{"id":12111,"date":"2019-11-21T08:00:01","date_gmt":"2019-11-20T23:00:01","guid":{"rendered":"https:\/\/academist-cf.com\/journal\/?p=12111"},"modified":"2020-01-10T17:55:59","modified_gmt":"2020-01-10T08:55:59","slug":"%e3%82%ae%e9%85%b8%e3%81%a7%e6%b0%b4%e7%b4%a0%e3%82%a8%e3%83%8d%e3%83%ab%e3%82%ae%e3%83%bc%e7%a4%be%e4%bc%9a%e3%82%92%e5%88%87%e3%82%8a%e6%8b%93%e3%81%8f-%e9%87%8d%e6%b0%b4%e7%b4%a0%e3%82%ac","status":"publish","type":"post","link":"https:\/\/academist-cf.com\/journal\/?p=12111","title":{"rendered":"\u30ae\u9178\u3067\u6c34\u7d20\u30a8\u30cd\u30eb\u30ae\u30fc\u793e\u4f1a\u3092\u5207\u308a\u62d3\u304f &#8211; 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id=\"attachment_12114\" aria-describedby=\"caption-attachment-12114\" style=\"width: 600px\" class=\"wp-caption aligncenter\"><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2019\/11\/003-1.jpg\" alt=\"\" width=\"600\" height=\"501\" class=\"size-full wp-image-12114\" srcset=\"https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2019\/11\/003-1.jpg 600w, https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2019\/11\/003-1-300x251.jpg 300w\" sizes=\"auto, (max-width: 600px) 100vw, 600px\" \/><figcaption id=\"caption-attachment-12114\" class=\"wp-caption-text\">\u91cd\u6c34\u7d20\u30ac\u30b9\u304c\u4f5c\u308a\u5206\u3051\u3089\u308c\u308b\u30e1\u30ab\u30cb\u30ba\u30e0\u3002\u56f3\u4e2d\u306e<em>E<sub>a<\/sub><\/em>\u306f\u7406\u8ad6\u8a08\u7b97\u306b\u3088\u308a\u5f97\u305f\u6d3b\u6027\u5316\u30a8\u30cd\u30eb\u30ae\u30fc\uff08kJ\/mol\uff09\u3002<\/figcaption><\/figure>\n<p>\u6c34\u7d20\u306e\u540c\u4f4d\u4f53\u5316\u5408\u7269\u3067\u3042\u308b\u91cd\u6c34\u7d20\u30ac\u30b9\uff08D<sub>2<\/sub>\u304a\u3088\u3073HD\uff09\u306f\u3001\u5316\u5b66\u30fb\u751f\u7269\u5b66\u306e\u5b9f\u9a13\u7814\u7a76\u7528\u8a66\u85ac\u3068\u3057\u3066\u3001\u307e\u305f\u3001\u534a\u5c0e\u4f53\u3001\u5149\u30d5\u30a1\u30a4\u30d0\u30fc\u306a\u3069\u306e\u88fd\u9020\u5de5\u7a0b\u3067\u3082\u4f7f\u7528\u3055\u308c\u308b\u9ad8\u4fa1\u306a\u7279\u6b8a\u30ac\u30b9\u3067\u3059\u3002<\/p>\n<p>\u73fe\u72b6D<sub>2<\/sub>\u30ac\u30b9\u306fD<sub>2<\/sub>O\u306e\u96fb\u6c17\u5206\u89e3\u306b\u3088\u308a\u3001HD\u30ac\u30b9\u306fH<sub>2<\/sub>\u3068D<sub>2<\/sub>\u306e\u63a5\u89e6\u540c\u4f4d\u4f53\u4ea4\u63db\u6cd5\u306b\u3088\u308a\u305d\u308c\u305e\u308c\u5408\u6210\u3055\u308c\u3066\u3044\u307e\u3059\u304c\u3001\u3044\u305a\u308c\u3082\u30a8\u30cd\u30eb\u30ae\u30fc\u591a\u6d88\u8cbb\u578b\u306e\u30d7\u30ed\u30bb\u30b9\u306e\u305f\u3081\u3001\u5e02\u8ca9\u54c1\u306f\u6975\u3081\u3066\u9ad8\u4fa1\u3067\u3059\u3002\u307e\u305f\u3001\u65e5\u672c\u3067\u306f\u305d\u306e\u307b\u3068\u3093\u3069\u3092\u6d77\u5916\u