\u30891\u4e16\u7d00\u304c\u904e\u304e\u305f\u73fe\u5728\u3067\u3082\u3001\u305d\u306e\u57fa\u672c\u7684\u6027\u8cea\u3055\u3048\u8b0e\u306b\u5305\u307e\u308c\u3066\u3044\u307e\u3059\u3002<\/p>\n<p>\u3053\u308c\u307e\u3067\u3001C<sub>2<\/sub>\u306f\u904e\u9177\u306a\u6761\u4ef6\uff08\u305f\u3068\u3048\u3070\u30013500\u2103\u4ee5\u4e0a\u306b\u3057\u305f\u70ad\u7d20\u84b8\u6c17\uff09\u3067\u3057\u304b\u767a\u751f\u3057\u306a\u3044\u3068\u8003\u3048\u3089\u308c\u3066\u304d\u305f\u305f\u3081\u3001\u9ad8\u30a8\u30cd\u30eb\u30ae\u30fc\u72b6\u614b\u3067\u306e\u767a\u751f\u30fb\u8abf\u67fb\u30fb\u7814\u7a76\u304c\u884c\u308f\u308c\u3066\u304d\u307e\u3057\u305f\u3002\u9ed2\u925b\u3078\u306e\u30a2\u30fc\u30af\u653e\u96fb\u3084\u30ec\u30fc\u30b6\u30fc\u5149\u7167\u5c04\u306a\u3069\u306b\u3088\u308aC<sub>2<\/sub>\u3092\u4eba\u5de5\u7684\u306b\u767a\u751f\u3055\u305b\u308b\u3053\u3068\u304c\u3067\u304d\u307e\u3059\u304c\u3001\u3053\u3046\u3057\u3066\u767a\u751f\u3055\u305b\u305fC<sub>2<\/sub>\u306f\u3001\u300c\u4e8c\u91cd\u7d50\u5408\uff08\u4e00\u91cd\u9805\u30b8\u30ab\u30eb\u30d9\u30f3\uff09\u300d\u304b\u300c\u4e09\u91cd\u7d50\u5408\uff08\u4e09\u91cd\u9805\u30d3\u30e9\u30b8\u30ab\u30eb\uff09\u300d\u3068\u3057\u3066\u632f\u308b\u821e\u3046\u3068\u5b9f\u9a13\u5316\u5b66\u306b\u3088\u3063\u3066\u7d50\u8ad6\u3065\u3051\u3089\u308c\u3066\u304d\u307e\u3057\u305f\u3002<\/p>\n<p>\u3068\u3053\u308d\u304c\u30012012\u5e74\u306b\u30a4\u30b9\u30e9\u30a8\u30eb\u306e\u30b0\u30eb\u30fc\u30d7\u3089\u306f\u3001\u9ad8\u7cbe\u5ea6\u91cf\u5b50\u5316\u5b66\u8a08\u7b97\u3092\u7528\u3044\u3066\u300cC<sub>2<\/sub>\u306f\u57fa\u5e95\u72b6\u614b\u306b\u304a\u3044\u3066\u201c\u56db\u91cd\u7d50\u5408\uff08\u4e00\u91cd\u9805\u30d3\u30e9\u30b8\u30ab\u30eb\uff09\u6027\u201d\u3092\u3082\u3064\u300d\u3068\u63d0\u5531\u3057\u307e\u3057\u305f\u3002\u3059\u306a\u308f\u3061\u3001\u5b9f\u9a13\u5316\u5b66\u8005\u3068\u7406\u8ad6\u5316\u5b66\u8005\u306e\u898b\u89e3\u306f\u771f\u3063\u5411\u304b\u3089\u5bfe\u7acb\u3057\u3001\u5927\u304d\u306a\u8b70\u8ad6\u3078\u3068\u767a\u5c55\u3057\u3066\u3044\u307e\u3057\u305f\u3002<\/p>\n<figure id=\"attachment_13393\" aria-describedby=\"caption-attachment-13393\" style=\"width: 600px\" class=\"wp-caption aligncenter\"><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-13393\" src=\"https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2020\/06\/001.jpg\" alt=\"\" width=\"600\" height=\"450\" srcset=\"https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2020\/06\/001.jpg 600w, https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2020\/06\/001-300x225.jpg 300w\" sizes=\"auto, (max-width: 600px) 100vw, 600px\" \/><figcaption id=\"caption-attachment-13393\" class=\"wp-caption-text\">C<sub>2<\/sub>\u306e\u7d50\u5408\u306b\u95a2\u3059\u308b\u5b9f\u9a13\u5316\u5b66\u8005\u3068\u7406\u8ad6\u5316\u5b66\u8005\u306e\u9577\u5e74\u306e\u5bfe\u7acb<\/figcaption><\/figure>\n<div class=\"center\"><!--Ads1--><\/div>\n<h3>\u5e38\u6e29\u5e38\u5727\u3067C<sub>2<\/sub>\u306e\u5316\u5b66\u5408\u6210\u306b\u6210\u529f<\/h3>\n<p>\u79c1\u305f\u3061\u306f\u3001C<sub>2<\/sub>\u306b\u304a\u3051\u308b\u89e3\u91c8\u306e\u5927\u304d\u306a\u4e56\u96e2\u306f\u3001\u5b9f\u9a13\u6761\u4ef6\u3068\u7406\u8ad6\u6761\u4ef6\u306e\u9055\u3044\u306b\u3088\u308b\u3082\u306e\u3067\u306f\u306a\u3044\u304b\u3068\u8003\u3048\u307e\u3057\u305f\u3002\u3059\u306a\u308f\u3061\u3001\u7406\u8ad6\u6761\u4ef6\u3067\u306f\u57fa\u5e95\u72b6\u614b\uff08\u5b89\u5b9a\u72b6\u614b\uff09\u3067\u306eC<sub>2<\/sub>\u306e\u6027\u8cea\u3092\u8b70\u8ad6\u3057\u3066\u3044\u308b\u306e\u306b\u5bfe\u3057\u3066\u3001\u5b9f\u9a13\u5316\u5b66\u306b\u3088\u308bC<sub>2<\/sub>\u306e\u767a\u751f\u306b\u306f\u9ad8\u30a8\u30cd\u30eb\u30ae\u30fc\u304c\u5fc5\u8981\u3067\u3042\u3063\u305f\u305f\u3081\u3001\u52b1\u8d77\u72b6\u614b\uff08\u4e0d\u5b89\u5b9a\u306a\u72b6\u614b\uff09\u3067\u306e\u6027\u8cea\u3092\u89b3\u6e2c\u3057\u3066\u304