{"id":12546,"date":"2020-02-03T08:00:39","date_gmt":"2020-02-02T23:00:39","guid":{"rendered":"https:\/\/academist-cf.com\/journal\/?p=12546"},"modified":"2020-04-08T10:58:14","modified_gmt":"2020-04-08T01:58:14","slug":"%e5%85%89%e8%a7%a6%e5%aa%92%e3%81%a8%e3%81%97%e3%81%a6%e6%a9%9f%e8%83%bd%e3%81%99%e3%82%8b%e5%a4%9a%e5%ad%94%e6%80%a7%e6%9d%90%e6%96%99%e3%81%a8%e3%81%af%ef%bc%9f-%e5%8d%8a%e5%b0%8e%e4%bd%93","status":"publish","type":"post","link":"https:\/\/academist-cf.com\/journal\/?p=12546","title":{"rendered":"\u5149\u89e6\u5a92\u3068\u3057\u3066\u6a5f\u80fd\u3059\u308b\u591a\u5b54\u6027\u6750\u6599\u3068\u306f\uff1f – \u534a\u5c0e\u4f53\u7279\u6027\u3092\u3082\u3064\u300c\u30b9\u30eb\u30d5\u30a3\u30c9MOF\u300d\u306e\u65b0\u305f\u306a\u53ef\u80fd\u6027"},"content":{"rendered":"

\u65b0\u3057\u3044\u591a\u5b54\u6027\u6750\u6599\u300cMOF\u300d\u3068\u306f\uff1f<\/h3>\n

\u6211\u3005\u306e\u751f\u6d3b\u306b\u306f\u3001\u5206\u5b50\u30b5\u30a4\u30ba\u306e\u5c0f\u3055\u306a\u7a74\u304c\u7121\u6570\u306b\u7a7a\u3044\u305f\u69cb\u9020\u3067\u3042\u308b\u591a\u5b54\u6027\u6750\u6599\u304c\u3042\u3075\u308c\u3066\u3044\u307e\u3059\u3002\u305f\u3068\u3048\u3070\u3001\u4e7e\u71e5\u6750\u306b\u4f7f\u7528\u3055\u308c\u3066\u3044\u308b\u30b7\u30ea\u30ab\u30b2\u30eb\u3084\u6d88\u81ed\u5264\u3068\u3057\u3066\u4f7f\u7528\u3055\u308c\u3066\u3044\u308b\u6d3b\u6027\u70ad\u306a\u3069\u304c\u305d\u308c\u3089\u306e\u4ef2\u9593\u3067\u3059\u3002\u3053\u306e\u3088\u3046\u306b\u3001\u591a\u5b54\u6027\u6750\u6599\u3068\u3044\u3046\u306e\u306f\u3001\u65e5\u5e38\u3067\u3082\u5229\u7528\u3055\u308c\u3066\u3044\u308b\u8eab\u8fd1\u306a\u3082\u306e\u3067\u3059\u3002<\/p>\n

\u591a\u5b54\u6027\u6750\u6599\u306f\u3001\u7121\u6a5f\u7269\u30fb\u6709\u6a5f\u7269\u306a\u3069\u591a\u304f\u306e\u3082\u306e\u304c\u77e5\u3089\u308c\u3066\u3044\u307e\u3059\u304c\u3001\u305d\u306e\u306a\u304b\u3067\u30011990\u5e74\u4ee3\u306b\u4eac\u90fd\u5927\u5b66\u5317\u5ddd\u9032\u6559\u6388\u3084\u30ab\u30ea\u30d5\u30a9\u30eb\u30cb\u30a2\u5927\u5b66O.M. Yaghi\u6559\u6388\u3089\u306b\u3088\u3063\u3066\u767a\u898b\u3055\u308c\u305f\u65b0\u3057\u3044\u591a\u5b54\u6027\u6750\u6599\u3068\u3057\u3066\u3001\u300c\u91d1\u5c5e\uff0d\u6709\u6a5f\u69cb\u9020\u4f53\/\u591a\u5b54\u6027\u914d\u4f4d\u9ad8\u5206\u5b50\uff08MOF: Metal Organic Framework\/PCP: Porous Coordination Polymer\uff09\u300d\u3068\u547c\u3070\u308c\u308b\u6750\u6599\u304c\u6ce8\u76ee\u3055\u308c\u3066\u3044\u307e\u3059\uff08\u3053\u3053\u3067\u306f\u4ee5\u4e0b\u3001MOF\u3068\u3044\u3046\u540d\u79f0\u3092\u4f7f\u7528\u3057\u307e\u3059\uff09\u3002<\/p>\n

