{"id":11658,"date":"2019-09-13T08:00:47","date_gmt":"2019-09-12T23:00:47","guid":{"rendered":"https:\/\/academist-cf.com\/journal\/?p=11658"},"modified":"2020-01-10T18:09:10","modified_gmt":"2020-01-10T09:09:10","slug":"%e6%96%b0%e3%81%9f%e3%81%aa%e8%a7%a6%e5%aa%92%e6%8a%80%e8%a1%93%e3%81%a7%e3%82%a2%e3%83%9f%e3%83%8e%e9%85%b8%e3%82%92%e5%8c%96%e6%88%90%e5%93%81%e5%8e%9f%e6%96%99%e3%81%b8%e5%a4%89%e6%8f%9b%e3%81%99","status":"publish","type":"post","link":"https:\/\/academist-cf.com\/journal\/?p=11658","title":{"rendered":"\u65b0\u305f\u306a\u89e6\u5a92\u6280\u8853\u3067\u30a2\u30df\u30ce\u9178\u3092\u5316\u6210\u54c1\u539f\u6599\u3078\u5909\u63db\u3059\u308b\uff01"},"content":{"rendered":"

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\n\n<\/div>\n

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\u89e6\u5a92\u306b\u306f\u3055\u307e\u3056\u307e\u306a\u9084\u5143\u53cd\u5fdc\u306b\u5bfe\u3057\u3066\u89e6\u5a92\u6d3b\u6027\u3092\u793a\u3059\u8cb4\u91d1\u5c5e\u89e6\u5a92\u306e\u767d\u91d1\uff08Pt\uff09\u3001 \u30d1\u30e9\u30b8\u30a6\u30e0\uff08Pd\uff09\u3001\u30ed\u30b8\u30a6\u30e0\uff08Rh\uff09\u3001\u30eb\u30c6\u30cb\u30a6\u30e0\uff08Ru\uff09\u3092\u30a2\u30eb\u30df\u30ca\u4e0a\u306b\u62c5\u6301\u3057\u305f\u5e02\u8ca9\u54c1\u3092\u7528\u3044\u3066\u53cd\u5fdc\u3092\u884c\u3063\u305f\u3068\u3053\u308d\u3001\u300c\u62c5\u6301\u30eb\u30c6\u30cb\u30a6\u30e0\u89e6\u5a92\u300d\u304c\u7279\u7570\u7684\u306b\u9ad8\u3044\u6d3b\u6027\u3092\u793a\u3057\u3001\u6700\u3082\u591a\u304f\u306e2-\u30d4\u30ed\u30ea\u30c9\u30f3\u3092\u751f\u6210\u3059\u308b\u3053\u3068\u3092\u898b\u51fa\u3057\u307e\u3057\u305f\u3002\u3053\u306e\u3068\u304d\u306b\u300c\u30d4\u30ed\u30b0\u30eb\u30bf\u30df\u30ce\u30fc\u30eb\u300d\u3082\u751f\u6210\u3057\u305f\u306e\u3067\u3053\u308c\u304c\u53cd\u5fdc\u4e2d\u9593\u4f53\u3067\u3042\u308b\u3068\u8003\u3048\u307e\u3057\u305f\u3002<\/p>\n

\"\"
\u30d4\u30ed\u30b0\u30eb\u30bf\u30df\u30f3\u9178\u304b\u3089\u306e2-\u30d4\u30ed\u30ea\u30c9\u30f3\u5408\u6210\uff08\u6c34\u7d202 MPa, 160 \u2103, 2 hr\uff09<\/figcaption><\/figure>\n