d\u305f\u306e\u3067\u306f\u306a\u3044\u304b\u3068\u8003\u3048\u305f\u3068\u3053\u308d\u306b\u4eca\u56de\u306e\u7814\u7a76\u306e\u30b9\u30bf\u30fc\u30c8\u30e9\u30a4\u30f3\u304c\u3042\u308a\u307e\u3059\u3002<\/p>\n<p>\u305d\u3053\u3067\u672c\u7814\u7a76\u3067\u306f\u3001\u5ba4\u6e29\uff08\u3042\u308b\u3044\u306f\u305d\u308c\u4ee5\u4e0b\uff09\u3067\u306eC<sub>2<\/sub>\u306e\u767a\u751f\u6cd5\u306b\u53d6\u308a\u7d44\u307f\u307e\u3057\u305f\u3002\u79c1\u305f\u3061\u306f\u3001\u8d85\u539f\u5b50\u4fa1\u30cf\u30ed\u30b2\u30f3\u7d50\u5408\u306e\u7279\u5fb4\u306e\u3072\u3068\u3064\u3067\u3042\u308b\u201c\u8d85\u201d\u8131\u96e2\u80fd\u306f\u3001C<sub>2<\/sub>\u3092\u5316\u5b66\u5408\u6210\u3059\u308b\u9375\u3068\u306a\u308b\u304b\u3082\u3057\u308c\u306a\u3044\u3068\u8003\u3048\u307e\u3057\u305f\u3002\u3055\u3063\u305d\u304f\u3001\u8d85\u539f\u5b50\u4fa1\u30e8\u30a6\u7d20\u3068\u30b1\u30a4\u7d20\u5b98\u80fd\u57fa\u3067C<sub>2<\/sub>\u30e6\u30cb\u30c3\u30c8\u3092\u631f\u3093\u3060\u300c\u6f5c\u5728C<sub>2<\/sub>\u5206\u5b50\u300d(<strong>1a<\/strong>) \u3092\u30c7\u30b6\u30a4\u30f3\u3057\u3001\u3053\u308c\u306b\u30d5\u30c3\u7d20\u30a2\u30cb\u30aa\u30f3\u3092\u4f5c\u7528\u3055\u305b\u308b\u3068\u3001\u5ba4\u6e29\u4ee5\u4e0b\u3067\u3082\u30a2\u30bb\u30c1\u30ec\u30f3\uff08HCCH\uff09\u306e\u767a\u751f\u304c\u78ba\u8a8d\u3055\u308c\u307e\u3057\u305f\u3002<\/p>\n<figure id=\"attachment_13436\" aria-describedby=\"caption-attachment-13436\" style=\"width: 600px\" class=\"wp-caption aligncenter\"><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-13436\" src=\"https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2020\/06\/001-0.jpg\" alt=\"\" width=\"600\" height=\"203\" srcset=\"https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2020\/06\/001-0.jpg 600w, https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2020\/06\/001-0-300x102.jpg 300w\" sizes=\"auto, (max-width: 600px) 100vw, 600px\" \/><figcaption id=\"caption-attachment-13436\" class=\"wp-caption-text\">\u8d85\u539f\u5b50\u4fa1\u30e8\u30a6\u7d20\u3068\u30b1\u30a4\u7d20\u5b98\u80fd\u57fa\u3067C<sub>2<\/sub>\u30e6\u30cb\u30c3\u30c8\u3092\u631f\u3093\u3060\u300c\u6f5c\u5728C<sub>2<\/sub>\u5206\u5b50\u300d<\/figcaption><\/figure>\n<p>\u672c\u53cd\u5fdc\u306f\u3001\u6975\u3081\u3066\u5b89\u5b9a\u306a\u300c\u30b1\u30a4\u7d20\uff0d\u30d5\u30c3\u7d20\u7d50\u5408\u300d\u3092\u3064\u304f\u308b\u539f\u52d5\u529b\u306b\u3088\u3063\u3066\u4e2d\u9593\u4f53<strong>A<\/strong>\u304c\u3044\u3063\u305f\u3093\u751f\u6210\u3057\u305f\u5f8c\u3001\u8d85\u539f\u5b50\u4fa1\u30e8\u30a6\u7d20\u306e\u8131\u96e2\u306b\u3088\u3063\u3066C<sub>2<\/sub>\u304c\u901f\u3084\u304b\u306b\u767a\u751f\u3057\u3001\u305d\u306e\u5f8c\u6eb6\u5a92\uff08CH<sub>2<\/sub>Cl<sub>2<\/sub>\uff09\u306a\u3069\u304b\u3089\u6c34\u7d20\u3092\u7372\u5f97\u3057\u3001\u30a2\u30bb\u30c1\u30ec\u30f3\u304c\u751f\u3058\u305f\u3068\u8003\u3048\u3089\u308c\u307e\u3059\u3002\u3053\u3053\u306b\u3001\u5e38\u6e29\u5e38\u5727\u306b\u304a\u3051\u308bC<sub>2<\/sub>\u306e\u5316\u5b66\u5408\u6210\u306b\u4e16\u754c\u3067\u521d\u3081\u3066\u6210\u529f\u3057\u307e\u3057\u305f\u3002<\/p>\n<h3>4\u3064\u76ee\u306e\u7d50\u5408 &#8211; \u5b9f\u9a13\u5316\u5b66\u8005\u3068\u7406\u8ad6\u5316\u5b66\u8005\u306e\u9577\u5e74\u306e\u8ad6\u4e89\u306b\u6c7a\u7740<\/h3>\n<p>\u3053\u3046\u3057\u3066\u767a\u751f\u3055\u305b\u305fC<sub>2<\/sub>\u306e\u6027\u8cea\u3092\u5b9f\u9a13\u5316\u5b66\u3092\u7528\u3044\u3066\u4e01\u5be7\u306b\u8abf\u3079\u305f\u3068\u3053\u308d\u3001\u9ad8\u30a8\u30cd\u30eb\u30ae\u30fc\u6761\u4ef6\u4e0b\u306b\u304a\u3051\u308bC<sub>2<\/sub>\u3068\u306f\u307e\u3063\u305f\u304f\u7570\u306a\u308b\u6319\u52d5\u3092\u793a\u3059\u3053\u3068\u304c\u660e\u3089\u304b\u3068\u306a\u3063\u3066\u304d\u307e\u3057\u305f\u3002\u305f\u3068\u3048\u3070\u3001\u9ad8\u30a8\u30cd\u30eb\u30ae\u30fc\u306b\u3066\u767a\u751f\u3055\u305b\u305fC<sub>2<\/sub>\u3092\u6355\u6349\u3059\u308b\u3053\u