MOF\u306f\u3001\u3055\u307e\u3056\u307e\u306a\u91d1\u5c5e\u30a4\u30aa\u30f3\u3068\u67b6\u6a4b\u6027\u6709\u6a5f\u591a\u5ea7\u914d\u4f4d\u5b50\u304b\u3089\u69cb\u6210\u3055\u308c\u308b\u914d\u4f4d\u7d50\u5408\u30cd\u30c3\u30c8\u30ef\u30fc\u30af\u3092\u6709\u3059\u308b\u932f\u4f53\u306e\u9ad8\u5206\u5b50\u3067\u3042\u308b\u3068\u3044\u3046\u3053\u3068\u304c\u7279\u5fb4\u3067\u3059\u3002\u591a\u304f\u306e\u5834\u5408\u3001\u914d\u4f4d\u5143\u7d20\u3068\u3057\u3066\u306f\u9178\u7d20\uff08\u30c6\u30ec\u30d5\u30bf\u30eb\u9178\u306a\u3069\uff09\u3084\u7a92\u7d20\uff084,4\u2019-\u30d3\u30d4\u30ea\u30b8\u30f3\u306a\u3069\uff09\u304c\u7528\u3044\u3089\u308c\u307e\u3059\u3002<\/p>\n

MOF\u306f\u3001\u91d1\u5c5e\u30a4\u30aa\u30f3\u3084\u30af\u30e9\u30b9\u30bf\u30fc\u304b\u3089\u306a\u308b\u7bc0\u3068\u67b6\u6a4b\u90e8\u4f4d\u304b\u3089\u69cb\u6210\u3055\u308c\u3066\u304a\u308a\u3001\u91d1\u5c5e\u30a4\u30aa\u30f3\u3068\u914d\u4f4d\u5b50\u306e\u7d44\u307f\u5408\u308f\u305b\u306f\u81a8\u5927\u306b\u3042\u308b\u3053\u3068\u304b\u3089\u3001\u975e\u5e38\u306b\u30c7\u30b6\u30a4\u30f3\u6027\u304c\u9ad8\u304f\u3001\u3055\u307e\u3056\u307e\u306aMOF\u306b\u3064\u3044\u3066\u306e\u5831\u544a\u304c\u3042\u308a\u307e\u3059\u3002<\/p>\n

\n\n<\/div>\n

\u534a\u5c0e\u4f53\u7279\u6027\u3092\u6709\u3059\u308b\u300c\u30b9\u30eb\u30d5\u30a3\u30c9MOF\u300d<\/h3>\n

MOF\u306f\u3001\u7d30\u5b54\u3092\u5229\u7528\u3057\u305f\u5438\u7740\u6750\u6599\u3068\u3057\u3066\u3060\u3051\u3067\u306a\u304f\u3001\u307b\u304b\u306b\u3082\u3055\u307e\u3056\u307e\u306a\u7269\u6027\u3092\u793a\u3059\u591a\u6a5f\u80fd\u6750\u6599\u3068\u3057\u3066\u77e5\u3089\u308c\u3066\u3044\u307e\u3059\u3002\u591a\u5b54\u8cea\u3067\u3042\u308b\u3053\u3068\u304b\u3089\u3001\u7269\u8cea\u306e\u5206\u96e2\u3084\u8caf\u8535\u306f\u3082\u3061\u308d\u3093\u306e\u3053\u3068\u3001\u89e6\u5a92\u3084\u30d7\u30ed\u30c8\u30f3\u8f38\u9001\u6750\u6599\u3068\u3057\u3066\u3082\u5229\u7528\u3055\u308c\u3066\u3044\u307e\u3059\u3002<\/p>\n