\u6b21\u306b\u30d4\u30ed\u30b0\u30eb\u30bf\u30df\u30ce\u30fc\u30eb\u3092\u53cd\u5fdc\u7269\u3068\u3057\u3066\u30d4\u30ed\u30b0\u30eb\u30bf\u30df\u30f3\u9178\u306e\u3068\u304d\u3068\u540c\u69d8\u306e\u6761\u4ef6\u3067\u53cd\u5fdc\u3092\u884c\u3044\u307e\u3057\u305f\u3002\u5148\u307b\u3069\u3068\u540c\u3058\u3088\u3046\u306b\u3001\u6c34\u7d20\u52a0\u5727\u96f0\u56f2\u6c17\u3067\u62c5\u6301\u30eb\u30c6\u30cb\u30a6\u30e0\u89e6\u5a92\u304c\u767d\u91d1\u3001\u30d1\u30e9\u30b8\u30a6\u30e0\u3001\u30ed\u30b8\u30a6\u30e0\u306b\u306f\u306a\u3044\u9ad8\u3044\u6d3b\u6027\u3092\u793a\u3059\u3053\u3068\u304c\u308f\u304b\u308a\u307e\u3057\u305f\u3002<\/p>\n

\u305f\u3060\u3001\u30d4\u30ed\u30b0\u30eb\u30bf\u30df\u30ce\u30fc\u30eb\u304b\u30892-\u30d4\u30ed\u30ea\u30c9\u30f3\u3078\u5909\u63db\u3059\u308b\u904e\u7a0b\u3067\u6c34\u7d20\u304c\u53cd\u5fdc\u306b\u95a2\u4e0e\u3057\u3066\u3044\u306a\u3044\u53ef\u80fd\u6027\u304c\u3042\u308b\u305f\u3081\u3001\u7a92\u7d20\u52a0\u5727\u96f0\u56f2\u6c17\u3067\u3082\u53cd\u5fdc\u3092\u884c\u3044\u307e\u3057\u305f\u304c\u3001\u3053\u306e\u6761\u4ef6\u3067\u306f\u3044\u305a\u308c\u306e\u89e6\u5a92\u3082\u53cd\u5fdc\u306f\u307b\u3068\u3093\u3069\u9032\u884c\u3057\u307e\u305b\u3093\u3067\u3057\u305f\u3002<\/p>\n

\"\"
\u30d4\u30ed\u30b0\u30eb\u30bf\u30df\u30ce\u30fc\u30eb\u304b\u3089\u306e2-\u30d4\u30ed\u30ea\u30c9\u30f3\u5408\u6210\uff08\u6c34\u7d20\u307e\u305f\u306f\u7a92\u7d201 MPa, 160 \u2103, 1 hr\uff09<\/figcaption><\/figure>\n

\u751f\u6210\u7269\u306e\u8a73\u7d30\u5206\u6790\u3084\u89e6\u5a92\u8868\u9762\u4e0a\u3067\u306e\u30d4\u30ed\u30b0\u30eb\u30bf\u30df\u30ce\u30fc\u30eb\u306e\u5909\u63db\u904e\u7a0b\u3092\u8d64\u5916\u5206\u5149\u6cd5\u3067\u6e2c\u5b9a\u3057\u305f\u7d50\u679c\u304b\u3089\u3001\u6c34\u7d20\u52a0\u5727\u6761\u4ef6\u3067\u306e\u30eb\u30c6\u30cb\u30a6\u30e0\u7279\u6709\u306e\u6d3b\u6027\u306f\u3001\u30d4\u30ed\u30b0\u30eb\u30bf\u30df\u30ce\u30fc\u30eb\u306e\u30d2\u30c9\u30ed\u30ad\u30b7\u30e1\u30c1\u30eb\u57fa\uff08-CH2<\/sub>OH\uff09\u304c\u8131\u96e2\u3059\u308b\u969b\u306b\u6c34\u7d20\u3068\u5171\u306b\u4e00\u9178\u5316\u70ad\u7d20\u304c\u751f\u6210\u3057\u3001\u4ed6\u306e\u91d1\u5c5e\u3067\u306f\u4e00\u9178\u5316\u70ad\u7d20\u306b\u3088\u3063\u3066\u88ab\u6bd2\u3057\u3066\u89e6\u5a92\u6d3b\u6027\u3092\u5931\u3046\u306e\u306b\u5bfe\u3057\u3066\u3001\u30eb\u30c6\u30cb\u30a6\u30e0\u3067\u306f\u3053\u308c\u3092\u7d20\u65e9\u304f\u6c34\u7d20\u5316\u3057\u3066\u30e1\u30bf\u30f3\u3068\u3057\u3066\u8131\u96e2\u3067\u304d\u308b\u305f\u3081\u3001\u9ad8\u3044\u89e6\u5a92\u6d3b\u6027\u3092\u793a\u3059\u3053\u3068\u304c\u308f\u304b\u308a\u307e\u3057\u305f\u3002<\/p>\n