3068\u304c\u5831\u544a\u3055\u308c\u3066\u3044\u308b\u30b7\u30af\u30ed\u30aa\u30af\u30bf\u30c6\u30c8\u30e9\u30a8\u30f3\u3084\u3001\u30a2\u30bb\u30c8\u30d5\u30a7\u30ce\u30f3\u3001\u30b7\u30af\u30ed\u30aa\u30af\u30bf\u30f3\u3092\u53cd\u5fdc\u306b\u7528\u3044\u3066\u3082\u3001\u4eca\u56de\u5408\u6210\u3057\u305fC<sub>2<\/sub>\u306f\u307e\u3063\u305f\u304f\u6355\u6349\u3055\u308c\u307e\u305b\u3093\u3067\u3057\u305f\u3002\u3064\u307e\u308a\u3001\u5e38\u6e29\u5e38\u5727\u306b\u3066\u767a\u751f\u3055\u305b\u305fC<sub>2<\/sub>\u306f\u300c\u30b8\u30ab\u30eb\u30d9\u30f3\uff08\u4e8c\u91cd\u7d50\u5408\uff09\u300d\u3084\u300c\u4e09\u91cd\u9805\u30d3\u30e9\u30b8\u30ab\u30eb\uff08\u4e09\u91cd\u7d50\u5408\uff09\u300d\u306e\u6027\u8cea\u306f\u307e\u3063\u305f\u304f\u793a\u3055\u306a\u304b\u3063\u305f\u306e\u3067\u3059\u3002<\/p>\n<p>C<sub>2<\/sub>\u304c\uff08\u7406\u8ad6\u4e88\u6e2c\u3069\u304a\u308a\u306b\uff09\u96fb\u8377\u30b7\u30d5\u30c8\u7d50\u5408\u3092\u6709\u3057\u3066\u3044\u308b\u3068\u3059\u308b\u3068\u3001\u30e9\u30b8\u30ab\u30eb\u3068\u3057\u3066\u306f\u6bd4\u8f03\u7684\u5b89\u5b9a\u306a\u4e00\u91cd\u9805\u30d3\u30e9\u30b8\u30ab\u30eb\u306b\u8fd1\u3044\u6027\u8cea\u3092\u793a\u3059\u306f\u305a\u3067\u3059\u3002\u305d\u3053\u3067\u3001\u5b89\u5b9a\u30e9\u30b8\u30ab\u30eb\u3067\u3082\u53cd\u5fdc\u53ef\u80fd\u306a 9,10-\u30b8\u30d2\u30c9\u30ed\u30a2\u30f3\u30c8\u30e9\u30bb\u30f3 (<strong>2<\/strong>) \u3084\u30ac\u30eb\u30d3\u30ce\u30ad\u30b7\u30eb\u30e9\u30b8\u30ab\u30eb (<strong>4<\/strong>) \u3092\u7cfb\u4e2d\u306b\u52a0\u3048\u3066\u307f\u305f\u3068\u3053\u308d\u3001\u671f\u5f85\u3069\u304a\u308a\u30a2\u30f3\u30c8\u30e9\u30bb\u30f3 (<strong>3<\/strong>) \u3068\u30a2\u30bb\u30c1\u30ec\u30f3\uff08HCCH\uff09\u3001\u30a8\u30c1\u30cb\u30eb\u30a8\u30fc\u30c6\u30eb (<strong>5<\/strong>) \u3092\u305d\u308c\u305e\u308c\u751f\u6210\u7269\u3068\u3057\u3066\u4e0e\u3048\u307e\u3057\u305f\u3002<\/p>\n<figure id=\"attachment_13467\" aria-describedby=\"caption-attachment-13467\" style=\"width: 600px\" class=\"wp-caption aligncenter\"><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2020\/06\/002-1r.jpg\" alt=\"\" width=\"600\" height=\"349\" class=\"size-full wp-image-13467\" srcset=\"https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2020\/06\/002-1r.jpg 600w, https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2020\/06\/002-1r-300x175.jpg 300w\" sizes=\"auto, (max-width: 600px) 100vw, 600px\" \/><figcaption id=\"caption-attachment-13467\" class=\"wp-caption-text\">(a) \u5e38\u6e29\u5e38\u5727\u306b\u304a\u3051\u308bC<sub>2<\/sub>\u306e\u5316\u5b66\u5408\u6210 (b) \u5b89\u5b9a\u30e9\u30b8\u30ab\u30eb\u306b\u3088\u308bC<sub>2<\/sub>\u306e\u88dc\u8db3\u5b9f\u9a13<\/figcaption><\/figure>\n<p>\u6b21\u306b\u3001\u30c7\u30b6\u30a4\u30f3\u3057\u305f\u9023\u7d50\u30d5\u30e9\u30b9\u30b3\u3092\u7528\u3044\u3066\u3001\u30d5\u30e9\u30b9\u30b3A\u306b\u3066\u767a\u751f\u3055\u305b\u305fC<sub>2<\/sub>\u3092\u3001\u30d5\u30e9\u30b9\u30b3B\u306b\u3066\u7121\u6eb6\u5a92\u6761\u4ef6\u4e0b\u3067\u30ac\u30eb\u30d3\u30ce\u30ad\u30b7\u30eb\u30e9\u30b8\u30ab\u30eb (<strong>4<\/strong>) \u3068\u53cd\u5fdc\u3055\u305b\u305f\u3068\u3053\u308d\u3001\u4e3b\u751f\u6210\u7269\u306e\u30a8\u30c1\u30cb\u30eb\u30a8\u30fc\u30c6\u30eb (<strong>5<\/strong>) \u306b\u52a0\u3048\u3066\u3001C<sub>2<\/sub>\u306e\u4e21\u7aef\u306b\u30ac\u30eb\u30d3\u30ce\u30ad\u30b7\u30eb\u30e9\u30b8\u30ab\u30eb (<strong>4<\/strong>) \u304c\u4ed8\u52a0\u3057\u305f (<strong>6<\/strong>) \u3082\u5f97\u3089\u308c\u307e\u3057\u305f\u3002<\/p>\n<figure id=\"attachment_13434\" aria-describedby=\"caption-attachment-13434\" style=\"width: 600px\" class=\"wp-caption aligncenter\"><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-13434\" src=\"https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2020\/06\/002-1-3.jpg\" alt=\"\" width=\"600\" height=\"230\" srcset=\"https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2020\/06\/002-1-3.jpg 