\u3055\u3089\u306b\u3001MOF\u306b\u5149\u5fdc\u7b54\u90e8\u4f4d\u3092\u4ed8\u4e0e\u3059\u308b\u3053\u3068\u3067\u3001\u592a\u967d\u96fb\u6c60\u3084\u5149\u89e6\u5a92\u3078\u306e\u5fdc\u7528\u3082\u671f\u5f85\u3055\u308c\u3066\u3044\u307e\u3059\u3002\u305d\u306e\u305f\u3081\u306b\u306f\u3001MOF\u306f\u534a\u5c0e\u4f53\u306e\u7279\u6027\u3092\u6709\u3059\u308b\u5fc5\u8981\u304c\u3042\u308a\u307e\u3059\u3002<\/p>\n

\u3053\u308c\u307e\u3067\u3001\u786b\u9ec4\u3092\u914d\u4f4d\u5143\u7d20\u3068\u3057\u3066\u542b\u3080\u914d\u4f4d\u5b50\u3092\u7528\u3044\u305fMOF\uff08\u30b9\u30eb\u30d5\u30a3\u30c9MOF\uff09\u306f\u534a\u5c0e\u4f53\u7279\u6027\u3092\u793a\u3059\u3053\u3068\u304c\u77e5\u3089\u308c\u3066\u3044\u307e\u3057\u305f\u3002\u3057\u304b\u3057\u3001\u305d\u306e\u7d50\u6676\u69cb\u9020\u306e\u5831\u544a\u4f8b\u306f\u307b\u3068\u3093\u3069\u306a\u304f\u3001\u30d0\u30f3\u30c9\u69cb\u9020\u3084\u534a\u5c0e\u4f53\u7279\u6027\u304c\u767a\u73fe\u3059\u308b\u8d77\u6e90\u306f\u5341\u5206\u306b\u691c\u8a0e\u3055\u308c\u3066\u3044\u307e\u305b\u3093\u3067\u3057\u305f\u3002<\/p>\n

\"\"<\/p>\n

\u30b9\u30eb\u30d5\u30a3\u30c9MOF\u306e\u7d50\u6676\u5316\u306b\u6210\u529f<\/h3>\n

\u3053\u308c\u307e\u3067\u3001\u30b9\u30eb\u30d5\u30a3\u30c9MOF\u306e\u7d50\u6676\u69cb\u9020\u306b\u3064\u3044\u3066\u5831\u544a\u4f8b\u304c\u9650\u5b9a\u7684\u3067\u3042\u308b\u306e\u306f\u3001\u786b\u9ec4\u306f\u96fb\u6c17\u9670\u6027\u5ea6\u304c\u5c0f\u3055\u304f\u91d1\u5c5e\u3068\u306e\u7d50\u5408\u306b\u304a\u3044\u3066\u5171\u6709\u7d50\u5408\u304c\u5f37\u304f\u306a\u308b\u305f\u3081\u306b\u3001\u69cb\u9020\u6c7a\u5b9a\u306b\u5341\u5206\u306a\u30b5\u30a4\u30ba\u306e\u7d50\u6676\u3092\u4f5c\u88fd\u3059\u308b\u3053\u3068\u304c\u56f0\u96e3\u3067\u3042\u3063\u305f\u304b\u3089\u3067\u3059\u3002\u7279\u306bMOF\u306e\u7d50\u6676\u5316\u3067\u306f\u3001\u914d\u4f4d\u5e73\u8861\u3092\u7d4c\u306a\u304c\u3089\u7d50\u6676\u6210\u9577\u3055\u305b\u308b\u5fc5\u8981\u304c\u3042\u308a\u307e\u3059\u3002<\/p>\n