\u6700\u5f8c\u306b\u3001\u30b0\u30eb\u30bf\u30df\u30f3\u9178\u304b\u30892-\u30d4\u30ed\u30ea\u30c9\u30f3\u306e\u5408\u6210\u53cd\u5fdc\u3092\u884c\u3044\u307e\u3057\u305f\u3002\u524d\u8ff0\u306e\u3068\u304a\u308a\u3001\u30b0\u30eb\u30bf\u30df\u30f3\u9178\u306f100 \u2103\u4ee5\u4e0a\u306e\u6761\u4ef6\u3067\u30d4\u30ed\u30b0\u30eb\u30bf\u30df\u30f3\u9178\u3078\u3068\u5bb9\u6613\u306b\u5909\u63db\u3055\u308c\u307e\u3059\u3002\u30b0\u30eb\u30bf\u30df\u30f3\u9178\u306e\u5834\u5408\u3001\u30d4\u30ed\u30b0\u30eb\u30bf\u30df\u30f3\u9178\u306e\u5834\u5408\u3068\u307b\u307c\u540c\u3058\u751f\u6210\u7269\u53ce\u7387\u3092\u793a\u3057\u3001\u51fa\u767a\u7269\u8cea\u306b\u3088\u308b\u6d3b\u6027\u306e\u5dee\u7570\u304c\u751f\u3058\u306a\u3044\u3053\u3068\u304c\u308f\u304b\u308a\u307e\u3057\u305f\u3002<\/p>\n

\"\"
\u30b0\u30eb\u30bf\u30df\u30f3\u9178\u304b\u30892-\u30d4\u30ed\u30ea\u30c9\u30f3\u306e\u5408\u6210\u53cd\u5fdc\u306b\u304a\u3051\u308b\u53cd\u5fdc\u6a5f\u69cb
<\/figcaption><\/figure>\n

\u62c5\u6301\u30eb\u30c6\u30cb\u30a6\u30e0\u89e6\u5a92\u306b\u3088\u308b\u30b0\u30eb\u30bf\u30df\u30f3\u9178\u304b\u30892-\u30d4\u30ed\u30ea\u30c9\u30f3\u3078\u306e\u5909\u63db\u306f\u3001\u5929\u7136\u306b\u8c4a\u5bcc\u306b\u5b58\u5728\u3059\u308b\u30a2\u30df\u30ce\u9178\u304b\u3089\u5316\u5b66\u5de5\u696d\u3067\u91cd\u8981\u306a\u542b\u7a92\u7d20\u5316\u5408\u7269\u3092\u5408\u6210\u3059\u308b\u65b9\u6cd5\u3068\u3057\u3066\u6709\u671b\u3067\u3042\u308b\u3068\u3044\u3048\u307e\u3059\u3002\u4eca\u5f8c\u306e\u8ab2\u984c\u3068\u3057\u3066\u306f\u526f\u751f\u6210\u7269\u306e\u751f\u6210\u91cf\u3092\u4f4e\u6e1b\u3057\u3066\u76ee\u7684\u7269\u306e\u53ce\u7387\u3092\u5411\u4e0a\u3055\u305b\u308b\u3053\u3068\u3067\u3059\u3002<\/p>\n