304b\u3089\u306e\u8f38\u5165\u306b\u983c\u3063\u3066\u3044\u308b\u305f\u3081\u3001\u89e6\u5a92\u6280\u8853\u3092\u7528\u3044\u305f\u7c21\u4fbf\u306a\u5408\u6210\u6cd5\u304c\u671b\u307e\u308c\u3066\u3044\u307e\u3057\u305f\u3002<\/p>\n<p>\u4eca\u56de\u79c1\u305f\u3061\u304c\u958b\u767a\u3057\u305f\u89e6\u5a92\u306f\u3001\u8abf\u88fd\u304c\u6975\u3081\u3066\u7c21\u4fbf\u3067\u3042\u308b\u3001\u5b89\u5b9a\u6027\u304c\u9ad8\u304f\u5206\u96e2\u30fb\u56de\u53ce\u306e\u5bb9\u6613\u306a\u56fa\u4f53\u89e6\u5a92\u3067\u3042\u308b\u3001\u5869\u57fa\u6027\u3092\u5236\u5fa1\u3059\u308b\u3053\u3068\u3067\u76ee\u7684\u306e\u91cd\u6c34\u7d20\u3092\u4efb\u610f\u306b\u5f97\u3089\u308c\u308b\u3001\u306a\u3069\u5b9f\u7528\u5316\u306b\u4e0d\u53ef\u6b20\u306a\u57fa\u76e4\u8981\u7d20\u3092\u517c\u306d\u5099\u3048\u3066\u3044\u307e\u3059\u3002\u3053\u308c\u306b\u3088\u308a\u3001\u4eca\u5f8c\u306e\u4e16\u754c\u7684\u306a\u9700\u8981\u62e1\u5927\u304c\u4e88\u60f3\u3055\u308c\u308b\u91cd\u6c34\u7d20\u306e\u88fd\u9020\u306b\u5bfe\u5fdc\u3067\u304d\u308b\u4f4e\u30b3\u30b9\u30c8\u88fd\u9020\u6cd5\u3068\u3057\u3066\u671f\u5f85\u3055\u308c\u307e\u3059\u3002<\/p>\n<h3>\u91cf\u5b50\u30c8\u30f3\u30cd\u30eb\u52b9\u679c\u304c\u95a2\u4e0e\uff1f<\/h3>\n<p>\u7269\u8cea\u3092\u7c92\u5b50\u3068\u3057\u3066\u6271\u3046\u53e4\u5178\u529b\u5b66\u3067\u306f\u3001\u5316\u5b66\u53cd\u5fdc\u304c\u9032\u884c\u3059\u308b\u305f\u3081\u306b\u306f\u53cd\u5fdc\u7269\u304c\u6d3b\u6027\u5316\u969c\u58c1\u3092\u4e57\u308a\u8d8a\u3048\u308b\u30a8\u30cd\u30eb\u30ae\u30fc\u304c\u5fc5\u8981\u3067\u3059\u3002\u3059\u306a\u308f\u3061\u30a2\u30ec\u30cb\u30a6\u30b9\u306e\u5f0f\u306b\u5f93\u3044\u3001\u71b1\u3092\u52a0\u3048\u308c\u3070\u53cd\u5fdc\u304c\u52a0\u901f\u3057\u307e\u3059\u304c\u3001\u3053\u308c\u3068\u306f\u7570\u306a\u308a\u96fb\u5b50\u3084\u8cea\u91cf\u306e\u8efd\u3044\u6c34\u7d20\u539f\u5b50\u3067\u306f\u6ce2\u52d5\u6027\u304c\u9855\u8457\u3067\u3042\u308b\u305f\u3081\u3001\u71b1\u529b\u5b66\u3068\u306f\u95a2\u4fc2\u306a\u304f\u91cf\u5b50\u30c8\u30f3\u30cd\u30eb\u52b9\u679c\u306b\u3088\u3063\u3066\u6d3b\u6027\u5316\u969c\u58c1\u3092\u900f\u904e\u3057\u3066\u5316\u5b66\u53cd\u5fdc\u304c\u9032\u3080\u5834\u5408\u304c\u3042\u308a\u307e\u3059\u3002<\/p>\n<figure id=\"attachment_12115\" aria-describedby=\"caption-attachment-12115\" style=\"width: 600px\" class=\"wp-caption aligncenter\"><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2019\/11\/004-1.jpg\" alt=\"\" width=\"600\" height=\"465\" class=\"size-full wp-image-12115\" srcset=\"https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2019\/11\/004-1.jpg 600w, https:\/\/academist-cf.com\/journal\/wp-content\/uploads\/2019\/11\/004-1-300x233.jpg 