\u305d\u3053\u3067\u6211\u3005\u306f\u3001\u786b\u9ec4\u3092\u542b\u3080\u914d\u4f4d\u5b50\u3068\u3057\u3066\u30c8\u30ea\u30c1\u30aa\u30b7\u30a2\u30cc\u30eb\u9178\u3092\u9078\u3073\u307e\u3057\u305f\u3002\u30d9\u30f3\u30bc\u30f3\u306e\u70ad\u7d20\u304c3\u3064\u7a92\u7d20\u306b\u7f6e\u63db\u3055\u308c\u305f\u30c8\u30ea\u30a2\u30b8\u30f3\u9aa8\u683c\u306b\u3088\u308a\u3001\u30c1\u30aa\u30fc\u30eb\u57fa\u306e\u786b\u9ec4\u4e0a\u306e\u96fb\u5b50\u5bc6\u5ea6\u3092\u4f4e\u4e0b\u3055\u305b\u308b\u3053\u3068\u3067\u53cd\u5fdc\u901f\u5ea6\u3092\u4f4e\u4e0b\u3055\u305b\u308b\u3053\u3068\u3092\u671f\u5f85\u3057\u307e\u3057\u305f\u3002<\/p>\n

\u307e\u305f\u91d1\u5c5e\u30a4\u30aa\u30f3\u3068\u3057\u3066\u306f\u3001\u925b\u3092\u9078\u5b9a\u3057\u307e\u3057\u305f\u3002\u925b\u30a4\u30aa\u30f3\u306f\u786b\u9ec4\u30a2\u30cb\u30aa\u30f3\u3068\u5b89\u5b9a\u7684\u306a\u7d50\u5408\u5f62\u6210\u304c\u671f\u5f85\u3067\u304d\u3001\u7bc0\u306bPbS\u306e\u30ca\u30ce\u69cb\u9020\u3092\u5c0e\u5165\u3059\u308b\u3053\u3068\u304c\u3067\u304d\u307e\u3059\u3002\u305d\u306e\u305f\u3081\u3001\u7279\u7570\u7684\u306a\u96fb\u6c17\u7684\u6027\u8cea\u306e\u767a\u73fe\u306b\u671f\u5f85\u3057\u307e\u3057\u305f\u3002\u52a0\u3048\u3066\u3001\u925b\u30a4\u30aa\u30f3\u306f\u9ad8\u3044\u914d\u4f4d\u6570\u3092\u53d6\u308b\u3053\u3068\u304c\u3067\u304d\u308b\u306e\u3067\u3001\u9ad8\u3044\u4f1d\u5c0e\u6027\u304c\u671f\u5f85\u3067\u304d\u308b\u9ad8\u6b21\u5143\u306ePb-S\u69cb\u9020\u3092\u6301\u3064MOF\u304c\u69cb\u7bc9\u3055\u308c\u308b\u3053\u3068\u3092\u671f\u5f85\u3057\u307e\u3057\u305f\u3002<\/p>\n

\u6211\u3005\u306f\u3001\u3053\u306e\u30c8\u30ea\u30c1\u30aa\u30b7\u30a2\u30cc\u30eb\u9178\u3068\u925b\u3092\u7d44\u307f\u5408\u308f\u305b\u308b\u3053\u3068\u3067\u3001\u786b\u9ec4\u304b\u3089\u69cb\u6210\u3055\u308c\u308b\u30af\u30e9\u30b9\u30bf\u30fc\u3092\u7bc0\u306b\u6301\u3064\u3001\u65b0\u898f\u30b9\u30eb\u30d5\u30a3\u30c9MOF\u306e\u7d50\u6676\u69cb\u9020\u3092\u6c7a\u5b9a\u3059\u308b\u3053\u3068\u306b\u6210\u529f\u3057\u307e\u3057\u305f\u3002<\/p>\n