600w, https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2020\/06\/002-1-3-300x115.jpg 300w\" sizes=\"auto, (max-width: 600px) 100vw, 600px\" \/><figcaption id=\"caption-attachment-13434\" class=\"wp-caption-text\">\u9023\u7d50\u30d5\u30e9\u30b9\u30b3\u306b\u3088\u308b\u5b9f\u9a13<\/figcaption><\/figure>\n<p>\u3055\u3089\u306b\u3001<sup>13<\/sup>C\u3067\u7247\u5074\u306e\u70ad\u7d20\u3092\u6a19\u8b58\u3057\u305f\u5206\u5b50\uff08<strong>1b<\/strong>&#8211;<sup>13<\/sup><em>C<sub>\u03b2<\/sub><\/em>\uff09\u3092\u8a2d\u8a08\u30fb\u5408\u6210\u3057\u3001\u30ac\u30eb\u30d3\u30ce\u30ad\u30b7\u30eb\u30e9\u30b8\u30ab\u30eb (<strong>4<\/strong>) \u3068\u306e\u53cd\u5fdc\u306b\u7528\u3044\u305f\u3068\u3053\u308d\u3001\u6eb6\u5a92\u306e\u6709\u7121\u3084\u7c98\u6027\u306b\u3088\u3063\u3066\u9078\u629e\u6027\u306f\u5909\u5316\u3059\u308b\u3082\u306e\u306e\u3001C<sub>2<\/sub>\u306e\u4e21\u5074\u304b\u3089\u53cd\u5fdc\u3057\u305f\u3068\u8003\u3048\u3089\u308c\u308b\u6df7\u5408\u7269 (<strong>5<\/strong>&#8211;<sup>13<\/sup><em>C<sub>\u03b1<\/sub><\/em>\/ <strong>5<\/strong>&#8211;<sup>13<\/sup><em>C<sub>\u03b2<\/sub><\/em>) \u304c\u5f97\u3089\u308c\u307e\u3057\u305f\u3002<\/p>\n<figure id=\"attachment_13435\" aria-describedby=\"caption-attachment-13435\" style=\"width: 600px\" class=\"wp-caption aligncenter\"><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-13435\" src=\"https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2020\/06\/002-1-4.jpg\" alt=\"\" width=\"600\" height=\"190\" srcset=\"https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2020\/06\/002-1-4.jpg 600w, https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2020\/06\/002-1-4-300x95.jpg 300w\" sizes=\"auto, (max-width: 600px) 100vw, 600px\" \/><figcaption id=\"caption-attachment-13435\" class=\"wp-caption-text\"><sup>13<\/sup>C\u6a19\u8b58\u5b9f\u9a13<\/figcaption><\/figure>\n<p>\u3053\u308c\u3089\u306e\u7d50\u679c\u3092\u6574\u7406\u3059\u308b\u3068\u3001\u5e38\u6e29\u5e38\u5727\u4e0b\u3001\u5316\u5b66\u5408\u6210\u3057\u305fC<sub>2<\/sub>\u306f\u300c\u6bd4\u8f03\u7684\u5b89\u5b9a\u306a\u6c17\u4f53\u5206\u5b50\u3068\u3057\u3066\u632f\u308b\u821e\u3046\u3053\u3068\u300d\u300c\u96fb\u8377\u30b7\u30d5\u30c8\u7d50\u5408\uff08\u4e00\u91cd\u9805\u30d3\u30e9\u30b8\u30ab\u30eb\uff09\u3092\u542b\u30804\u3064\u306e\u7d50\u5408\u3092\u6709\u3059\u308b\u3053\u3068\u300d\u306a\u3069\u3001\u7406\u8ad6\u5316\u5b66\u8005\u306e\u4e88\u6e2c\u3092\u5f37\u304f\u652f\u6301\u3059\u308b\u3082\u306e\u3067\u3057\u305f\u3002\u3053\u3046\u3057\u3066\u3001\u5b9f\u9a13\u5316\u5b66\u8005\u3068\u306e\u9577\u5e74\u306e\u8ad6\u4e89\u306b\u6c7a\u7740\u3092\u3064\u3051\u308b\u3053\u3068\u304c\u3067\u304d\u307e\u3057\u305f\u3002<\/p>\n<h3>\u591a\u69d8\u306a\u30ca\u30ce\u69cb\u9020\u3092\u751f\u307f\u51fa\u3059\u300c\u70ad\u7d20\u300d\u306e\u4e0d\u601d\u8b70<\/h3>\n<p>4\u3064\u306e\u4fa1\u96fb\u5b50\u3092\u6301\u3064\u300c\u70ad\u7d20\u300d\u306f\u3001<em>sp<sup>3<\/sup><\/em>\u3001<em>sp<sup>2<\/sup><\/em>\u3001<em>sp<\/em>\u3068\u3044\u30463\u7a2e\u306e\u6df7\u6210\u8ecc\u9053\u3092\u3068\u308a\u3001\u5358\u7d50\u5408\u3001\u4e8c\u91cd\u7d50\u5408\u3001\u4e09\u91cd\u7d50\u5408\u306e\u7d44\u307f\u5408\u308f\u305b\u306b\u3088\u3063\u3066\u7570\u306a\u308b\u5f62\u30fb\u6027\u8cea\u3092\u6301\u3064\u69cb\u9020\u4f53\uff08\u70ad\u7d20\u540c\u7d20\u4f53\uff09\u3092\u3064\u304f\u308a\u307e\u3059\u3002<em>sp<sup>3<\/sup><\/em>\u70ad\u7d20\u304b\u3089\u306a\u308b\u69cb\u9020\u4f53\u306e\u4ee3\u8868\u683c\u3068\u3057\u3066\u77e5\u3089\u308c\u308b\u306e\u304c\u30c0\u30a4\u30e4\u30e2\u30f3\u30c9\u3067\u3042\u308a\u3001\u6b63\u56db\u9762\u4f53\u578b\u306e3\u6b21\u5143\u30cd\u30c3\u30c8\u30ef\u30fc\u30af\u69cb\u9020\u3092\u6301\u3061\u307e\u3059\u30024\u3064\u306e\u7b49\u4fa1\u306a<em>sp<sup>3<\/sup><\/em>\u8ecc\u9053\u304c3\u6b21\u5143\u7684\u306b\u62e1\u304c\u308a\u5358\u7d50\u5408\u3067\u