300w\" sizes=\"auto, (max-width: 600px) 100vw, 600px\" \/><figcaption id=\"caption-attachment-12115\" class=\"wp-caption-text\">\u71b1\u6d3b\u6027\u5316\u3068\u91cf\u5b50\u30c8\u30f3\u30cd\u30eb\u52b9\u679c\u306b\u3088\u308b\u5316\u5b66\u53cd\u5fdc<br \/><\/figcaption><\/figure>\n<p>\u3053\u308c\u307e\u3067\u3001\u96fb\u5b50\u4f1d\u9054\u7cfb\u3001\u9175\u7d20\u3001\u7a2e\u3005\u306e\u6709\u6a5f\u5316\u5b66\u53cd\u5fdc\u306a\u3069\u306b\u304a\u3044\u3066\u91cf\u5b50\u30c8\u30f3\u30cd\u30eb\u52b9\u679c\u304c\u78ba\u8a8d\u3055\u308c\u3066\u3044\u307e\u3059\u3002\u30c8\u30f3\u30cd\u30eb\u52b9\u679c\u3092\u76f4\u63a5\u89b3\u5bdf\u3059\u308b\u3053\u3068\u306f\u975e\u5e38\u306b\u56f0\u96e3\u3067\u3059\u304c\u3001\u7269\u8cea\u306e\u6ce2\u52d5\u6027\u306f\u8cea\u91cf\u306b\u53cd\u6bd4\u4f8b\u3059\u308b\u305f\u3081\u3001\u91cd\u6c34\u7d20\u539f\u5b50\uff08D\uff09\u306f\u6c34\u7d20\u539f\u5b50\uff08H\uff09\u306b\u6bd4\u3079\u969c\u58c1\u3092\u900f\u904e\u3057\u306b\u304f\u304f\u3001\u5927\u304d\u306a\u540c\u4f4d\u4f53\u52b9\u679c\u304c\u89b3\u6e2c\u3067\u304d\u307e\u3059\u3002<\/p>\n<p>\u4eca\u56de\u7d39\u4ecb\u3057\u305f\u30ae\u9178\u304b\u3089\u306e\u6c34\u7d20\u751f\u6210\u53cd\u5fdc\u306b\u306f\u91cf\u5b50\u30c8\u30f3\u30cd\u30eb\u52b9\u679c\u304c\u95a2\u4e0e\u3057\u3066\u304a\u308a\u3001\u7279\u306bPdAg\u5408\u91d1\u30ca\u30ce\u7c92\u5b50\u4e0a\u3067\u306eH\uff0dD\u4ea4\u63db\u53cd\u5fdc\u304c\u91cf\u5b50\u30c8\u30f3\u30cd\u30eb\u52b9\u679c\u306b\u652f\u914d\u3055\u308c\u3066\u3044\u308b\u3053\u3068\u3092\u3001\u540c\u4f4d\u4f53\u52b9\u679c\u304a\u3088\u3073\u7406\u8ad6\u8a08\u7b97\u3092\u7528\u3044\u3066\u79c1\u305f\u3061\u306f\u8a3c\u660e\u3057\u307e\u3057\u305f\u3002<\/p>\n<p>\u6c34\u7d20\u539f\u5b50\u306fH<sub>2<\/sub>O\u3092\u306f\u3058\u3081\u975e\u5e38\u306b\u8eab\u8fd1\u306a\u5143\u7d20\u3067\u3042\u308b\u305f\u3081\u3001\u6c34\u7d20\u304c\u95a2\u308f\u308b\u5316\u5b66\u53cd\u5fdc\u306b\u91cf\u5b50\u30c8\u30f3\u30cd\u30eb\u52b9\u679c\u304c\u3069\u306e\u3088\u3046\u306b\u95a2\u4e0e\u3057\u3066\u3044\u308b\u304b\u3092\u7406\u89e3\u3059\u308b\u3053\u3068\u306f\u3001\u5b66\u8853\u7684\u306a\u610f\u7fa9\u304c\u6975\u3081\u3066\u9ad8\u3044\u3082\u306e\u3067\u3059\u3002\u91cf\u5b50\u30c8\u30f3\u30cd\u30eb\u52b9\u679c\u306f\u6628\u4eca\u65b0\u3057\u3044\u53cd\u5fdc\u30d1\u30e9\u30c0\u30a4\u30e0\u3068\u3057\u3066\u6ce8\u76ee\u3055\u308c\u3066\u304a\u308a\u3001\u71b1\u529b\u5b66\u7684\u304a\u3088\u3073\u53cd\u5fdc\u901f\u5ea6\u8ad6\u7684\u5236\u5fa1\u306b\u52a0\u3048\u3001\u91cf\u5b50\u30c8\u30f3\u30cd\u30eb\u52b9\u679c\u3092\u5229\u7528\u3057\u3066\u5316\u5b66\u53cd\u5fdc\u304c\u5236\u5fa1\u3067\u304d\u308b\u53ef\u80fd\u6027\u304c\u3042\u308a\u307e\u3059\u3002<\/p>\n<p><strong>\u53c2\u8003\u6587\u732e<\/strong><\/p>\n<ul>\n<li>K. Mori, S. Masuda, H. Tanaka, K. Yoshizawa, M. Che, H. Yamashita, \u201cPhenylamine-Functionalized Mesoporous Silica Supported PdAg Nanoparticles: A Reversible Heterogeneous Catalyst for the Formic Acid\/CO2-mediated Chemical Hydrogen Delivery\/Storage\u201d, <em>Chem. Commun.