\u7d50\u6676\u69cb\u9020\u3092\u898b\u3066\u307f\u308b\u3068\u3001\u7d50\u6676\u5b66\u7684\u306b\u975e\u7b49\u4fa1\u306a2\u7a2e\u985e\u306e\u925b\u539f\u5b50\u304c\u5b58\u5728\u3057\u3001\u7247\u65b9\u304c1\u6b21\u5143\u306b\u3064\u306a\u304c\u3063\u3066\u3044\u308b\u3053\u3068\u304c\u308f\u304b\u308a\u307e\u3059\u3002\u305d\u306e1\u6b21\u5143\u9396\u3092\u3082\u3046\u3072\u3068\u3064\u306e\u925b\u539f\u5b50\u304c\u67b6\u6a4b\u3059\u308b\u3053\u3068\u3067\u30013\u6b21\u5143\u69cb\u9020\u3092\u6709\u3057\u3066\u3044\u308b\u3053\u3068\u304c\u308f\u304b\u308a\u307e\u3057\u305f\u3002<\/p>\n

\"\"<\/p>\n

\u6c34\u304b\u3089\u6c34\u7d20\u3092\u767a\u751f\u3059\u308b\u300c\u5149\u89e6\u5a92\u300d\u3078\u306e\u5fdc\u7528<\/h3>\n

\u3053\u306e\u30b9\u30eb\u30d5\u30a3\u30c9MOF\u306f\u3001\u7d50\u6676\u69cb\u9020\u304b\u3089\u308f\u304b\u308b\u3088\u3046\u306b\u7121\u6570\u306e\u7a74\u304c\u958b\u3044\u3066\u3044\u308b\u69cb\u9020\u3067\u3042\u308a\u3001\u5408\u6210\u76f4\u5f8c\u306f\u3053\u306e\u7a74\u306b\u6c34\u5206\u5b50\u3092\u5438\u7740\u3057\u3066\u3044\u308b\u3053\u3068\u304c\u308f\u304b\u308a\u307e\u3057\u305f\u3002\u3053\u306e\u7d30\u5b54\u4e2d\u306e\u6c34\u5206\u5b50\u306f\u3001\u52a0\u71b1\u771f\u7a7a\u4e7e\u71e5\u3092\u884c\u3046\u3053\u3068\u3067\u8131\u7740\u3067\u304d\u3001\u8131\u7740\u5f8c\u3082\u540c\u69d8\u306e\u69cb\u9020\u3092\u6709\u3057\u3066\u3044\u308b\u3053\u3068\u304c\u308f\u304b\u308a\u307e\u3057\u305f\u3002\u307e\u305f\u3001\u30a2\u30eb\u30b3\u30fc\u30eb\u3084\u7a92\u7d20\u5206\u5b50\u306f\u5438\u7740\u305b\u305a\u3001\u6c34\u5206\u5b50\u306e\u307f\u3092\u9078\u629e\u7684\u306b\u5438\u7740\u3059\u308b\u3053\u3068\u3084\u3001\u6c34\u4e2d\u304a\u3088\u3073\u9178\u30fb\u5869\u57fa\u6c34\u6eb6\u6db2\u4e2d\u3067\u3082\u5b89\u5b9a\u306b\u5b58\u5728\u3067\u304d\u308b\u3053\u3068\u3082\u308f\u304b\u308a\u307e\u3057\u305f\u3002<\/p>\n