\u4eca\u5f8c\u306e\u5c55\u671b – \u30a2\u30df\u30ce\u9178\u306e\u6c34\u7d20\u5316<\/h3>\n

\u4eca\u56de\u306e\u53cd\u5fdc\u3067\u62c5\u6301\u30eb\u30c6\u30cb\u30a6\u30e0\u89e6\u5a92\u306f\u30ab\u30eb\u30dc\u30f3\u9178\u306e\u6c34\u7d20\u5316\u306b\u5bfe\u3057\u3066\u3082\u9ad8\u3044\u6d3b\u6027\u3092\u793a\u3059\u3053\u3068\u304c\u308f\u304b\u308a\u307e\u3057\u305f\u3002\u305d\u3053\u3067\u3001\u73fe\u5728\u4ed6\u306e\u30a2\u30df\u30ce\u9178\u306e\u6c34\u7d20\u5316\u306b\u3088\u3063\u3066\u30a2\u30eb\u30ab\u30ce\u30fc\u30eb\u30a2\u30df\u30f3\u3092\u5408\u6210\u3059\u308b\u7814\u7a76\u3092\u9032\u3081\u3066\u3044\u307e\u3059\u3002\u3053\u306e\u53cd\u5fdc\u306b\u306f\u4e00\u822c\u7684\u306b\u9084\u5143\u5264\u3068\u3057\u3066\u6c34\u7d20\u5316\u30a2\u30eb\u30df\u30cb\u30a6\u30e0\u30ea\u30c1\u30a6\u30e0\u304c\u7528\u3044\u3089\u308c\u3066\u3044\u307e\u3059\u304c\u3001\u975e\u5e38\u306b\u5f37\u529b\u306a\u9084\u5143\u5264\u3067\u3042\u308b\u305f\u3081\u6c34\u3068\u6fc0\u3057\u304f\u53cd\u5fdc\u3057\u3084\u3059\u304f\u3001\u307e\u305f\u767a\u706b\u3092\u4f34\u3046\u306e\u3067\u53cd\u5fdc\u5f8c\u306e\u51e6\u7406\u3092\u614e\u91cd\u306b\u884c\u3046\u5fc5\u8981\u304c\u3042\u308a\u307e\u3059\u3002\u3082\u3057\u56fa\u4f53\u89e6\u5a92\u3092\u7528\u3044\u3066\u30a2\u30eb\u30ab\u30ce\u30fc\u30eb\u30a2\u30df\u30f3\u306e\u5408\u6210\u304c\u53ef\u80fd\u306b\u306a\u308c\u3070\u3001\u5b89\u5168\u5bfe\u7b56\u306e\u305f\u3081\u306e\u30b3\u30b9\u30c8\u4f4e\u6e1b\u306b\u7e4b\u304c\u308a\u307e\u3059\u3002\u3053\u308c\u3089\u306e\u7814\u7a76\u3092\u542b\u3081\u3001\u4eca\u5f8c\u65b0\u305f\u306a\u30a2\u30df\u30ce\u9178\u5909\u63db\u30d7\u30ed\u30bb\u30b9\u3078\u3068\u5c55\u958b\u3057\u3066\u3044\u304d\u305f\u3044\u3068\u8003\u3048\u3066\u3044\u307e\u3059\u3002<\/p>\n

\u53c2\u8003\u6587\u732e<\/strong>
\nS. Suganuma, A. Otani, S. Joka, H. Asako, R. Takagi, E. Tsuji, N. Katada, \u201cOne-Step Conversion of Glutamic Acid into 2-Pyrrolidone on a Supported Ru Catalyst in a Hydrogen Atmosphere: Remarkable Effect of CO Activation\u201d, ChemSusChem<\/em>, 12 (7), 1381-1389 (2019).<\/p>\n","protected":false},"excerpt":{"rendered":"

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