5f37\u304f\u7d50\u3073\u3064\u3044\u3066\u3044\u308b\u305f\u3081\u3001\u786c\u304f\u3001\u71b1\u4f1d\u5c0e\u6027\u304c\u9ad8\u304f\u306a\u3063\u3066\u3044\u307e\u3059\u3002<em>sp<\/em>\u70ad\u7d20\u304b\u3089\u306a\u308b\u30ab\u30eb\u30d3\u30f3\u306f\u3001\u4e09\u91cd\u7d50\u5408\u3068\u5358\u7d50\u5408\u306e\u7e70\u308a\u8fd4\u3057\u306b\u3088\u308b\u300c\u30dd\u30ea\u30a4\u30f3\u69cb\u9020\u300d\u3068\u4e8c\u91cd\u7d50\u5408\u304c\u9023\u7d50\u3059\u308b\u300c\u30af\u30e0\u30ec\u30f3\u69cb\u9020\u300d\u304b\u3089\u306a\u308a\u3001\u6975\u3081\u3066\u4e0d\u5b89\u5b9a\u3067\u8a73\u3057\u3044\u6027\u8cea\u306f\u308f\u304b\u3063\u3066\u3044\u307e\u305b\u3093\u3002<\/p>\n<p>\u30b0\u30e9\u30d5\u30a7\u30f3\u3001\u30d5\u30e9\u30fc\u30ec\u30f3\uff08C<sub>60<\/sub>\uff09\u3001\u30ab\u30fc\u30dc\u30f3\u30ca\u30ce\u30c1\u30e5\u30fc\u30d6\uff08CNT\uff09\u306f20\u4e16\u7d00\u306b\u306a\u3063\u3066\u767a\u898b\u3055\u308c\u305f<em>sp<sup>2<\/sup><\/em>\u70ad\u7d20\u306b\u3088\u3063\u3066\u69cb\u6210\u3055\u308c\u308b\u70ad\u7d20\u540c\u7d20\u4f53\u3067\u3059\u3002\u3053\u308c\u3089\u306f\u300c\u30ca\u30ce\u30ab\u30fc\u30dc\u30f3\u300d\u3068\u547c\u3070\u308c\u3001\u8c4a\u5bcc\u306a\u03c0\u96fb\u5b50\u3092\u6d3b\u7528\u3057\u305f\u6b21\u4e16\u4ee3\u6750\u6599\u3068\u3057\u3066\u6ce8\u76ee\u3092\u96c6\u3081\u3066\u3044\u307e\u3059\u3002\u30b0\u30e9\u30d5\u30a7\u30f3\u306f\u3001\u5404\u70ad\u7d20\u304c6\u54e1\u74b0\u5e73\u9762\u30b7\u30fc\u30c8\u69cb\u9020\u3092\u3068\u308a\u3001\u03c0\u96fb\u5b50\u304c\u975e\u5c40\u5728\u5316\u3055\u308c\u6975\u3081\u3066\u5b89\u5b9a\u3067\u3059\u3002C<sub>60<\/sub>\u3084CNT\u3067\u306f\u30016\u54e1\u74b0\u69cb\u9020\u306b\u52a0\u3048\u3066\u90e8\u5206\u7684\u306b5\u54e1\u74b0\u304c\u542b\u307e\u308c\u3001\u201c\u6e7e\u66f2\u3057\u305f\u201d\u69cb\u9020\u3092\u3064\u304f\u3063\u3066\u3044\u307e\u3059\u3002\u540c\u3058<em>sp<sup>2<\/sup><\/em>\u70ad\u7d20\u304b\u3089\u306a\u305c\u3001\u3053\u306e\u3088\u3046\u306a\u591a\u69d8\u306a\u69cb\u9020\u4f53\u304c\u751f\u3058\u308b\u306e\u3067\u3057\u3087\u3046\u304b\uff1f<\/p>\n<p>C<sub>60<\/sub>\u3084CNT\u3092\u5de5\u696d\u7684\u306b\u5408\u6210\u3059\u308b\u624b\u6cd5\u3084\u30ca\u30ce\u30ab\u30fc\u30dc\u30f3\u306e\u90e8\u5206\u69cb\u9020\u3092\u4eba\u5de5\u7684\u306b\u5408\u6210\u3059\u308b\u7814\u7a76\u306f\u76db\u3093\u306b\u884c\u308f\u308c\u3066\u3044\u308b\u3082\u306e\u306e\u3001\u81ea\u7136\u754c\u306b\u304a\u3044\u3066\u3053\u308c\u3089\u304c\u3069\u306e\u3088\u3046\u306b\u5408\u6210\u3055\u308c\u305f\u306e\u304b\u306b\u3064\u3044\u3066\u306f\u3001\u672a\u3060\u591a\u304f\u304c\u8b0e\u306b\u5305\u307e\u308c\u3066\u3044\u307e\u3059\u3002C<sub>60<\/sub>\u306e\u751f\u6210\u6a5f\u69cb\u306b\u3064\u3044\u3066\u306f\u7406\u8ad6\u3068\u5b9f\u9a13\u306b\u3088\u308b\u9577\u5e74\u306e\u7814\u7a76\u306b\u3088\u3063\u3066\u3001\u3055\u307e\u3056\u307e\u306a\u6a5f\u69cb\u304c\u63d0\u5531\u3055\u308c\u3066\u3044\u307e\u3059\u304c\u3001\u3044\u305a\u308c\u3082\u3001\u521d\u671f\u306b\u306f\u201c\u70ad\u7d20\u304c\u3044\u304f\u3064\u304b\u9023\u306a\u3063\u305f\u3082\u306e\u201d\u304c\u7d50\u5408\u30fb\u5909\u5f62\u30fb\u8131\u96e2\u3092\u7e70\u308a\u8fd4\u3057\u3066C<sub>60<\/sub>\u304c\u3067\u304d\u3042\u304c\u308b\u3068\u3044\u3046\u3082\u306e\u3067\u3059\u3002\u5b9f\u969b\u3001\u30a2\u30fc\u30af\u653e\u96fb\u3084\u70ad\u7d20\u84b8\u6c17\u306b\u306f\u3001C<sub>1<\/sub>\uff0dC<sub>4<\/sub>\uff08\u52b1\u8d77\u72b6\u614b\u306e\u3082\u306e\u3092\u542b\u3080\uff09\u304c\u5b58\u5728\u3059\u308b\u3053\u3068\u304c\u78ba\u8a8d\u3055\u308c\u3066\u3044\u307e\u3059\u304c\u3001\u70ad\u7d20\u540c\u7d20\u4f53\u306e\u767a\u751f\u6a5f\u69cb\u3084\u69cb\u9020\u591a\u5f62\u306e\u8d77\u6e90\u306b\u95a2\u3057\u3066\u306f\u672a\u3060\u6c7a\u5b9a\u7684\u306a\u3082\u306e\u306f\u5b58\u5728\u3057\u307e\u305b\u3093\u3002<\/p>\n<h3>C<sub>2<\/sub>\u306f\u30ca\u30ce\u30ab\u30fc\u30dc\u30f3\u306e\u8d77\u6e90\u5206\u5b50\uff1f<\