\u6b21\u306b\u3001\u3053\u306e\u30b9\u30eb\u30d5\u30a3\u30c9MOF\u306e\u30d0\u30f3\u30c9\u69cb\u9020\u3092\u8a55\u4fa1\u3059\u308b\u305f\u3081\u306b\u3001\u6642\u9593\u5206\u89e3\u30de\u30a4\u30af\u30ed\u6ce2\u4f1d\u5c0e\u5ea6\u6e2c\u5b9a\u3092\u884c\u3044\u307e\u3057\u305f\u3002\u3053\u306e\u6e2c\u5b9a\u306f\u3001\u5149\u3092\u5f53\u3066\u305f\u969b\u306b\u30ad\u30e3\u30ea\u30a2\uff08\u96fb\u5b50\u3068\u6b63\u5b54\uff09\u306e\u751f\u6210\u3068\u305d\u308c\u3089\u306e\u79fb\u52d5\u5ea6\u306b\u3064\u3044\u3066\u8a55\u4fa1\u3067\u304d\u308b\u6e2c\u5b9a\u3067\u3059\u3002\u3053\u306e\u6e2c\u5b9a\u306b\u3088\u308a\u3001\u3053\u306eMOF\u306f\u5149\u96fb\u6c17\u4f1d\u5c0e\u7279\u6027\u3092\u6709\u3057\u3066\u3044\u308b\u3053\u3068\u304c\u308f\u304b\u308a\u307e\u3057\u305f\u3002<\/p>\n

\u52a0\u3048\u3066\u3001\u7b2c\u4e00\u539f\u7406\u8a08\u7b97\u3092\u7528\u3044\u305f\u72b6\u614b\u5bc6\u5ea6\u8a08\u7b97\u3088\u308a\u3001\u4fa1\u96fb\u5b50\u5e2f\u306f\u786b\u9ec4\u306e\u5bc4\u4e0e\u304c\u975e\u5e38\u306b\u5927\u304d\u3044\u3053\u3068\u304c\u660e\u3089\u304b\u306b\u306a\u308a\u307e\u3057\u305f\u3002\u307e\u305f\u3001\u4f1d\u5c0e\u5e2f\u306b\u306f\u3059\u3079\u3066\u306e\u7a2e\u985e\u306e\u539f\u5b50\u304c\u5bc4\u4e0e\u3057\u3066\u304a\u308a\u3001\u786b\u9ec4\u306f\u4fa1\u96fb\u5b50\u5e2f\u3068\u4f1d\u5c0e\u5e2f\u306e\u3069\u3061\u3089\u306b\u3082\u91cd\u8981\u306a\u5bc4\u4e0e\u3057\u3066\u3044\u308b\u3053\u3068\u304c\u308f\u304b\u308a\u307e\u3057\u305f\u3002<\/p>\n

\u5149\u7167\u5c04\u306b\u3088\u308a\u30ad\u30e3\u30ea\u30a2\u304c\u751f\u6210\u3059\u308b\u3053\u3068\u304c\u308f\u304b\u308a\u307e\u3057\u305f\u306e\u3067\u3001\u6211\u3005\u306f\u3053\u306e\u751f\u6210\u3057\u305f\u30ad\u30e3\u30ea\u30a2\u3092\u6c34\u306e\u5206\u89e3\u306b\u3088\u3063\u3066\u6c34\u7d20\u3092\u767a\u751f\u3059\u308b\u300c\u5149\u89e6\u5a92\u300d\u306b\u5fdc\u7528\u3057\u307e\u3057\u305f\u3002\u3053\u306eMOF\u3068\u3001\u72a0\u7272\u9084\u5143\u5264\u3067\u3042\u308b\u30a8\u30c1\u30ec\u30f3\u30b8\u30a2\u30df\u30f34\u9162\u9178\uff08EDTA\uff09\u3092\u6c34\u306b\u52a0\u3048\u3001\u53ef\u8996\u5149\u3092\u7167\u5c04\u3057\u305f\u3068\u3053\u308d\u3001\u6c34\u7d20\u306e\u767a\u751f\u304c\u78ba\u8a8d\u3055\u308c\u307e\u3057\u305f\u3002\u3055\u3089\u306b\u3001\u52a9\u89e6\u5a92\u3068\u306a\u308b\u767d\u91d1\u3092MOF\u306b\u62c5\u6301\u3059\u308b\u3053\u3068\u3067\u3001\u89e6\u5a92\u3068\u3057\u3066\u306e\u6027\u80fd\u304c\u5411\u4e0a\u3057\u307e\u3057\u305f\u3002<\/p>\n