<\/em>, 53, 4677 (2017)<\/li>\n<li>K. Mori, Y. Futamura, S. Masuda, H. Kobayashi, H. Yamashita, \u201cControlled Release of Hydrogen Isotope Compounds and Tunneling Effect in the Heterogeneously-Catalyzed Formic Acid Dehydrogenation\u201d, <em>Nat. Commun.<\/em>, 10, 4094 (2019).<\/li>\n<\/ul>\n","protected":false},"excerpt":{"rendered":"<p>\u30ae\u9178\u306f\u6c34\u7d20\u30ac\u30b9\u3092\u5b89\u5168\u306b\u8caf\u8535\u8f38\u9001\u3067\u304d\u308b\u6db2\u4f53 \u65e5\u672c\u56fd\u5185\u306b\u304a\u3051\u308b\u71c3\u6599\u96fb\u6c60\u81ea\u52d5\u8eca\u306e\u8ca9\u58f2\u304c\u958b\u59cb\u3057\u3001\u3055\u3089\u306b\u6c34\u7d20\u30b9\u30c6\u30fc\u30b7\u30e7\u30f3\u306e\u5546\u7528\u904b\u7528\u3082\u6574\u5099\u3055\u308c\u59cb\u3081\u3001\u6c34\u7d20\u30a8\u30cd\u30eb\u30ae\u30fc\u793e\u4f1a\u304c\u672c\u683c\u7684\u306b\u5e55\u3092\u958b\u3051\u307e\u3057\u305f\u3002\u74b0\u5883\u8ca0\u8377\u304c\u4f4e\u304f\u9ad8\u52b9\u7387 [&hellip;]<\/p>\n","protected":false},"author":444,"featured_media":12114,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_acf_changed":false,"_monsterinsights_skip_tracking":false,"_monsterinsights_sitenote_active":false,"_monsterinsights_sitenote_note":"","_monsterinsights_sitenote_category":0,"footnotes":""},"categories":[3],"tags":[20,103],"class_list":["post-12111","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-outcome","tag-20","tag-103","has_thumb"],"acf":[],"aioseo_notices":[],"_links":{"self":[{"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=\/wp\/v2\/posts\/12111","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=\/wp\/v2\/users\/444"}],"replies":[{"embeddable":true,"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=12111"}],"version-history":[{"count":18,"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=\/wp\/v2\/posts\/12111\/revisions"}],"predecessor-version":[{"id":12475,"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=\/wp\/v2\/posts\/12111\/revisions\/12475"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=\/wp\/v2\/media\/12114"}],"wp:attachment":[{"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=12111"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=12111"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/academist-cf.com\/journal\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=12111"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}