/h3>\n<p>\u79c1\u305f\u3061\u306f\u3001C<sub>2<\/sub>\u304c\u30ca\u30ce\u30ab\u30fc\u30dc\u30f3\u306e\u8d77\u6e90\u5206\u5b50\u306a\u306e\u3067\u306f\u306a\u3044\u304b\u3068\u8003\u3048\u307e\u3057\u305f\u3002\u3057\u304b\u3057\u3001C<sub>2<\/sub>\u306f\u96fb\u8377\u30b7\u30d5\u30c8\u7d50\u5408\u306e\u30d3\u30e9\u30b8\u30ab\u30eb\u6027\u306b\u3088\u308a\u3001\u7a7a\u6c17\u4e2d\u306e\u9178\u7d20\u3084\u6eb6\u5a92\u5206\u5b50\u306a\u3069\u3067\u3059\u3050\u306b\u6355\u6349\u30fb\u4e0d\u6d3b\u5316\u3055\u308c\u3066\u3057\u307e\u3044\u307e\u3059\u3002\u305d\u3053\u3067\u3001\u4e0d\u6d3b\u6027\u30ac\u30b9\uff08\u30a2\u30eb\u30b4\u30f3\uff09\u96f0\u56f2\u6c17\u4e0b\u306b\u7121\u6eb6\u5a92\u306b\u3066C<sub>2<\/sub>\u306e\u767a\u751f\u3092\u8a66\u307f\u305f\u3068\u3053\u308d\uff08\u4e73\u9262\u3068\u4e73\u68d2\u3067\u304b\u304d\u6df7\u305c\u308b\u3060\u3051\uff01\uff09\u3001\u7159\u3092\u4e0a\u3052\u3066\u9ed2\u8272\u56fa\u4f53\u304c\u751f\u3058\u308b\u3053\u3068\u3092\u898b\u51fa\u3057\u307e\u3057\u305f\u3002\u305d\u3057\u3066\u3001\u305d\u306e\u9ed2\u8272\u56fa\u4f53\u306e\u30c8\u30eb\u30a8\u30f3\u62bd\u51fa\u6db2\u304b\u3089\u306f\u3001C<sub>60<\/sub>\u306b\u5bfe\u5fdc\u3059\u308b\u5206\u5b50\u30a4\u30aa\u30f3\u30d4\u30fc\u30af\uff08<em>m\/z<\/em> = 720\uff09\u304cMALDI-MS\u306b\u3088\u3063\u3066\u89b3\u6e2c\u3055\u308c\u307e\u3057\u305f\u3002\u3053\u306e\u3068\u304d\u3001C<sub>70<\/sub>\u4ee5\u4e0a\u306e\u9ad8\u6b21\u30d5\u30e9\u30fc\u30ec\u30f3\u306f\u691c\u51fa\u3055\u308c\u307e\u305b\u3093\u3067\u3057\u305f\u3002<\/p>\n<p>\u3068\u3053\u308d\u3067\u3001\u5e38\u6e29\u30fb\u5e38\u5727\u4e0b\u3001\u4e73\u9262\u3067\u5316\u5b66\u5408\u6210\u3057\u305f\u30ca\u30ce\u30ab\u30fc\u30dc\u30f3\u306f\u3001\u305d\u306e\u307b\u3068\u3093\u3069\u304c\u30c8\u30eb\u30a8\u30f3\u306b\u4e0d\u6eb6\u306e\u9ed2\u8272\u56fa\u4f53\u3067\u3057\u305f\u3002\u305d\u3053\u3067\u3001\u9178\u5316\u51e6\u7406\u306b\u3088\u308a\u30a2\u30e2\u30eb\u30d5\u30a1\u30b9\u70ad\u7d20\u90e8\u5206\u3092\u9664\u53bb\u3057\u305f\u8a66\u6599\u3092\u30e9\u30de\u30f3\u30b9\u30da\u30af\u30c8\u30eb\u3084\u9ad8\u5206\u89e3\u80fd\u900f\u904e\u578b\u96fb\u5b50\u9855\u5fae\u93e1\uff08HRTEM\uff09\u3092\u7528\u3044\u3066\u7cbe\u67fb\u3057\u305f\u3068\u3053\u308d\u3001\u30b0\u30e9\u30d5\u30a1\u30a4\u30c8\u3084CNT\u3001\u30ab\u30fc\u30dc\u30f3\u30ca\u30ce\u30db\u30fc\u30f3\u304c\u89b3\u6e2c\u3055\u308c\u307e\u3057\u305f\u3002<\/p>\n<p>\u30b0\u30e9\u30d5\u30a1\u30a4\u30c8\u306b\u7279\u5fb4\u7684\u306a\u30d4\u30fc\u30af\u304c\u89b3\u6e2c\u3055\u308c\u305f\u30e9\u30de\u30f3\u30b9\u30da\u30af\u30c8\u30eb\u3092\u4e0b\u56f3a\u306b\u793a\u3057\u307e\u3057\u305f\u3002\u3053\u306e\u8a66\u6599\u306b\u3064\u3044\u3066\u3001HRTEM\u6e2c\u5b9a\u3092\u884c\u3063\u305f\u3082\u306e\u304c\u4e0b\u56f3b\u3001c\u3067\u3059\u3002(100)\u9762\u306b\u5bfe\u5fdc\u3059\u308bTEM\u753b\u50cf\u306e\u30d1\u30ef\u30fc\u30b9\u30da\u30af\u30c8\u30eb\u304b\u3089\u306f\u30d9\u30f3\u30bc\u30f3\u74b0\u306e\u516d\u89d2\u5f62\u306b\u5bfe\u5fdc\u3059\u308b 0.20 nm\u306e\u96fb\u5b50\u7dda\u56de\u6298\u304c\u5f97\u3089\u308c\u3066\u304a\u308a\u3001(002)\u9762\u306e\u30d1\u30ef\u30fc\u30b9\u30da\u30af\u30c8\u30eb\u304b\u3089\u306f0.33 nm\u306e\u7a4d\u5c64\u5e45\u3067\u30b0\u30e9\u30d5\u30a1\u30a4\u30c8\u5c64\u304c\u304d\u308c\u3044\u306b\u4e26\u3093\u3067\u3044\u308b\u3053\u3068\u304c\u89b3\u6e2c\u3067\u304d\u307e\u3057\u305f\u3002\u305d\u3057\u3066\u3001\u4eca\u56de\u5e38\u6e29\u5e38\u5727\u306b\u3066\u767a\u751f\u3055\u305b\u305fC<sub>2<\/sub>\u304b\u3089\u306f\u3001\u6b20\u9665\u69cb\u9020\u306e\u5c11\u306a\u3044\u30b0\u30e9\u30d5\u30a7\u30f3\u30b7\u30fc\u30c8\u304c\u5bc6\u306b\u8a70\u307e\u3063\u305f\u30b0\u30e9\u30d5\u30a1\u30a4\u30c8\u304c\u751f\u6210\u3057\u3066\u3044\u308b\u3053\u3068\u304c\u660e\u3089\u304b\u3068\u306a\u308a\u307e\u3057\u305f\u3002\u4e0b\u56f3d\u306b\u306f\u3001\u76f4\u5f84\u304c1.8 