\u3053\u308c\u3089\u306e\u7d50\u679c\u3088\u308a\u3001\u89e6\u5a92\u30e1\u30ab\u30cb\u30ba\u30e0\u306f\u4ee5\u4e0b\u306e\u3088\u3046\u306b\u8003\u3048\u3089\u308c\u307e\u3059\u3002\u307e\u305a\u3001\u53ef\u8996\u5149\u5438\u53ce\u306b\u3088\u308a\u96fb\u5b50\u304c\u52b1\u8d77\u3055\u308c\u307e\u3059\u3002\u3053\u306e\u969b\u3001\u751f\u6210\u3057\u305f\u6b63\u5b54\u306f\u72a0\u7272\u9084\u5143\u5264\u3067\u3042\u308bEDTA\u306b\u30af\u30a8\u30f3\u30c1\u3055\u308c\u307e\u3059\u3002\u52b1\u8d77\u3057\u305f\u96fb\u5b50\u306f\u3001MOF\u4e0a\u3067\u306e\u6c34\u3092\u9084\u5143\u3082\u3057\u304f\u306f\u30de\u30a4\u30b0\u30ec\u30fc\u30b7\u30e7\u30f3\u3057\u3066\u52a9\u89e6\u5a92\u306e\u767d\u91d1\u4e0a\u306b\u79fb\u52d5\u3057\u307e\u3059\u3002\u3053\u306e\u767d\u91d1\u4e0a\u306b\u79fb\u52d5\u3057\u305f\u96fb\u5b50\u3082\u3001\u6c34\u306e\u5206\u89e3\u306b\u5229\u7528\u3055\u308c\u308b\u3053\u3068\u304c\u308f\u304b\u308a\u307e\u3057\u305f\u3002<\/p>\n

\"\"<\/p>\n

\u30b9\u30eb\u30d5\u30a3\u30c9MOF\u306e\u4eca\u5f8c\u306e\u5c55\u958b<\/h3>\n

\u30b9\u30eb\u30d5\u30a3\u30c9MOF\u306f\u3001\u534a\u5c0e\u4f53MOF\u306e\u9818\u57df\u306b\u65b0\u305f\u306a\u53ef\u80fd\u6027\u3092\u5207\u308a\u62d3\u304f\u3082\u306e\u306b\u306a\u3063\u3066\u3044\u304f\u3068\u601d\u3044\u307e\u3059\u3002\u4eca\u56de\u306e\u30b9\u30eb\u30d5\u30a3\u30c9MOF\u304b\u3089\u3001\u786b\u9ec4\u306f\u30d0\u30f3\u30c9\u69cb\u9020\u306b\u5927\u304d\u306a\u5909\u5316\u3092\u53ca\u307c\u3059\u3053\u3068\u304c\u660e\u3089\u304b\u306b\u306a\u308a\u307e\u3057\u305f\u3002\u3053\u306e\u77e5\u898b\u3092\u6d3b\u304b\u3057\u3066\u3001\u3055\u3089\u306b\u591a\u304f\u306e\u30b9\u30eb\u30d5\u30a3\u30c9MOF\u304c\u5408\u6210\u3055\u308c\u308b\u3053\u3068\u3067\u3001\u9ad8\u6a5f\u80fd\u6750\u6599\u306e\u958b\u767a\u304c\u671f\u5f85\u3055\u308c\u307e\u3059\u3002<\/p>\n