nm\u306a\u3069\u306e\u30ab\u30fc\u30dc\u30f3\u30ca\u30ce\u30c1\u30e5\u30fc\u30d6\u304c\u78ba\u8a8d\u3067\u304d\u307e\u3059\u3002<\/p>\n<figure id=\"attachment_13395\" aria-describedby=\"caption-attachment-13395\" style=\"width: 600px\" class=\"wp-caption aligncenter\"><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-13395\" src=\"https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2020\/06\/003.jpg\" alt=\"\" width=\"600\" height=\"389\" srcset=\"https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2020\/06\/003.jpg 600w, https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2020\/06\/003-300x195.jpg 300w\" sizes=\"auto, (max-width: 600px) 100vw, 600px\" \/><figcaption id=\"caption-attachment-13395\" class=\"wp-caption-text\">\u30b0\u30e9\u30d5\u30a1\u30a4\u30c8\u304c\u542b\u307e\u308c\u308b\u8a66\u6599\u306e (a) \u30e9\u30de\u30f3\u30b9\u30da\u30af\u30c8\u30eb (b) (002) \u9762\u306eHRTEM\u753b\u50cf <br \/>(c) (100) \u9762\u306eHRTEM\u753b\u50cf (d) \u30ab\u30fc\u30dc\u30f3\u30ca\u30ce\u30c1\u30e5\u30fc\u30d6\u304c\u542b\u307e\u308c\u308bHRTEM\u753b\u50cf<\/figcaption><\/figure>\n<p>\u4eca\u56de\u306e\u767a\u751f\u6761\u4ef6\u3067\u306f\u3001\u30b0\u30e9\u30d5\u30a1\u30a4\u30c8\u304c\u5727\u5012\u7684\u306b\u591a\u304f\u3001C<sub>60<\/sub>\u3084CNT\u306f\u6975\u3081\u3066\u5c11\u306a\u3044\u3053\u3068\u304c\u660e\u3089\u304b\u3068\u306a\u308a\u307e\u3057\u305f\u3002\u3053\u308c\u306f\u81ea\u7136\u754c\u306b\u304a\u3051\u308b<em>sp<sup>2<\/sup><\/em>\u70ad\u7d20\u540c\u7d20\u4f53\u306e\u5b58\u5728\u6bd4\u7387\u3068\u3082\u4e00\u81f4\u3057\u3066\u304a\u308a\u3001\u6700\u3082\u5b89\u5b9a\u306a\u30d2\u30e5\u30c3\u30b1\u30eb\u82b3\u9999\u65cf\u3067\u6e80\u305f\u3055\u308c\u305f\u30b0\u30e9\u30d5\u30a7\u30f3\u30b7\u30fc\u30c8\u304c\u65ad\u7136\u591a\u304f\u751f\u6210\u3059\u308b\u306e\u304b\u3082\u3057\u308c\u307e\u305b\u3093\u3002\u57fa\u5e95\u72b6\u614b\u306eC<sub>2<\/sub>\u306f\u6bd4\u8f03\u7684\u5b89\u5b9a\u3067\u3042\u308a\u3001\u53cd\u5fdc\u6761\u4ef6\u3082\u7a4f\u3084\u304b\u3067\u3042\u308c\u3070\u3001\u5b89\u5b9a\u306a\u30d2\u30e5\u30c3\u30b1\u30eb\u82b3\u9999\u65cf\u3067\u6e80\u305f\u3055\u308c\u305f\u30b0\u30e9\u30d5\u30a7\u30f3\uff08\u30b0\u30e9\u30d5\u30a1\u30a4\u30c8\uff09\u304c\u9078\u629e\u751f\u6210\u3059\u308b\u306e\u306b\u3082\u3046\u306a\u3065\u3051\u307e\u3059\u3002\u305d\u3057\u3066\u3088\u308a\u91cd\u8981\u306a\u3053\u3068\u306f\u3001C<sub>2<\/sub>\u304b\u3089\u5e38\u6e29\u5e38\u5727\u4e0b\u3001\u3055\u307e\u3056\u307e\u306a\u70ad\u7d20\u540c\u7d20\u4f53\u304c\u81ea\u7136\u5f62\u6210\u3055\u308c\u305f\u4e8b\u5b9f\u3067\u3059\u3002\u3053\u306e\u5b9f\u9a13\u306f\u3001C<sub>2<\/sub>\u304c\u30ca\u30ce\u30ab\u30fc\u30dc\u30f3\u306e\u8d77\u6e90\u5206\u5b50\u306b\u306a\u308a\u5f97\u308b\u3053\u3068\u3092\u521d\u3081\u3066\u5b9f\u8a3c\u3057\u305f\u7d50\u679c\u3067\u3059\u3002<\/p>\n<figure id=\"attachment_13396\" aria-describedby=\"caption-attachment-13396\" style=\"width: 600px\" class=\"wp-caption aligncenter\"><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-13396\" src=\"https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2020\/06\/004.jpg\" alt=\"\" width=\"600\" height=\"443\" srcset=\"https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2020\/06\/004.jpg 600w, https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2020\/06\/004-300x222.jpg 300w\" sizes=\"auto, (max-width: 600px) 100vw, 600px\" \/><figcaption