\u4e00\u65b9\u3067\u3001\u30b9\u30eb\u30d5\u30a3\u30c9MOF\u306e\u5408\u6210\u306f\u96e3\u3057\u304f\u3001\u5408\u6210\u304a\u3088\u3073\u7d50\u6676\u5316\u306e\u305f\u3081\u306e\u53cd\u5fdc\u6761\u4ef6\u306e\u63a2\u7d22\u306b\u306f\u975e\u5e38\u306b\u591a\u6570\u306e\u5408\u6210\u5b9f\u9a13\u306e\u8a66\u884c\u932f\u8aa4\u304c\u5fc5\u8981\u3068\u306a\u308a\u307e\u3059\u3002\u4eca\u5f8c\u306f\u3001\u3053\u306e\u3088\u3046\u306a\u5408\u6210\u306e\u96e3\u3057\u3044\u6750\u6599\u3092\u52b9\u7387\u7684\u306b\u63a2\u7d22\u3059\u308b\u305f\u3081\u306b\u3001\u6211\u3005\u306e\u7814\u7a76\u5ba4\u3067\u306f\u30de\u30c6\u30ea\u30a2\u30eb\u30ba\u30a4\u30f3\u30d5\u30a9\u30de\u30c6\u30a3\u30af\u30b9\u306e\u624b\u6cd5\u3092\u6d3b\u7528\u3057\u3001\u6a5f\u68b0\u5b66\u7fd2\u306a\u3069\u3092\u5229\u7528\u3057\u3066\u5408\u6210\u6761\u4ef6\u63a2\u7d22\u306e\u52b9\u7387\u5316\u3082\u4f75\u305b\u3066\u9032\u3081\u3066\u3044\u307e\u3059\u3002<\/p>\n

\u53c2\u8003\u6587\u732e<\/strong>
\nY. Kamakura, P. Chinapang, S. Masaoka, A. Saeki, K. Ogasawara, S. R. Nishitani, H. Yoshikawa, T. Katayama, N. Tamai, K. Sugimototo, D. Tanaka “Semiconductive Nature of Lead-Based Metal\u2013Organic Frameworks with Three-Dimensionally Extended Sulfur Secondary Building Units” J. Am. Chem. Soc.<\/em> 2020<\/strong>, 142, 27-32 https:\/\/doi.org\/10.1021\/jacs.9b10436<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"

\u65b0\u3057\u3044\u591a\u5b54\u6027\u6750\u6599\u300cMOF\u300d\u3068\u306f\uff1f \u6211\u3005\u306e\u751f\u6d3b\u306b\u306f\u3001\u5206\u5b50\u30b5\u30a4\u30ba\u306e\u5c0f\u3055\u306a\u7a74\u304c\u7121\u6570\u306b\u7a7a\u3044\u305f\u69cb\u9020\u3067\u3042\u308b\u591a\u5b54\u6027\u6750\u6599\u304c\u3042\u3075\u308c\u3066\u3044\u307e\u3059\u3002\u305f\u3068\u3048\u3070\u3001\u4e7e\u71e5\u6750\u306b\u4f7f\u7528\u3055\u308c\u3066\u3044\u308b\u30b7\u30ea\u30ab\u30b2\u30eb\u3084\u6d88\u81ed\u5264\u3068\u3057\u3066\u4f7f\u7528\u3055\u308c\u3066\u3044\u308b\u6d3b\u6027\u70ad\u306a […]<\/p>\n","protected":false},"author":460,"featured_media":12542,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_acf_changed":false,"_monsterinsights_skip_tracking":false,"_monsterinsights_sitenote_active":false,"_monsterinsights_sitenote_note":"","_monsterinsights_sitenote_category":0,"footnotes":""},"categories":[3],"tags":[20,139,59,84],"class_list":["post-12546","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-outcome","tag-20","tag-139","tag-59","tag-84","has_thumb"],"acf":[],"aioseo_notices":[],"_links":{"self":[{"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=\/wp\/v2\/posts\/12546","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=\/wp\/v2\/users\/460"}],"replies":[{"embeddable":true,"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=12546"}],"version-history":[{"count":14,"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=\/wp\/v2\/posts\/12546\/revisions"}],"predecessor-version":[{"id":12829,"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=\/wp\/v2\/posts\/12546\/revisions\/12829"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=\/wp\/v2\/media\/12542"}],"wp:attachment":[{"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=12546"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=12546"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=12546"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}