id=\"caption-attachment-13396\" class=\"wp-caption-text\">C<sub>2<\/sub>\u304b\u3089\u30ca\u30ce\u30ab\u30fc\u30dc\u30f3\u3078<\/figcaption><\/figure>\n<h3>\u4eca\u5f8c\u306e\u5c55\u671b<\/h3>\n<p>\u4eca\u56de\u3001\u79c1\u305f\u3061\u304c\u958b\u767a\u3057\u305fC<sub>2<\/sub>\u306e\u5e38\u6e29\u5e38\u5727\u306b\u304a\u3051\u308b\u5316\u5b66\u5408\u6210\u6cd5\u306f\u3001C<sub>2<\/sub>\u306e\u5316\u5b66\u7d50\u5408\u8ad6\u306b\u4e00\u5b9a\u306e\u6c7a\u7740\u3092\u3064\u3051\u3001\u70ad\u7d20\u6750\u6599\u79d1\u5b66\u306e\u65b0\u3057\u3044\u57fa\u790e\u79d1\u5b66\u304a\u3088\u3073\u5fdc\u7528\u79d1\u5b66\u3092\u5c55\u958b\u3059\u308b\u305f\u3081\u306e\u3001\u5f37\u529b\u306a\u65b9\u6cd5\u306b\u306a\u308b\u3053\u3068\u304c\u671f\u5f85\u3055\u308c\u307e\u3059\u3002\u5f97\u3089\u308c\u305f\u30ca\u30ce\u30ab\u30fc\u30dc\u30f3\u306f\u3001\u305d\u306e\u69cb\u9020\u3084\u5f62\u614b\u304c\u3044\u305a\u308c\u3082\u7279\u5fb4\u3042\u308b\u3082\u306e\u3070\u304b\u308a\u3067\u3001\u62b5\u6297\u52a0\u71b1\u6cd5\u3084\u30a2\u30fc\u30af\u653e\u96fb\u6cd5\u3001\u30ec\u30fc\u30b6\u30fc\u5149\u7167\u5c04\u306a\u3069\u306e\u9ad8\u30a8\u30cd\u30eb\u30ae\u30fc\u3092\u7528\u3044\u308b\u5f93\u6765\u6cd5\u3068\u6bd4\u3079\u3066\u5927\u304d\u304f\u7570\u306a\u3063\u3066\u3044\u307e\u3059\u3002\u672c\u6cd5\u306b\u3088\u308a\u5b9f\u73fe\u3057\u305f\u4f4e\u6e29C<sub>2<\/sub>\u767a\u751f\u6cd5\u306f\u3001C<sub>2<\/sub>\u304b\u3089\u70ad\u7d20\u540c\u7d20\u4f53\u3078\u306e\u6210\u9577\u30e1\u30ab\u30cb\u30ba\u30e0\u306e\u89e3\u660e\u3092\u542b\u3080\u3001\u30ca\u30ce\u70ad\u7d20\u6750\u6599\u306e\u201c\u5316\u5b66\u5408\u6210\u201d\u306b\u5411\u3051\u305f\u9769\u65b0\u7684\u306a\u4e00\u6b69\u306b\u306a\u308b\u3068\u671f\u5f85\u3055\u308c\u307e\u3059\u3002<\/p>\n<p><strong>\u53c2\u8003\u6587\u732e<\/strong><\/p>\n<ul>\n<li>Shaik, S.; Danovich, D.; Wu, W.; Su, P.; Rzepa H. S.; Hiberty P. C.; <em>Nature Chem.<\/em>, <strong>2012<\/strong>, <em>4<\/em>, 195.<\/li>\n<li>Skell, P. S.; Harris, R. F. <em>J. Am. Chem. Soc.<\/em>, <strong>1966<\/strong>, <em>88<\/em>, 5933.<\/li>\n<li>Miyamoto, K.; Narita, S.; Masumoto, Y.; Hashishin, T.; Kimura, M.; Ochiai, M.; Uchiyama, M. <em>Nature Commun<\/em>., <strong>2020<\/strong>, <em>11<\/em>, 2134.<\/li>\n<li>\u7814\u7a76\u80cc\u666f\u306a\u3069\u306e\u8a73\u7d30\u306b\u3064\u3044\u3066\u306f\u6b21\u3092\u53c2\u7167\uff1a\u5bae\u672c \u548c\u7bc4\u3001\u5185\u5c71 \u771f\u4f38\u300e\u73fe\u4ee3\u5316\u5b66\u300f\uff082020\u5e74\u30018\u6708\u53f7\uff09<\/li>\n<\/ul>\n","protected":false},"excerpt":{"rendered":"<p>C2\u3068\u3044\u3046\u8b0e\u306e\u5206\u5b50 \u4e8c\u539f\u5b50\u70ad\u7d20\uff08C2\uff09\u306f\u70ad\u7d202\u3064\u304b\u3089\u69cb\u6210\u3055\u308c\u308b\u3001\u5730\u7403\u4e0a\u306b\u304a\u3044\u3066\u6700\u3082\u5358\u7d14\u306a\u70ad\u7d20\u5206\u5b50\u3067\u3059\u3002\u53e4\u304f\u304b\u3089\u3001\u308d\u3046\u305d\u304f\u306e\u9752\u3044\u708e\u3084\u5b87\u5b99\u7a7a\u9593\u306b\u5b58\u5728\u3059\u308b\u3053\u3068\u304c\u77e5\u3089\u308c\u3066\u304d\u307e\u3057\u305f\u304c\u3001\u767a\u898b\u304b\u30891\u4e16\u7d00\u304c\u904e\u304e\u305f\u73fe\u5728 [&hellip;]<\/p>\n","protected":false},"author":487,"featured_media":13396,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_acf_changed":false,"_monsterinsights_skip_tracking":false,"_monsterinsights_sitenote_active":false,"_monsterinsights_sitenote_note":"","_monsterinsights_sitenote_category":0,"footnotes":""},"categories":[3],"tags":[20],"class_list":["post-13392","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-outcome","tag-20","has_thumb"],"acf":[],"aioseo_notices":[],"_links":{"self":[{"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=\/wp\/v2\/posts\/13392","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=\/wp\/v2\/users\/487"}],"replies":[{"embeddable":true,"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=13392"}],"version-history":[{"count":25,"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=\/wp\/v2\/posts\/13392\/revisions"}],"predecessor-version":[{"id":13696,"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=\/wp\/v2\/posts\/13392\/revisions\/13696"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=\/wp\/v2\/media\/13396"}],"wp:attachment":[{"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=13392"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=13392"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=13392"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}